Skip to main content

2018 | OriginalPaper | Buchkapitel

Selective Recovery of P and Mn from Steelmaking Slag by Carbothermic Reduction

verfasst von : Dong Jun Shin, Xu Gao, Shigeru Ueda, Shin-ya Kitamura

Erschienen in: 9th International Symposium on High-Temperature Metallurgical Processing

Verlag: Springer International Publishing

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Steelmaking slag contains useful elements such as P and Mn. Generally, in the carbothermic reduction of slag, not only P but also Mn are reduced and a Fe–P–Mn alloy is formed. In this study, the possibility of the separation of Mn and P was investigated. A mixture of synthesized slag and graphite was heated at 1773 K, and the compositions of the separated slag and metal were analyzed. The results showed that with a decrease in basicity, the reduction of P was enhanced but that of Mn was suppressed. Thus, under an optimum condition, steelmaking slag was separated into a Fe–P alloy and a high MnO-containing slag. Although further investigation is necessary, the formed alloy and slag could be used as raw materials for fertilizers and Fe–Mn alloys, respectively. This paper elucidates the concept of this process and the results of the fundamental experiments.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
2.
Zurück zum Zitat Nakajima K, Yokoyama K, Nagasaka T (2008) Substance flow analysis of manganese associated with iron and steel flow in Japan. ISIJ Int 48(4):549–553CrossRef Nakajima K, Yokoyama K, Nagasaka T (2008) Substance flow analysis of manganese associated with iron and steel flow in Japan. ISIJ Int 48(4):549–553CrossRef
4.
Zurück zum Zitat Matsubae K, Kajiyama J, Hiraki T, Nagasaka T (2011) Virtual phosphorus ore requirement of Japanese economy. Chemosphere 84:767–772CrossRef Matsubae K, Kajiyama J, Hiraki T, Nagasaka T (2011) Virtual phosphorus ore requirement of Japanese economy. Chemosphere 84:767–772CrossRef
6.
Zurück zum Zitat Nakase K, Matsui A, Kikuchi N, Miki Y (2017) Effect of slag composition on phosphorus separation from steelmaking slag by reduction. ISIJ Int 57(7):1197–1204CrossRef Nakase K, Matsui A, Kikuchi N, Miki Y (2017) Effect of slag composition on phosphorus separation from steelmaking slag by reduction. ISIJ Int 57(7):1197–1204CrossRef
7.
Zurück zum Zitat Li H-J, Suito H, Tokuda M (1995) Thermodynamic analysis of slag recycling using a slag regenerator. ISIJ Int 35(9):1079–1088CrossRef Li H-J, Suito H, Tokuda M (1995) Thermodynamic analysis of slag recycling using a slag regenerator. ISIJ Int 35(9):1079–1088CrossRef
8.
Zurück zum Zitat Kim S-J, Shibata H, Takekawa J, Kitamura S, Yamaguchi K, Kang Y-B (2012) Influence of partial pressure of sulfur and oxygen on distribution of Fe and Mn between liquid Fe-Mn oxysulfide and molten slag. Metall Mater Trans B 43B(5):1069–1077CrossRef Kim S-J, Shibata H, Takekawa J, Kitamura S, Yamaguchi K, Kang Y-B (2012) Influence of partial pressure of sulfur and oxygen on distribution of Fe and Mn between liquid Fe-Mn oxysulfide and molten slag. Metall Mater Trans B 43B(5):1069–1077CrossRef
9.
Zurück zum Zitat Kim S-J, Takekawa J, Shibata H, Kitamura S, Yamaguchi K, Kang Y-B (2013) Thermodynamic assessment of MnO and FeO activities in FeO-MnO-MgO-P2O5-SiO2(-CaO) molten slag. ISIJ Int 53(8):1325–1333CrossRef Kim S-J, Takekawa J, Shibata H, Kitamura S, Yamaguchi K, Kang Y-B (2013) Thermodynamic assessment of MnO and FeO activities in FeO-MnO-MgO-P2O5-SiO2(-CaO) molten slag. ISIJ Int 53(8):1325–1333CrossRef
10.
Zurück zum Zitat Kim S-J, Takekawa J, Shibata H, Kitamura S, Yamaguchi K (2013) Influence of slag basicity and temperature on Fe and Mn distribution between liquid Fe-Mn-Ca-O-S Matte and Molten Slag. ISIJ Int 53(10):1715–1724CrossRef Kim S-J, Takekawa J, Shibata H, Kitamura S, Yamaguchi K (2013) Influence of slag basicity and temperature on Fe and Mn distribution between liquid Fe-Mn-Ca-O-S Matte and Molten Slag. ISIJ Int 53(10):1715–1724CrossRef
11.
Zurück zum Zitat Kim S-J, Suzuki J, Gao X, Ueda S, Kitamura S (2016) A kinetic model to simulate the reaction between slag and matte for the production of ferromanganese alloy from steelmaking slag. J Sustain Metal 2(2):141–151CrossRef Kim S-J, Suzuki J, Gao X, Ueda S, Kitamura S (2016) A kinetic model to simulate the reaction between slag and matte for the production of ferromanganese alloy from steelmaking slag. J Sustain Metal 2(2):141–151CrossRef
12.
Zurück zum Zitat Sasaki K, Nakashima H, Okumura H, Yamada Y, Goto H, Sumida M, Tsujino R (1983) Investigation of dephosphorization reaction by injecting lime based fluxes and iron oxides into hot metal in torpedo ladle. Tetsu-to-Hagané 69(15):1818–1824CrossRef Sasaki K, Nakashima H, Okumura H, Yamada Y, Goto H, Sumida M, Tsujino R (1983) Investigation of dephosphorization reaction by injecting lime based fluxes and iron oxides into hot metal in torpedo ladle. Tetsu-to-Hagané 69(15):1818–1824CrossRef
13.
Zurück zum Zitat Kitamura T, Shibata K, Sawada I, Kitamura S (1990) Mathematical modeling for kinetics of hot metal pretreatment reaction. In: Proceedings of the 6th International Iron and Steel Congress, Nagoya, Japan, vol 1, pp 50–56 Kitamura T, Shibata K, Sawada I, Kitamura S (1990) Mathematical modeling for kinetics of hot metal pretreatment reaction. In: Proceedings of the 6th International Iron and Steel Congress, Nagoya, Japan, vol 1, pp 50–56
14.
Zurück zum Zitat Kaneko T, Matsuzaki T, Kugimiya T, Ide K, Kumakura M, Kasama A (1993) Improvement of Mn yield in less slag blowing at BOF by use of sintered manganese ore. Tetsu-to-Hagané 79(8):941–947CrossRef Kaneko T, Matsuzaki T, Kugimiya T, Ide K, Kumakura M, Kasama A (1993) Improvement of Mn yield in less slag blowing at BOF by use of sintered manganese ore. Tetsu-to-Hagané 79(8):941–947CrossRef
15.
Zurück zum Zitat Suito H, Inoue R (1984) Thermodynamic considerations on manganese equilibria between liquid iron and FetO-MnO-MOx (MOx = PO2.5, SiO2, AlO1.5, MgO, CaO) slags. Tetsu-to-Hagané 70(6):533–540CrossRef Suito H, Inoue R (1984) Thermodynamic considerations on manganese equilibria between liquid iron and FetO-MnO-MOx (MOx = PO2.5, SiO2, AlO1.5, MgO, CaO) slags. Tetsu-to-Hagané 70(6):533–540CrossRef
16.
Zurück zum Zitat Turkdogan ET, Pearson J (1953) Activities of constituents of iron and steel making slags: Part III-P2O5. JISI 175:398–401 Turkdogan ET, Pearson J (1953) Activities of constituents of iron and steel making slags: Part III-P2O5. JISI 175:398–401
17.
Zurück zum Zitat Suito H, Inoue R (1984) Manganese equilibrium between molten iron and MgO-saturated CaO-FetO-SiO2-MnO-P2O5 slags. Tetsu-to-Hagané 70(7):672–679CrossRef Suito H, Inoue R (1984) Manganese equilibrium between molten iron and MgO-saturated CaO-FetO-SiO2-MnO-P2O5 slags. Tetsu-to-Hagané 70(7):672–679CrossRef
18.
Zurück zum Zitat Suito H, Inoue R (1984) Phosphorus distribution between MgO-saturated CaO-FetO-SiO2-P2O5-MnO slags and liquid iron. Tetsu-to-Hagané 70(2):186–193CrossRef Suito H, Inoue R (1984) Phosphorus distribution between MgO-saturated CaO-FetO-SiO2-P2O5-MnO slags and liquid iron. Tetsu-to-Hagané 70(2):186–193CrossRef
19.
Zurück zum Zitat Shin D-J, Gao X, Ueda S, Kitamura S (2017) Selective recovery of phosphorus and manganese from steelmaking slag by carbothermic reduction. In: Proceeding 5th International Slag Valorization Symposium, Leuven Belgium. pp 161–164 Shin D-J, Gao X, Ueda S, Kitamura S (2017) Selective recovery of phosphorus and manganese from steelmaking slag by carbothermic reduction. In: Proceeding 5th International Slag Valorization Symposium, Leuven Belgium. pp 161–164
Metadaten
Titel
Selective Recovery of P and Mn from Steelmaking Slag by Carbothermic Reduction
verfasst von
Dong Jun Shin
Xu Gao
Shigeru Ueda
Shin-ya Kitamura
Copyright-Jahr
2018
DOI
https://doi.org/10.1007/978-3-319-72138-5_31

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.