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Journal of Nanoparticle Research

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01.08.2020 | Research paper

Selective uptake of Ag(I) from aqueous solutions using ionic liquid-modified iron oxide nanoparticles

verfasst von: Abiodun D. Aderibigbe, Richard A. Crane, Martin R. Lees, Andrew J. Clark

Erschienen in: Journal of Nanoparticle Research | Ausgabe 8/2020

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Abstract

Surface functionalized magnetic nanoparticles represent a potentially highly valuable new suite of technologies for the selective recovery of metals from the aqueous phase, due to their ability to be manipulated and then recovered using an externally applied magnetic field. Ionic liquids are ideal candidates for such surface functionalization for a range of reasons, including their enhanced selectivity, low water consumption, and high chemical stability. Herein the removal of Ag⁺ onto [MTESPIm]⁺[Cl]⁻ on Fe₃O₄@SiO₂ has been investigated as a function of pH, exposure time, nanosorbent concentration, and type of stripping agent. The Ag⁺ removal was recorded to fit the Langmuir isotherm indicating monolayer formation, with a saturation capacity of 23.69 mg/g. Optimum conditions for the selective removal of Ag⁺ in preference to Cu²⁺ and Pb²⁺ were recorded at pH 3, exposure time ranging between 0 and 15 min, and at the highest nanosorbent dose tested (80 mg nanosorbent/10 mL of adsorbate solution) Moreover, thiourea outperformed both HNO₃ and HCl for the stripping of sorbed Ag⁺, with optimum efficacy at 0.6 M. Overall, the results indicate that [MTESPIm]⁺[Cl]⁻ on Fe₃O₄@SiO₂ is a highly adaptable and efficient agent for the selective recovery of Ag from the aqueous phase.

Vorheriger Artikel Temperature features of non-radiative energy transfer in hybrid associates of CdS/TGA quantum dots with methylene blue molecules

Nächster Artikel Phase-control synthesis and catalytic property of nickel phosphide nanospheres

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Titel: Selective uptake of Ag(I) from aqueous solutions using ionic liquid-modified iron oxide nanoparticles
verfasst von: Abiodun D. Aderibigbe
Richard A. Crane
Martin R. Lees
Andrew J. Clark
Publikationsdatum: 01.08.2020
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 8/2020
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-020-04944-1

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