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Journal of Nanoparticle Research
Erschienen in: Journal of Nanoparticle Research 8/2020

01.08.2020 | Research paper

Influence of size, shape and dimension on glass transition and Kauzmann temperature of silver (Ag) and tantalum (Ta) nanoparticles

verfasst von: Chetna S. Tiwari, Arun Pratap, Prafulla K. Jha

Erschienen in: Journal of Nanoparticle Research | Ausgabe 8/2020

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Abstract

A simple model is developed for the investigation of size, shape and dimension dependent glass transition temperature (Tg) and Kauzmann temperature (TK) of nanoparticles. The model is based on thermodynamical quantity cohesive energy and is free from fitting parameters and approximations. To check the validity of the model, calculations on the size, shape and dimension dependent glass transition (Tg) and Kauzmann temperature (TK) are performed for silver (Ag) and tantalum (Ta) nanoparticles (NPs) of different shapes. The considered shapes are spherical, tetrahedral, octahedral and icosahedral accompanied with zero-, one- and two-dimensional geometries. Our results reveal that the Tg and TK strongly depend on the size of the nanoparticles. As the size of the NPs decreases, Tg and TK decrease. It is observed that both temperatures follow the trend as (icosahedral, D) > (spherical, D) > (octahedral, D) > (tetrahedral, D) for selected Ag and Ta nanoparticles. However, in terms of dimension, they show the d = 0 < d = 1 < d = 2 trend. The calculated values of glass transition and Kauzmann temperatures for both considered nanoparticles have good agreement with available molecular dynamics (MD) simulation and experimental data.
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Literatur
Adam G, Gibbs JH (1965) On the temperature dependence of cooperative relaxation properties in glass-forming liquids. J Chem Phys 43:139–146
Alcoutlabi M, McKenna GB (2005) Effects of confinement on material behaviour at the nanometre size scale J. Phys: Condens Matter 17:461
Ao ZM, Zheng WT, Jiang Q (2007) Size effects on the Kauzmann temperature and related thermodynamic parameters of Ag nanoparticles. Nanotechnology 18:255706–255712
Attili A, Gallo P, Rovere M (2005) Inherent structures and Kauzmann temperature of confined liquids Phys. Rev E 71:031204
Baletto F, Ferrando R, Fortunelli A, Montalenti F, Mottet C (2002) Crossover among structural motifs in transition and noble-metal clusters. J Chem Phys 116:3856–3863
Bhatt P, Pratap A, Jha PK (2012) Study of size-dependent glass transition and Kauzmann temperatures of tin dioxide nanoparticles. J Therm Anal Calorim 110:535–538
Chen X, Mao SS (2007) Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem Rev 107:2891–2959
Coluzzi B, Parisi G, Verrocchio P (2000) Thermodynamical liquid-glass transition in a Lennard-Jones Binary Mixture. Phys Rev Lett 84:306–309
Debenedetti PG, Stillinger FH (2001) Supercooled liquids and the glass transition. Nature 410:259–267
Guisbiers G (2010) Size-dependent materials properties toward a universal equation Nanoscale Res. Lett. 5:1132–1136
Gao W, Zhao M, Jiang Q (2007) A DFT study on electronic structures and catalysis of Ag12O6/Ag(111) for ethylene Epoxidation. J Phys Chem C 111:4042–4046
Gibbs JH, Di Marzio EA (1958) Nature of the glass transition and the glassy state. J Chem Phys 28:373–383
Guisbiers G, Kazan M, Van Overschelde O, Wautelet M, Pereira S (2008) Mechanical and thermal properties of metallic and semiconductive nanostructures. J Phys Chem C 112:4097–4103
Guisbiers G, Wautelet M (2006) Size, shape and stress effects on the melting temperature of nano-polyhedral grains on a substrate. Nanotechnology 17:2008–2011
Jiang Q, Lang XY (2004) Glass transition of low-dimensional polystyrene Macromol. Rapid Commun 25:825
Jiang Q, Zhao M, Xu XY (1997) Kauzmann temperature of alloys obtained by different methods. Phil MagB 76:1–10
Kauzmann W (1948) The nature of the glassy state and the behaviour of liquids at low temperatures. Chem Rev 43:219–256
Khan MM, Nemati A, Rahman ZU, Shah UH, Asgar H, Haider W (2017) Recent advancements in bulk metallic glasses and their applications: a review. Critical Reviews In Solid State and Materials Sciences 43:233–268
Klose G, Fecht HJ (1994) Vitrification close to the Kauzmann point of eutectic Au Pb Sb alloys Mater. Sci. Eng. A 180:77–80
Krakoviack V (2005) Liquid-glass transition of a fluid confined in a disordered porous matrix: a mode-coupling theory. Phys Rev Lett 94:065703–065707
Kumar G, Desai A, Schroers J (2011) Bulk metallic glass: the smaller the better Adv. Mater. 23:461–476
Li YZ, Sun YT, Lu Z, Li MZ, Bai HY, Wang WH (2017) Size effect on dynamics and glass transition in metallic liquids and glasses. J Chem Phys 146:224502
Lu HM, Li PY, Cao ZH, Meng XK (2009) Size-, Shape-, and Dimensionality-Dependent Melting Temperatures of Nanocrystals. J Phys Chem C 113:7598–7602
Luo J, Wang J, Bitzek E, Huang JY, Zhang H, Tong L, Yang Q, Li J, Mao SX (2016) Size-dependent brittle-to-ductile transition in silica glass nanofibers. Nano Lett 16:105–113
Mishra S, Jha PK, Pratap A (2012) Study of size-dependent glass transition and Kauzmann temperature of titanium dioxide nanoparticles. J Therm Anal Calorim 107:65–68
Morones J et al (2005) The bactericidal effect of silver nanoparticles. Nanotechnology 16:2346
Nanda KK, Sahu SN, Behera SN (2002) Liquiddrop model for the size-dependent melting of lowdimensional systems, Phys. Rev. A 66, 013208
Narayanan R, El-Sayed MA (2003) Effect of catalysis on the stability of metallic nanoparticles: Suzuki reaction catalyzed by PVP-palladium nanoparticles. J Am Chem Soc 125:8340–8347
Jiang Q, Shi HX, Zhao M (1999) Melting thermodynamics of organic nanocrystals. J Chem Phys 111:5
Kumar R, Kumar M (2012) Effect of size on cohesive energy, melting temperature and Debye temperature of nanomaterial. Indian J pure Appl. Phys. 50:329–334
Bhatt S, Kumar M (2017) Effect of size and shape on melting and superheating of free standing and embedded nanoparticles. J Phys Chem Solids 106:112–117
Safaei A, Shandiz M, Sanjabi A, Barber S, Z. H. (2008) Modeling the melting temperature of nanoparticles by an analytical approach. J Phys Chem C 112:99–155
Saslow WS (1988) Scenario for the Vogel-Fulcher “law”. Phys Rev B 37:676–678
Sastry S (2001) The relationship between fragility, configurational entropy and the potential energy landscape of glass-forming liquids. Nature 409:164–167
Sastry S, Debenedetti PG, Stillinger FH (1998) Signatures of distinct dynamical regimes in the energy landscape of a glass-forming liquid. Nature 393:554–557
Scala A, Starr FW, Nave EL, Sciortino F, Stanley HE (2000) Configurational entropy and diffusivity of supercooled water. Nature 406:166–175
Seifert G (2004) Nanocluster magic. Nat Mater 3:77–78
Stillinger FH et al (1999) J Phys Chem B 103:7390
Sun J, He LB, Lo YC, Xu T, Bi HC, Sun L, Zhang Z, Mao SX, Li J (2014) Liquid-like pseudo-elasticity of sub-10-nm crystalline silver particles. Nat Mater 13:1007–1012
Tanaka H (2005) Two-order-parameter model of the liquid–glass transition. III. Universal patterns of relaxations in glass-forming liquids. J Non-Cryst Solids 351:3396–3413
Qi WH (2005) Size effect on melting temperature of nanosolids. Physica B 368(2005):46–50
Wang Y et al (2004) Synthesis and phase structure of tantalum nanoparticles. Mater Lett 58:3017–3020
Yu HB, Luo Y, Samwer K (2013) Ultrastable metallic glass. Adv Mater 25:5904–5908
Yu HB et al (2015) Suppression of β relaxation in vapor-deposited ultrastable glasses. Phys Rev Lett 115:185501–185506
Zhang X et al (2018) Size and shape dependent melting temperature of metallic nanomaterials J. Phys: Condens Matter 31:7
Zhong L, Wang J, Sheng H, Zhang Z, Mao SX (2014) Formation of monatomic metallic glasses through ultrafast liquid quenching. Nature 512:177–180
Metadaten
Titel
Influence of size, shape and dimension on glass transition and Kauzmann temperature of silver (Ag) and tantalum (Ta) nanoparticles
verfasst von
Chetna S. Tiwari
Arun Pratap
Prafulla K. Jha
Publikationsdatum
01.08.2020
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 8/2020
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-020-04955-y

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