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Erschienen in: Journal of Nanoparticle Research 10/2016

01.10.2016 | Research Paper

Self-assembly of metal–organic frameworks and graphene oxide as precursors for lithium-ion battery applications

verfasst von: Xia Yang, Linlin Liu, Ruo Yuan, Chun-Sing Lee

Erschienen in: Journal of Nanoparticle Research | Ausgabe 10/2016

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Abstract

We fabricated composites of Fe2O3/reduced graphene oxide as lithium-ion batteries anode material with controlled structures by employing self-assembly of metal–organic frameworks (MOFs) and polymer-functionalized graphene oxide as precursors. By electrostatic interaction, the negatively charged MOFs, Prussian Blue (PB), are assembled on poly(diallyldimethylammonium chloride) (PDDA)-functionalized graphene oxide (positive charge). Then the PB cubes become FeOOH nanosheets when treated with sodium hydroxide. Upon further annealing, the FeOOH nanosheets transform to Fe2O3 nanoparticles while the graphene oxide become reduced graphene oxide simultaneously. It was found that the composites have good performance as anode of lithium-ion battery. This work shows a new way for self-assembling MOFs and 2D materials.

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Metadaten
Titel
Self-assembly of metal–organic frameworks and graphene oxide as precursors for lithium-ion battery applications
verfasst von
Xia Yang
Linlin Liu
Ruo Yuan
Chun-Sing Lee
Publikationsdatum
01.10.2016
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 10/2016
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-016-3589-5

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