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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 23/2020

21.10.2020

Silver and yttrium-doped bismuth vanadate for photoluminescent activity and boosted visible light-induced photodegradation

verfasst von: O. P. Kumar, Muhammad Naeem Ashiq, Muhammad Ahmad, Saima Anjum, Aziz ur Rehman

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 23/2020

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Abstract

Silver and ytterbium-doped bismuth vanadate (AgxYbyBiz−xyVO4) composites have been synthesized via solid state-reaction in one-step at 950 °C for 6 h in the open air atmosphere. The effect of dopants concentration on the morphology, the optical property and the dye degradation efficiency was studied by X-ray Diffraction (XRD), energy-dispersive X-ray (EDX) spectroscopy, thermogravimetric analysis (TGA), scanning electron microscope (SEM), photoluminescence (PL) spectroscopy and Fourier transform infrared (FTIR) and UV–Visible spectroscopy. The scanning electron microscopic analysis has revealed the presence of most irregular-shaped particles; however, some definite grain-like particles have also been seen. EDX analysis disclosed the presence of V, Bi, Ag, Yb and O in the doped materials. TGA has described the stability of doped materials at the ordinary temperature. Fourier transform infrared results of AgxYbyBiz−xyVO4 composites have indicated the formation of vanadium pentaoxide based materials and the presence of V–O bond. The calculated optical band gaps of V2O5 and composites have been recorded as 2.25, 1.56 and 1.75 eV, respectively. The Nyquist plot has demonstrated nearly straight lines for V2O5 and composites which is attributed to the higher charge transfer potential. The photoluminescence spectra of the doped materials have revealed the presence of spectral bands in the red and red to infrared regions which could be used in the optical devices. The degradation efficiency of crystal violet (CV) dye was explored under the solar-light irradiation. A remarkable dye degradation efficiency of 94.57% has been recorded for 7 mg/L of the dye solution within 120 min. Besides, the proposed dye degradation mechanism and reusability experiment was also discussed in detail. The photoluminescent study of the materials exhibited emission bands at 1088 and 1045 nm are recorded which could be used in optical devices.
Vorheriger Artikel Bio-inspired synthesis of silver nanoparticles using Hibiscus Tiliaceus L. flower extracts for improved optical characteristics
Nächster Artikel Crystal engineering and physicochemical properties of l-threoninium succinate (LTS) single crystal for frequency conversion applications

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Metadaten
Titel
Silver and yttrium-doped bismuth vanadate for photoluminescent activity and boosted visible light-induced photodegradation
verfasst von
O. P. Kumar
Muhammad Naeem Ashiq
Muhammad Ahmad
Saima Anjum
Aziz ur Rehman
Publikationsdatum
21.10.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 23/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-04620-z

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