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Journal of Electronic Materials
Erschienen in: Journal of Electronic Materials 1/2023

11.11.2022 | Original Research Article

Single-Site Mn2+-Activated and Sr-Alloyed Ca3(PO4)2 Red Phosphors and Their Lighting Applications

verfasst von: Jian Zhou, Sili Ren

Erschienen in: Journal of Electronic Materials | Ausgabe 1/2023

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Abstract

The phosphor-converted white light-emitting diode (WLED) has received tremendous attention as a promising alternative to traditional light sources in lighting and displays. Herein, a novel broadband red emitter Ca2Sr(PO4)2:Mn2+ was successfully designed and synthesized based on the Sr-alloying and Mn-doping of Ca3(PO4)2. The phase purity of the materials was verified by x-ray diffraction (XRD) analyses, while a scanning electron microscope (SEM) coupled with an energy-dispersive spectrometer (EDS) was employed to confirm the uniform dopant distribution. XRD Rietveld refinements were further performed to clarify the site occupation of alloying Sr and the Mn dopants. Effective site engineering confined the Mn dopants in a highly symmetric Ca5 site and excluded the immersion of Sr, leading to an extraordinarily long fluorescence lifetime. Density functional theory (DFT) simulations also revealed the good potential of the materials as host matrices for activators such as Mn2+. Finally, Ca2Sr(PO4)2:Mn2+ was used to fabricate a WLED prototype based on a near-ultraviolet (n-UV) commercial LED chip, which realized a warm white-light emission and high color rendering index (Ra) of 82.9. This WLED was able to survive the long-term stability test while maintaining high luminous efficacy of ~ 60 lm/W within 20 h, showing its great potential in practical applications.
Vorheriger Artikel Preparation of a Wood-Based Thermally Conductive Composite
Nächster Artikel Low Thermal Conductivity and Enhancement in Figure-of-Merit in Na and Mg Co-doped β-Zn4Sb3

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Metadaten
Titel
Single-Site Mn2+-Activated and Sr-Alloyed Ca3(PO4)2 Red Phosphors and Their Lighting Applications
verfasst von
Jian Zhou
Sili Ren
Publikationsdatum
11.11.2022
Verlag
Springer US
Erschienen in
Journal of Electronic Materials / Ausgabe 1/2023
Print ISSN: 0361-5235
Elektronische ISSN: 1543-186X
DOI
https://doi.org/10.1007/s11664-022-10024-y

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