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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 1/2015

01.10.2015 | Original Paper

Sol–gel synthesis, characterization and study of substitution effects in different gallium-containing garnets

verfasst von: Skirmante Butkute, Akvile Zabiliute, Ramunas Skaudzius, Pranciskus Vitta, Aldona Beganskiene, Arturas Zukauskas, Aivaras Kareiva

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2015

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Abstract

Gallium-containing garnets (gadolinium gallium Gd3Ga5O12; GGG, and gadolinium scandium gallium Gd3Sc2Ga3O12; GSGG) were prepared using an aqueous sol–gel synthesis route. Different starting materials and TRIS (tris-(hydroxymethyl)-aminomethane), NH2C(CH2OH)3 and 1,2-ethandiol as complexing agents were used in the sol–gel processing. The final products were obtained after the heating of the precursor gels at 1000 °C for 10 h. The substitution effects of Fe3+, Ce3+, and Ce3+/Cr3+ in gallium garnets have been also investigated. The results obtained in this study have demonstrated that the formation of mixed-metal gallium garnets depends on the sol–gel synthesis parameters and nature of dopant element. The luminescent properties of GGG:Fe3+ specimens were identical to those of GSGG:Fe3+, showing the great iron quenching effect. The luminescence at 720–780 nm for the cerium-/chromium-co-doped GGG:Ce3+, Cr3+ phosphors was observed. The highest emission intensity for GGG:Ce3+, Cr3+ samples containing 3 mol% of dopants (1.5 mol% Ce and 1.5 mol% Cr) was determined.

Graphical Abstract

Cerium/chromium concentration-dependent luminescence spectra of doped GGG:Ce3+, Cr3+ samples. PL excitation spectrum (λ em = 730 nm) of pure GGG is presented at left. Emission spectra (λ ex = 460 nm) of GGG:Ce3+, Cr3+ as a function of Ce3+ and Cr3+ concentration are presented at right.
Vorheriger Artikel Effects of PVA content on the synthesis of Y2NiMnO6 by sol–gel method
Nächster Artikel Investigation of electrical properties in La-doped BiFeO3–PbTiO3 thin films prepared by sol–gel method

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Literatur
1.
Shi Y, Zhu G, Mikami M, Shimomura Y, Wang YH (2015) A novel Ce3+ activated Lu3MgAl3SiO12 garnet phosphor for blue chip light-emitting diodes with excellent performance. Dalton Trans 44:1775–1781CrossRef
2.
Yang H, Zhang L, Luo D, Qiao XB, Zhang J, Zhao T, Shen DY, Tang DY (2015) Optical properties of Ho: YAG and Ho: LuAG polycrystalline transparent ceramics. Opt Mater Express 5:142–148CrossRef
3.
Skaudzius R, Katelnikovas A, Enseling D, Kareiva A, Juestel T (2014) Dependence of the D-5(0) → F-7(4) transitions of Eu3+ on the local environment in phosphates and garnets. J Lumin 147:290–294CrossRef
4.
Wei RB, Zhang YJ, Li XN, Gong HY, Zhang Y, Jiang YZ (2013) Synthesis of a dysprosium aluminum garnet nanopowder via sol–gel method. J Sol-Gel Sci Technol 65:388–391CrossRef
5.
Katelnikovas A, Ogieglo JM, Winkler H, Kareiva A, Jüstel T (2011) Synthesis of Y3−x Lu x Al3MgSiO12 garnet powders by sol–gel method. J Sol-Gel Sci Technol 59:311–314CrossRef
6.
Jung KY, Lee DY, Kang YC (2005) Morphology control and luminescent property of Y3Al5O12: Tb particles prepared by spray pyrolysis. Mater Res Bull 40:2212–2218CrossRef
7.
Zanatta SC, Cotica LF, Paesano A, Medeiros SN, Cunha JBM, Hallouche B (2005) Mechanosynthesis of gadolinium iron garnet. J Am Ceram Soc 88:3316–3321CrossRef
8.
Galazka Z, Wilke H (2000) Heat transfer and fluid flow during growth of Y3Al5O12 single crystals using the Czochralski method. Cryst Res Technol 35:1263–1278CrossRef
9.
Veith M, Mathur S, Kareiva A, Jilavi M, Zimmer M, Huch V (1999) Low temperature synthesis of nanocrystalline Y3Al5O12 (YAG) and Ce-doped Y3Al5O12 via different sol–gel methods. J Mater Chem 9:3069–3079CrossRef
10.
Marker VK, Elseth KM, Radosevich JA (1990) The contact neodymium-yttrium-aluminum-garnet (ND-YAG) laser reduces local recurrence of tumor-growth. Clin Res 38:A821–A821
11.
Katelnikovas A, Vitta P, Pobedinskas P, Tamulaitis G, Zukauskas A, Jørgensen JE, Kareiva A (2007) Photoluminescence in sol–gel-derived YAG: Ce phosphors. J Cryst Growth 304:361–368CrossRef
12.
Hreniak D, Strek W, Mazur P, Pazik R, Zabkowska-Waclawek M (2004) Luminescence properties of Tb3+: Y3Al5O12 nanocrystallites prepared by the sol–gel method. Opt Mater 26:117–121CrossRef
13.
Rodríguez-Rojas RA, De la Rosa-Cruz E, Díaz-Torres LA, Salas P, Meléndrez R, Barboza-Flores M, Meneses-Nava MA, Barbosa-García O (2004) Preparation, photo- and thermo-luminescence characterization of Tb3+ and Ce3+ doped nanocrystalline Y3Al5O12 exposed to UV-irradiation. Opt Mater 25:285–293CrossRef
14.
Nishi M, Tanabe S, Inoue M, Takahashi M, Fujita K, Hirao K (2005) Optical-telecommunication-band fluorescence properties of Er3+-doped YAG nanocrystals synthesized by glycothermal method. Opt Mater 27:655–662CrossRef
15.
Garskaite E, Lindgren M, Einarsrud MA, Grande T (2010) Luminescent properties of rare earth (Er, Yb) doped yttrium aluminium garnet thin films and bulk samples synthesised by an aqueous sol–gel technique. J Eur Ceram Soc 30:1707–1715CrossRef
16.
Boyer D, Bertrand-Chadeyron G, Mahiou R (2004) Structural and optical characterizations of YAG: Eu3+ elaborated by the sol–gel process. Opt Mater 26:101–105CrossRef
17.
Zhou YH, Lin J, Wang SB, Zhang HJ (2002) Preparation of Y3Al5O12: Eu phosphors by citric-gel method and their luminescent properties. Opt Mater 20:13–20CrossRef
18.
Głuchowski P, Pązik R, Hreniak D, Stręk W (2009) Luminescence properties of Cr3+:Y3Al5O12 nanocrystals. J Lumin 129:548–553CrossRef
19.
Shabir H, Lal B, Rafat M (2010) Sol–gel synthesis of Eu3+: Tb3Al5O12 nanophosphor. J Sol-Gel Sci Technol 53:399–404CrossRef
20.
Dubnikova N, Garskaite E, Pinkas J, Bezdicka P, Beganskiene A, Kareiva A (2010) Sol–gel preparation of selected lanthanide aluminium garnets. J Sol-Gel Sci Technol 55:213–219CrossRef
21.
Ogieglo JM, Katelnikovas A, Zych A, Juestel T, Meijerink A, Ronda CR (2013) Luminescence and luminescence quenching in Gd3(Ga, Al)5O12 scintillators doped with Ce3+. J Phys Chem A 117:2479–2484CrossRef
22.
Shi YR, Zhu G, Mikami M, Shimomura Y, Wang YH (2015) A novel Ce3+ activated Lu3MgAl3SiO12 garnet phosphor for blue chip light-emitting diodes with excellent performance. Dalton Trans 44:1775–1781CrossRef
23.
Tucureanu V, Matei A, Mihalache I, Danila M, Popescu M, Bita B (2015) Synthesis and characterization of YAG:Ce, Gd and YAG:Ce, Gd/PMMA nanocomposites for optoelectronic applications. J Mater Sci 50:1883–1890CrossRef
24.
Fan GF, Tang YQ, Lu WZ, Zhang XR, Xu X (2015) Reduce synthesis temperature and improve dispersion of YAG nanopowders based on the co-crystallization method. J Alloys Compd 618:1–6CrossRef
25.
Pereira PFS, Matos MG, Ávila LR, Nassor ECO, Cestari A, Ciuffi KJ, Calefi PS, Nassar EJ (2010) Red, green and blue (RGB) emission doped Y3Al5O12 (YAG) phosphors prepared by non-hydrolytic sol–gel route. J Lumin 130:488–493CrossRef
26.
Taylor E, Edwards PR, Martin RW (2012) Colorimetry and efficiency of white LEDs: spectral width dependence. Phys Status Solidi A 209:461–464CrossRef
27.
Chen DQ, Xiang WD, Liang XJ, Zhong JS, Yu H, Ding MY, Lu HW, Ji ZG (2015) Advances in transparent glass-ceramic phosphors for white light-emitting diodes—a review. J Eur Ceram Soc 35:859–869CrossRef
28.
Gautier N, Gervais M, Landron C, Massiot D, Coutures JP (1998) Aluminium-gallium substitution in yttrium garnets investigated by NMR and X-ray absorption. Phys Status Solidi A Appl Res 165:329–336CrossRef
29.
Thongmee S, Winotai P, Tang IM (1999) Local field fluctuations in the substituted aluminium iron garnets, Y3Fe5−x Al x O12. Solid State Commun 109:471–476CrossRef
30.
Garskaite E, Gibson K, Leleckaite A, Glaser J, Niznansky D, Kareiva A, Meyer HJ (2006) On the synthesis and characterization of iron-containing garnets (Y3Fe5O12, YIG and Fe3Al5O12, IAG). Chem Phys 323:204–210CrossRef
31.
Muliuoliene I, Mathur S, Jasaitis D, Shen H, Sivakov V, Rapalaviciute R, Beganskiene A, Kareiva A (2003) Evidence of the formation of mixed-metal garnets via sol–gel synthesis. Opt Mater 22:241–250CrossRef
32.
Garskaite E, Moravec Z, Pinkas J, Mathur S, Kazlauskas R, Kareiva A (2005) Synthesis and evolution of crystalline garnet phases in Y3Sc5–x Ga x O12. Philos Mag Lett 85:557–562CrossRef
33.
Skaudzius R, Pinkas J, Raudonis R, Selskis A, Juskenas R, Kareiva A (2012) On the limitary radius of garnet structure compounds Y3Al5–xMxO12 (M = Cr Co, Mn, Ni, Cu) and Y3Fe5–xCoxO12 (0 ≤ x ≤ 2.75) synthesized by sol–gel method. Mater Chem Phys 135:479–485CrossRef
34.
Thiel CW, Sinclair N, Tittel W, Cone RL (2014) Optical decoherence of Tm3+:Y3Ga5O12. Phys Rev B 90:214301CrossRef
35.
Yamaji A, Kurosawa S, Suzuki A, Pejchal J, Kamada K, Yokota Y, Yoshikawa A (2014) Optical and scintillation properties of Cr doped Y3Ga5O12 crystal for infra-red scintillators. Adv Ceram Nov Process 616:92–95
36.
Monteseguro V, Rodriguez-Hernandez P, Vilaplana R, Manjon FJ, Venkatramu V, Errandonea D, Lavin V, Munoz A (2014) Lattice dynamics study of nanocrystalline yttrium gallium garnet at high pressure. J Phys Chem C 118:13177–13185CrossRef
37.
Seeley ZM, Cherepy NJ, Payne SA (2014) Expanded phase stability of Gd-based garnet transparent ceramic scintillators. J Mater Res 29:2332–2337CrossRef
38.
Valiev UV, Gruber JB, Fu DJ, Pelenovich VO, Burdick GW, Malysheva ME (2011) Specific features of Eu3+ and Tb3+ magnetooptics in gadolinium–gallium garnet (Gd3Ga5O12). J Rare Earths 29:776–782CrossRef
39.
Blasse G, Grabmaier BC, Ostertag M (1993) The afterglow mechanism of chromium-doped gadolinium gallium garnet. J Alloys Compd 200:17–18CrossRef
40.
Ueda J, Kuroishi K, Tanabe S (2014) Yellow persistent luminescence in Ce3+–Cr3+-codoped gadolinium aluminium gallium garnet transparent ceramics after blue-light excitation. Appl Phys Express 7:062201CrossRef
41.
Leon-Luis SF, Munoz-Santiuste JE, Lavin V, Rodriguez-Mendoza UR (2012) Optical pressure and temperature sensor based on the luminescence properties of Nd3+ ion in a gadolinium gallium garnet crystal. Opt Express. doi:10.​1364/​OE.​20.​010393
42.
Tian L, Yuan H, Wang SX, Wu K, Pan ZB, Cai HQ, Yu HH, Zhang HJ (2014) Evaluation of growth, thermal and spectroscopic properties of Yb3+-doped GSGG crystals for use in ultrashort pulsed and tunable lasers. Opt Mater Express 4:1953–1965CrossRef
43.
Lupei V, Pavel N, Lupei A (2014) Improved laser efficiency by direct diode laser pumping of the radiation-resistant Nd: gadolinium–scandium–gallium garnet. Laser Phys 24:045801CrossRef
44.
Lewis WB (1992) Single-crystal EPR-spectrum of Cr3+ in lanthanum lutecium gallium garnet. Appl Phys A Mater Sci Process 54:31–34CrossRef
45.
Zorenko Y, Zorenko T, Vistovskyy V, Grinberg M, Lukasiewicz T (2009) Time-resolved spectroscopy of intrinsic luminescence of Y3Ga5O12 and (LaLu)3Lu2Ga3O12 single crystals. Opt Mater 31:1835–1838CrossRef
46.
Wu K, Hao LZ, Zhang HJ, Yu HH, Wang YC, Wang JY, Tian XP, Zhou ZC, Liu JH, Boughton RI (2012) Lu3Ga5O12 crystal: exploration of new laser host material for the ytterbium ion. J Opt Soc Am B: Opt Phys 29:2320–2328CrossRef
47.
Sun GH, Zhang QL, Yang HJ, Luo JQ, Sun DL, Gu CJ, Yin ST (2013) Crystal growth and characterization of Ho-doped Lu3Ga5O12 for 2 μm laser. Mater Chem Phys 138:162–166CrossRef
48.
Katelnikovas A, Jurkevicius J, Kazlauskas K, Vitta P, Jüstel T, Kareiva A, Zukauskas A, Tamulaitis G (2011) Efficient cerium-based sol–gel derived phosphors in different garnet matrices for light-emitting diodes. J Alloys Compd 509:6247–6251CrossRef
49.
Zabiliute A, Butkute S, Zukauskas A, Vitta P, Kareiva A (2014) Sol–gel synthesized far-red chromium-doped garnet phosphors for phosphor-conversion light-emitting diodes that meet the photomorphogenetic needs of plants. Appl Opt 53:907–914CrossRef
50.
Gibson A, Dehghani H (2009) Diffuse optical imaging. Philos Trans R Soc A Math Phys Eng Sci 367:3055–3072CrossRef
51.
Kareiva A (2011) Aqueous sol–gel synthesis methods for the preparation of garnet crystal structure compounds. Mater Sci 17:428–437
52.
Inoue M, Nishikawa T, Otsu H, Kominami H, Inui T (1998) Synthesis of rare-earth gallium garnets by the glycothermal method. J Am Ceram Soc 81:1173–1183CrossRef
53.
Zhao GJ, Xiao XH, Li T, He XM, Zhao HM, Xu J (2002) Preparation of Gd3Ga5O12 (GGG) polycrystalline material by liquid-phase co-deposition synthesis method. J Inorg Mater 17:443–447
54.
Lei M, Zhang LJ, Zeng FM, Wang YM, Piao XQ, Liu JH (2005) Preparation of gadolinium gallium garnet polycrystalline material with carbonate coprecipitation method. J Rare Earths 23:231–234
55.
Shao SF, Zhang QL, Su J, Sun DL, Wang ZB, Yin ST (2007) Preparation and characterization of Gd3Sc2Ga3O12 polycrystalline material by co-precipitation method. J Rare Earths 25:158–162CrossRef
56.
Li XX, Hu ZG, Li JT (2007) Nanostructured GGG powders via gel combustion. Opt Mater 29:854–857CrossRef
57.
Leleckaite A, Kareiva A (2004) Synthesis of garnet structure compounds using aqueous sol–gel processing. Opt Mater 26:123–128CrossRef
58.
Mathur S, Shen H, Leleckaite A, Beganskiene A, Kareiva A (2005) Low-temperature synthesis and characterization of yttrium-gallium garnet Y3Ga5O12 (YGG). Mater Res Bull 40:439–446CrossRef
59.
Zhu NF, Li YX, Yu XF, Wy Ge (2007) Synthesis and luminescent properties of YGG: Tb phosphors by Pecini method. J Lumin 122:704–706CrossRef
60.
Yu FP, Yuan DR, Cheng XF, Duan XL, Wang XQ, Kong LM, Wang LH, Li ZF (2007) Preparation and characterization of yttrium gallium garnet nanoparticles by citrate sol–gel method at low temperature. Mater Lett 61:2322–2324CrossRef
61.
Katelnikovas A, Kareiva A (2008) Low temperature synthesis of lutetium gallium garnet (LGG) using sol–gel technique. Mater Lett 62:1655–1658CrossRef
62.
Brinker CJ, Scherrer GW (1990) Sol–gel science: the physics and chemistry of sol–gel processing. Academic Press, New York
63.
Katelnikovas A, Barkauskas J, Ivanauskas F, Beganskiene A, Kareiva A (2007) Aqueous sol–gel synthesis route for the preparation of YAG: evaluation of sol–gel process by mathematical regression model. J Sol-Gel Sci Technol 41:193–201CrossRef
64.
Walker G, Glynn TJ (1992) Infrared luminescence of iron-doped synthetic forsterite. J Lumin 54:131–137CrossRef
65.
Heitz R, Maxim P, Eckey L, Thurian P, Hoffmann A, Broser I, Pressel K, Meyer BK (1997) Excited sites of Fe3+ in GaN. Phys Rev B 55:4382–4387CrossRef
66.
Sosman LP, Abritta T, Amaral MR, Cella N, Vargas H (1998) Optical properties of LiGaTiO4:Fe3+. Solid State Commun 105:135–138CrossRef
67.
Bryknar Z, Potucek Z, Schulz HF (1999) Luminescence spectroscopy of iron-doped KTaO3 crystals. Radiat Eff Defects Solids 149:51–54CrossRef
68.
Bondarenko V, Kazuchits N, Volchek S, Dolgyi L, Petrovich V, Yakovtseva V, Gaiduk P, Balucani M, Lamedica G, Ferrari A (2003) Fine structure of photoluminescence spectra from erbium incorporated with iron in oxidized porous silicon. Physica Status Solidi A Appl Res 197:441–445CrossRef
69.
Arakawa T, Akamine M (2003) Determination of transition metal irons based on quenching of the rare earth luminescence. Sens Actuators B Chem 91:252–255CrossRef
70.
Machida K (2003) Synthesis of structure and surface functional rare earth materials. J Ceram Soc Jpn 111:162–167CrossRef
71.
Katelnikovas A, Justel T, Uhlich D, Jorgensen JE, Sakirzanovas S, Kareiva A (2008) Characterization of cerium-doped yttrium aluminium garnet nanopowders synthesized via sol–gel process. Chem Eng Commun 195:758–769CrossRef
Metadaten
Titel
Sol–gel synthesis, characterization and study of substitution effects in different gallium-containing garnets
verfasst von
Skirmante Butkute
Akvile Zabiliute
Ramunas Skaudzius
Pranciskus Vitta
Aldona Beganskiene
Arturas Zukauskas
Aivaras Kareiva
Publikationsdatum
01.10.2015
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2015
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-015-3768-3

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