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Journal of Materials Science
Erschienen in: Journal of Materials Science 13/2014

01.07.2014

Structural and spectroscopic effects of Ag–Eu3+ codoping of TeO2–PbO glass ceramics

verfasst von: Eugen Culea, Ioan Vida-Simiti, Gheorghe Borodi, Eugen Nicolae Culea, Razvan Stefan, Petru Pascuta

Erschienen in: Journal of Materials Science | Ausgabe 13/2014

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Abstract

Structural and spectroscopic behavior of TeO2–PbO–Eu2O3 glass ceramics containing small amounts of Ag2O (0.5 mol%) or metallic Ag nanoparticles (AgNPs) (0.33 mol%) have been studied by varying their Eu2O3 content (0–10 mol%). The structural behavior of these samples was investigated by means of X-ray diffraction (XRD), SEM microscopy, and Fourier transform infrared (FTIR) spectroscopy. The average unit-cell parameters, crystallites size, and the quantitative ratio of the crystallographic phases in the samples were evaluated based on XRD data. FTIR spectroscopy data revealed that the TeO3 and TeO4 are the main structural units of these glass ceramics and their ratio, TeO3/TeO4, changes as function of the europium oxide content and the codoping of the samples. Luminescence spectroscopy measurements evidenced the important peaks located at 438, 550, and 722 nm due to the Pb2+ ions and at 589 and 611 nm due to the Eu3+ ions present in the studied samples. The presence of AgNPs in the studied glass ceramics determines a considerable enhancement of the luminescence bands of Eu3+ ions from 589 and 611 nm.
Vorheriger Artikel Preparation of alginate–CaCl2 microspheres as resveratrol carriers
Nächster Artikel The effect of polyethylenimine on the microwave absorbing properties of a hybrid microwave absorber of Fe3O4/MWNTs

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Metadaten
Titel
Structural and spectroscopic effects of Ag–Eu3+ codoping of TeO2–PbO glass ceramics
verfasst von
Eugen Culea
Ioan Vida-Simiti
Gheorghe Borodi
Eugen Nicolae Culea
Razvan Stefan
Petru Pascuta
Publikationsdatum
01.07.2014
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8164-9

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