Skip to main content
Erschienen in: Journal of Sol-Gel Science and Technology 3/2019

05.07.2019 | Original Paper: Nano-structured materials (particles, fibres, colloids, composites, etc.)

Structural, microstructural, electrical, thermal and non-isothermal degradation kinetic studies on technologically important poly(aniline)/CdO nanocomposites

verfasst von: M. Amita, K. Kiruthiga, S. Mahalakshmi, V. Parthasarathy, Chechia Hu, Yi-Feng Lin, Kuo-Lun Tung, R. Anbarasan

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The main aim of this study was to prepare polyaniline (PANI) nanocomposites. The CdO nanoparticles were obtained by the sol–gel method. The PANI-CdO nanocomposites were synthesized by in situ chemical oxidative polymerization technique. The chemical structure of CdO, PANI and PANI nanocomposites were confirmed by FTIR and XRD techniques. The surface morphology of CdO and PANI nanocomposites was investigated using SEM. The TEM analysis was used to confirm the actual particle size of the CdO nanoparticles. The morphology and surface roughness of the prepared composites were examined with the help of atomic force microscopy. The band gap values of PANI and PANI nanocomposites were determined using Tauc’s plot. The thermal properties of PANI nanocomposites were assessed using thermogravimetric analysis. The non-isothermal degradation kinetic study was carried out to comprehend the degradation rate and determine the energy of activation (Ea). The dc electrical conductivity study was also carried out for the prepared composites.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Seidel KF, Rossi L, Mello RMQ, Hüm- Melgen IM (2012) Vertical organic field effect transistor using sulfonated poly(aniline)/Aluminum bilayer as intermediate electrode. J Mater Sci 24:1052–1056 Seidel KF, Rossi L, Mello RMQ, Hüm- Melgen IM (2012) Vertical organic field effect transistor using sulfonated poly(aniline)/Aluminum bilayer as intermediate electrode. J Mater Sci 24:1052–1056
2.
Zurück zum Zitat Kumar V, Goyal PK, Mahendia S, Gupta R, Sharma T, Kumar S (2011) Tuning of refractive index and optical band gap of CR-39 polymer by heating. Rad Eff Def Solids 166:109–113CrossRef Kumar V, Goyal PK, Mahendia S, Gupta R, Sharma T, Kumar S (2011) Tuning of refractive index and optical band gap of CR-39 polymer by heating. Rad Eff Def Solids 166:109–113CrossRef
3.
Zurück zum Zitat Wan (2008) Conducting polymers with micro or nanometer structure. Tsinghua University Press, Beijing and Springer-Verlag GmbH, Berlin, Heidelberg Wan (2008) Conducting polymers with micro or nanometer structure. Tsinghua University Press, Beijing and Springer-Verlag GmbH, Berlin, Heidelberg
4.
Zurück zum Zitat Wallace GG, Spinks GM, Kane-Maguire LAP, Teasdale PR (2009) Conductive electroactive polymers. Taylor & Francis Group, LLC, Florida Wallace GG, Spinks GM, Kane-Maguire LAP, Teasdale PR (2009) Conductive electroactive polymers. Taylor & Francis Group, LLC, Florida
5.
Zurück zum Zitat Jiang L, Li J, Xu F (2007) Synthesis and ferromagnetic properties of novel Sm-substituted Li,Ni ferrite– polyaniline nanocomposites. Mater Lett 61:109 Jiang L, Li J, Xu F (2007) Synthesis and ferromagnetic properties of novel Sm-substituted Li,Ni ferrite– polyaniline nanocomposites. Mater Lett 61:109
6.
Zurück zum Zitat Srivastava S, Kumar S, Singh VN, Singh M, Vijay VK (2011) Synthesis and characterization of TiO2 doped polyaniline composites for hydrogen gas sensing. Int J Hydro Energ 36:43–55 Srivastava S, Kumar S, Singh VN, Singh M, Vijay VK (2011) Synthesis and characterization of TiO2 doped polyaniline composites for hydrogen gas sensing. Int J Hydro Energ 36:43–55
7.
Zurück zum Zitat Wei D, Ivaska A (2006) Electochemical biosensors based on polyaniline. Part A Chem. Anal 51:39–52 Wei D, Ivaska A (2006) Electochemical biosensors based on polyaniline. Part A Chem. Anal 51:39–52
8.
Zurück zum Zitat Cheng FY, Tang W, Li CS, Chen J, Liu HK, Shen PW, Dou SX (2006) Conducting poly(aniline) nanotubes and nanofibers: controlled synthesis and application in lithium/poly(aniline) rechargeable batteries. Chem Eur J 12:82–88 Cheng FY, Tang W, Li CS, Chen J, Liu HK, Shen PW, Dou SX (2006) Conducting poly(aniline) nanotubes and nanofibers: controlled synthesis and application in lithium/poly(aniline) rechargeable batteries. Chem Eur J 12:82–88
9.
Zurück zum Zitat Deshpande NG, Gudage YG, Sharma R, Vyas JC, Kim JB, Lee YP (2009) Studies on tin oxide-intercalated polyaniline nanocomposite for ammonia gas sensing applications. Sens Actuat 138:76–84CrossRef Deshpande NG, Gudage YG, Sharma R, Vyas JC, Kim JB, Lee YP (2009) Studies on tin oxide-intercalated polyaniline nanocomposite for ammonia gas sensing applications. Sens Actuat 138:76–84CrossRef
10.
Zurück zum Zitat Katz E, Willner I, Wang J (2004) Electroanalytical and bioelectroanalytical systems based on metal and semiconductor nanoparticles. Electroanal 16:19–44CrossRef Katz E, Willner I, Wang J (2004) Electroanalytical and bioelectroanalytical systems based on metal and semiconductor nanoparticles. Electroanal 16:19–44CrossRef
11.
Zurück zum Zitat Balaz AC, Emric T, Russel T (2006) Nanoparticle polymer composites: where two small worlds meet. Nanopart Sci 314:7–10 Balaz AC, Emric T, Russel T (2006) Nanoparticle polymer composites: where two small worlds meet. Nanopart Sci 314:7–10
12.
Zurück zum Zitat Chen X, Qi S (2017) Preparation and microwave absorbing properties of poly(aniline)/NiFe2O4/graphite nanosheet composites via sol–gel reaction and insitu polymerization. J Sol-Gel Sci Technol 81:824–830CrossRef Chen X, Qi S (2017) Preparation and microwave absorbing properties of poly(aniline)/NiFe2O4/graphite nanosheet composites via sol–gel reaction and insitu polymerization. J Sol-Gel Sci Technol 81:824–830CrossRef
13.
Zurück zum Zitat Bavastrello V, Carrara S, Ram MK, Nicolin C (2004) Optical and electrochemical properties of poly(o-toluidine) multiwalled carbon nanotubes composite Langmuir-Schaefer films. Langmuir 20:969–973 Bavastrello V, Carrara S, Ram MK, Nicolin C (2004) Optical and electrochemical properties of poly(o-toluidine) multiwalled carbon nanotubes composite Langmuir-Schaefer films. Langmuir 20:969–973
14.
Zurück zum Zitat Liu A, Bac LH, Kim BK, Kim JS, Kim JC (2013) Synthesis and characterization of conducting polyaniline-copper composites. J Nanosci Nanotechnol 13:7728–7733CrossRef Liu A, Bac LH, Kim BK, Kim JS, Kim JC (2013) Synthesis and characterization of conducting polyaniline-copper composites. J Nanosci Nanotechnol 13:7728–7733CrossRef
15.
Zurück zum Zitat Ingle RV, Arote SA, Rajendra Prasad MB, Kadam VS, Mane RS, Inamuddin Mu, Naushad, Tabhane VA, Pathan HM (2014) Studies on facile synthesis of polyaniline/cadmium sulfide composites and their morphology. High Perform Polym 26:660–665CrossRef Ingle RV, Arote SA, Rajendra Prasad MB, Kadam VS, Mane RS, Inamuddin Mu, Naushad, Tabhane VA, Pathan HM (2014) Studies on facile synthesis of polyaniline/cadmium sulfide composites and their morphology. High Perform Polym 26:660–665CrossRef
16.
Zurück zum Zitat Nagesa Sastry D, Revanasiddappa M, Basavraja C, Suresh T, Raghavebdra SC (2013) DC conductivity studies of doped polyaniline tungsten oxide. J Eng Mater Sci 20:435–442 Nagesa Sastry D, Revanasiddappa M, Basavraja C, Suresh T, Raghavebdra SC (2013) DC conductivity studies of doped polyaniline tungsten oxide. J Eng Mater Sci 20:435–442
17.
Zurück zum Zitat Sravani C, Reddy KTR, Md. Hussain O, Reddy PJ (1996) Polycrystalline thin film CdO/CdTe solar cells. J Solar Energy Soc India 6:1–9 Sravani C, Reddy KTR, Md. Hussain O, Reddy PJ (1996) Polycrystalline thin film CdO/CdTe solar cells. J Solar Energy Soc India 6:1–9
18.
Zurück zum Zitat Zhao Z, Morel DL, Ferekides CS (2002) Metal–organic chemical vapour deposition of thin films of cobalt on different substrates: study of microstructure. Thin Solid Films 413:203–211CrossRef Zhao Z, Morel DL, Ferekides CS (2002) Metal–organic chemical vapour deposition of thin films of cobalt on different substrates: study of microstructure. Thin Solid Films 413:203–211CrossRef
19.
Zurück zum Zitat Aashis Roy S, Koppalkar R, Anilkumar MVN, Ambika P (2012) Studies of AC conductivity and dielectric relaxation behavior of CdO-doped nanometric polyaniline. J Appl Polym Sci 123:928–1934 Aashis Roy S, Koppalkar R, Anilkumar MVN, Ambika P (2012) Studies of AC conductivity and dielectric relaxation behavior of CdO-doped nanometric polyaniline. J Appl Polym Sci 123:928–1934
20.
Zurück zum Zitat Mahalakshmi S, Alagesan T, Parthasarathy V, Tung KL, Anbarasan R (2018) Non-isothermal crystallization kinetics and degradation kinetics studies on barium thioglycolate end-capped poly(ε-caprolactone). J Therm Anal Calorim 135:3129–3140 Mahalakshmi S, Alagesan T, Parthasarathy V, Tung KL, Anbarasan R (2018) Non-isothermal crystallization kinetics and degradation kinetics studies on barium thioglycolate end-capped poly(ε-caprolactone). J Therm Anal Calorim 135:3129–3140
21.
Zurück zum Zitat Selvi J, Mahalakshmi S, Parthasarathy V (2017) Synthesis, structural, optical, electrical and thermal studies of poly(vinyl alcohol)/CdO nanocomposite films. J Inorg Organomet Polym 27:1918–1926CrossRef Selvi J, Mahalakshmi S, Parthasarathy V (2017) Synthesis, structural, optical, electrical and thermal studies of poly(vinyl alcohol)/CdO nanocomposite films. J Inorg Organomet Polym 27:1918–1926CrossRef
22.
Zurück zum Zitat Tauc J, Grigorovici R, Vancu A (1966) Optical properties and electronic structure of amorphous germanium. Physica Status Solidi 15:627–637CrossRef Tauc J, Grigorovici R, Vancu A (1966) Optical properties and electronic structure of amorphous germanium. Physica Status Solidi 15:627–637CrossRef
23.
Zurück zum Zitat Jancirani A, Kohila V, Meenarathi B, Yelilarasi A, Anbarasan R (2016) Synthesis, characterisation and non-isothermal degradation kinetics of novel poly(mono ethylene glycol dimethacrylate-co-4-aminobenzoate). Bull Mater Sci 39:1725–1733CrossRef Jancirani A, Kohila V, Meenarathi B, Yelilarasi A, Anbarasan R (2016) Synthesis, characterisation and non-isothermal degradation kinetics of novel poly(mono ethylene glycol dimethacrylate-co-4-aminobenzoate). Bull Mater Sci 39:1725–1733CrossRef
24.
Zurück zum Zitat Anbarasan R, Seethalakshmi M, Maria Franklin Dheepa A, Jayalakshmi T, Dhanalakshmi V (2013) Synthesis and characterization of CdO nanorod by Ultrasound assisted one pot method and its surface catalytic effect on poly(vinyl alcohol). Ind J Sci 2:121–123 Anbarasan R, Seethalakshmi M, Maria Franklin Dheepa A, Jayalakshmi T, Dhanalakshmi V (2013) Synthesis and characterization of CdO nanorod by Ultrasound assisted one pot method and its surface catalytic effect on poly(vinyl alcohol). Ind J Sci 2:121–123
25.
Zurück zum Zitat Aijie L, Luong Huu B, Ji-Soon K, Byoung-Kee K, Jin-Chun K (2013) Synthesis and characterization of conducting polyaniline-copper composites. J Nanosci Technol 13:7728–7733 Aijie L, Luong Huu B, Ji-Soon K, Byoung-Kee K, Jin-Chun K (2013) Synthesis and characterization of conducting polyaniline-copper composites. J Nanosci Technol 13:7728–7733
26.
Zurück zum Zitat Aldwayyan AS, Jekhedab FM, Noaimi MA, Hammouti B, Hadda TB, Suleiman M, Warad I (2013) Synthesis and characterization of CdO nanoparticles starting from organometallic Dmphen-CdI2 complex. Int J Electrochem Sci 8:10506–10514 Aldwayyan AS, Jekhedab FM, Noaimi MA, Hammouti B, Hadda TB, Suleiman M, Warad I (2013) Synthesis and characterization of CdO nanoparticles starting from organometallic Dmphen-CdI2 complex. Int J Electrochem Sci 8:10506–10514
27.
Zurück zum Zitat Wang Y, Liu M, Lu D, Zhang H (2019) Electrospun porous hybrid CuO/CdO nanofibers using carboxylic functionalized poly(arylene ether ketone)s as a template for glucose determination. High Perform Polym 31:570–579CrossRef Wang Y, Liu M, Lu D, Zhang H (2019) Electrospun porous hybrid CuO/CdO nanofibers using carboxylic functionalized poly(arylene ether ketone)s as a template for glucose determination. High Perform Polym 31:570–579CrossRef
28.
Zurück zum Zitat Almasi MJ, Fanaei Sheikholeslami T, Naghdi MR (2016) Band Gap study of Polyaniline and polyaniline/MWNT nanocomposites with insitu polymerization method. Composites Part B 96:63–68CrossRef Almasi MJ, Fanaei Sheikholeslami T, Naghdi MR (2016) Band Gap study of Polyaniline and polyaniline/MWNT nanocomposites with insitu polymerization method. Composites Part B 96:63–68CrossRef
29.
Zurück zum Zitat Yoffe AD (1993) Low-dimensional systems: quantum size effects and electronic properties of semiconductor microcrystallites (zerodimensional systems) and some quasi-two dimensional systems. Adv Phys 42:173–262CrossRef Yoffe AD (1993) Low-dimensional systems: quantum size effects and electronic properties of semiconductor microcrystallites (zerodimensional systems) and some quasi-two dimensional systems. Adv Phys 42:173–262CrossRef
30.
Zurück zum Zitat Rastogi AC, Sharma SN, Kohli S (2000) Size-dependent optical edge shifts and electrical conduction behaviour of RF magnetron sputtered CdTe nanocrystals:TiO2 composite thin films. Semicond Sci Technol 15:1011CrossRef Rastogi AC, Sharma SN, Kohli S (2000) Size-dependent optical edge shifts and electrical conduction behaviour of RF magnetron sputtered CdTe nanocrystals:TiO2 composite thin films. Semicond Sci Technol 15:1011CrossRef
31.
Zurück zum Zitat Ramna T, Alo D, Sayantani D, Akhilesh K, Sinha TP (2016) Dielectric relaxation of CdO nanoparticles. Appl Nanosci 6:175–181CrossRef Ramna T, Alo D, Sayantani D, Akhilesh K, Sinha TP (2016) Dielectric relaxation of CdO nanoparticles. Appl Nanosci 6:175–181CrossRef
32.
Zurück zum Zitat Ramesh P, Aashis. S, Roy R, Koppalkar, Srikant E (2011) Electrical conductivity of polyaniline/NiZnO3 composites: A solid state electrolyte. Ferroelectrics 423:77–85CrossRef Ramesh P, Aashis. S, Roy R, Koppalkar, Srikant E (2011) Electrical conductivity of polyaniline/NiZnO3 composites: A solid state electrolyte. Ferroelectrics 423:77–85CrossRef
33.
Zurück zum Zitat Eskizeybek V, Avci A, Chhowalla M (2011) Structural and optical properties of CdO nanowires synthesized from Cd(OH)2 precursors by calcination. Cryst Res Technol 46:1093–1100CrossRef Eskizeybek V, Avci A, Chhowalla M (2011) Structural and optical properties of CdO nanowires synthesized from Cd(OH)2 precursors by calcination. Cryst Res Technol 46:1093–1100CrossRef
34.
Zurück zum Zitat Daikh S, Zeggai FZ, Bellil A, Benyoucef A (2018) Chemical polymerization, characterization and electrochemical studies of PANI/ZnO doped with hydrochloric acid and/or zinc chloride: Differences between the synthesized nanocomposites. J Phys Chem Solids 121:78–84CrossRef Daikh S, Zeggai FZ, Bellil A, Benyoucef A (2018) Chemical polymerization, characterization and electrochemical studies of PANI/ZnO doped with hydrochloric acid and/or zinc chloride: Differences between the synthesized nanocomposites. J Phys Chem Solids 121:78–84CrossRef
35.
Zurück zum Zitat Bauri K, Roy SG, Arora S, Dey RK, Goswami A, Madras G, De P (2013) Thermaldegradation kinetics of thermoresponsive poly(N-isopropylacrylamide-co-N,N-dimethylacrylamide) copolymers prepared via RAFT polymerization. J Therm Anal Calorim 111:753–761CrossRef Bauri K, Roy SG, Arora S, Dey RK, Goswami A, Madras G, De P (2013) Thermaldegradation kinetics of thermoresponsive poly(N-isopropylacrylamide-co-N,N-dimethylacrylamide) copolymers prepared via RAFT polymerization. J Therm Anal Calorim 111:753–761CrossRef
Metadaten
Titel
Structural, microstructural, electrical, thermal and non-isothermal degradation kinetic studies on technologically important poly(aniline)/CdO nanocomposites
verfasst von
M. Amita
K. Kiruthiga
S. Mahalakshmi
V. Parthasarathy
Chechia Hu
Yi-Feng Lin
Kuo-Lun Tung
R. Anbarasan
Publikationsdatum
05.07.2019
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2019
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-019-05060-w

Weitere Artikel der Ausgabe 3/2019

Journal of Sol-Gel Science and Technology 3/2019 Zur Ausgabe

Original Paper: Sol-gel and hybrid materials for biological and health (medical) applications

The impact of copper oxide nanoparticles on the structure and applicability of bioactive glasses

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Synthesis of nitrogen- and cobalt-doped rod-like mesoporous ZnO nanostructures to study their photocatalytic activity

Brief Communication: Nano-structured materials (particles, fibers, colloids, composites, etc.)

A facile method for the fabrication of SiO2 and SiO2/TiO2 hollow particles using Na2SO4 particles as templates

Original Paper: Characterization methods of sol-gel and hybrid materials

Study of a silicon-based preceramic for the processing of polymer-derived ceramics

Original Paper: Industrial and technological applications of sol–gel and hybrid materials

Study on the surface quality of marble tiles polished with Sol-Gel derived pads

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.