nach oben

Journal of Materials Science

Erschienen in:

25.02.2024 | Chemical routes to materials

Studies on elimination of nutrients from aqueous effluents using ZnO nanoparticles: the case of ammonium as a model. Experimental and theoretical insights

verfasst von: María Belén Perez Adassus, Herman Heffner, Ignacio López-Corral, Carla Spetter, Verónica Lassalle

Erschienen in: Journal of Materials Science | Ausgabe 8/2024

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The presence of ammonium (NH₄⁺) in natural waters has increased in the last years due to the rising use of agricultural fertilizers, industrial activity and sewage discharges without any decontamination treatment. The great amounts of this inorganic cation in water bodies have been considered an environmental problem, due to its influence on the eutrophication process which leads to the deterioration of water quality. The application of ZnO nanoparticles to assess nutrient elimination, including ammonium, from water bodies has not been exhaustively studied. In this work, the capability of ZnO nanoparticles to remove ammonium cation from aqueous samples induced by adsorption is investigated. In this regards, experiments tending to determine the efficiency of nanomaterials have been performed employing two different NH₄⁺ concentrations aiming to replicate two feasible real water-impacted environments. The interactions between adsorbent and adsorbate have been explored by employing experimental characterization techniques as well as theoretical DFT simulations. The achieved data demonstrated that the efficiency of ZnONPs shows a dependency on the ammonium concentration, ranging between 0.79 and 11.6 mg of ammonium adsorbed per gram of ZnONPs. According to the data on characterization prior and post adsorption of the ZnO nanomaterials the electrostatic interaction would not be favored, being the coordination ones the most feasible as suggested experimental and DFT results.

Graphical Abstract

Vorheriger Artikel Well-established carbon nanomaterials: modification, characterization and dispersion in different solvents

Nächster Artikel Pyridinic N and semi-ionic F Co-functionalized biochar nanofibers as efficient metal-free electrocatalysts for oxygen reduction reaction

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Bock G (2016) Removal of high and low levels of ammonium from industrial wastewaters, Prof Pap 94.

Yin Q, Si L, Wang R, Zhao Z, Li H, Wen Z (2022) DFT study on the effect of functional groups of carbonaceous surface on ammonium adsorption from water. Chemosphere 287:132294. https://doi.org/10.1016/j.chemosphere.2021.132294CrossRefPubMed

Karri RR, Sahu JN, Chimmiri V (2018) Critical review of abatement of ammonia from wastewater. J Mol Liq 261:21–31. https://doi.org/10.1016/j.molliq.2018.03.120CrossRef

Spetter CV, Popovich CA, Arias A, Asteasuain RO, Freije RH, Marcovecchio JE (2015) Role of nutrients in phytoplankton development during a winter diatom bloom in a Eutrophic South American Estuary (Bahía Blanca, Argentina). J Coast Res 31:76–87. https://doi.org/10.2112/JCOASTRES-D-12-00251.1CrossRef

Bricker SB, Longstaff B, Dennison W, Jones A, Boicourt K, Wicks C, Woerner J (2008) Effects of nutrient enrichment in the nation’s estuaries: a decade of change. Harmful Algae 8:21–32. https://doi.org/10.1016/j.hal.2008.08.028CrossRef

Ferreira JG, Andersen JH, Borja A, Bricker SB, Camp J, Cardoso da Silva M, Garcés E, Heiskanen AS, Humborg C, Ignatiades L, Lancelot C, Menesguen A, Tett P, Hoepffner N, Claussen U (2011) Overview of eutrophication indicators to assess environmental status within the European marine strategy framework directive. Estuar Coast Shelf Sci 93:117–131. https://doi.org/10.1016/j.ecss.2011.03.014ADSCrossRef

Muruganandham M, Zhang Y, Suri R, Lee GJ, Chen PK, Hsieh SH, Sillanpää M, Wu JJ (2015) Environmental applications of ZnO materials. J Nanosci Nanotechnol 15:6900–6913. https://doi.org/10.1166/jnn.2015.10725CrossRefPubMed

Alshameri A, He H, Zhu J, Xi Y, Zhu R, Ma L, Tao Q (2018) Adsorption of ammonium by different natural clay minerals: characterization, kinetics and adsorption isotherms. Appl Clay Sci 159:83–93. https://doi.org/10.1016/j.clay.2017.11.007CrossRef

Ong CB, Ng LY, Mohammad AW (2018) A review of ZnO nanoparticles as solar photocatalysts: synthesis, mechanisms and applications. Renew Sustain Energy Rev 81:536–551. https://doi.org/10.1016/j.rser.2017.08.020CrossRef

10.

Sood AK, Wang ZL, Polla DL, Dhar NK, Manzur T, Anwar AFM (2011) ZnO nanostructures for optoelectronic applications. Optoelectron Devices Prop. https://doi.org/10.5772/16202CrossRef

11.

Tripathi S, Roy A, Nair S, Durani S, Bose R (2018) Removal of U(VI) from aqueous solution by adsorption onto synthesized silica and zinc silicate nanotubes: equilibrium and kinetic aspects with application to real samples. Environ. Nanotechnol Monit Manag 10:127–139. https://doi.org/10.1016/j.enmm.2018.05.003CrossRef

12.

Choina J, Bagabas A, Fischer C, Flechsig GU, Kosslick H, Alshammari A, Schulz A (2015) The influence of the textural properties of ZnO nanoparticles on adsorption and photocatalytic remediation of water from pharmaceuticals. Catal Today 241:47–54. https://doi.org/10.1016/j.cattod.2014.05.014CrossRef

13.

Beegam A, Prasad P, Jose J, Oliveira M, Costa FG, Soares AMVM, Gonçalves PP, Trindade T, Kalarikkal N, Thomas S, de Pereira DL (2016) Environmental fate of zinc oxide nanoparticles: risks and benefits. Toxicol-New Asp This Sci Conundrum. https://doi.org/10.5772/65266CrossRef

14.

Tatagar AM, Moodi JI, Abbar JC, Phaniband MA (2021) Photocatalytic activity and anti-microbial application of synthesized Zinc oxide nanoparticles (ZnO Nps) towards remediation of hospital waste water (HWW). Mater Today Proc 49:699–702. https://doi.org/10.1016/j.matpr.2021.05.176CrossRef

15.

Bhattacharya P, Mukherjee D, Deb N, Swarnakar S, Banerjee S (2020) Application of green synthesized ZnO nanoparticle coated ceramic ultrafiltration membrane for remediation of pharmaceutical components from synthetic water: reusability assay of treated water on seed germination. J Environ Chem Eng 8:103803. https://doi.org/10.1016/j.jece.2020.103803CrossRef

16.

Tsyshevsky R, Holdren S, Eichhorn BW, Zachariah MR, Kuklja MM (2019) Sarin decomposition on pristine and hydroxylated ZnO : quantum–chemical modeling. J Phys Chem C. https://doi.org/10.1021/acs.jpcc.9b07974CrossRef

17.

Sowik J, Miodyńska M, Bajorowicz B, Mikołajczyk A, Lisowski W, Klimczuk T, Kaczor D, Zaleska A, Malankowska A (2018) Optical and photocatalytic properties of rare earth metal-modified ZnO quantum dots. Appl Surf Sci. https://doi.org/10.1016/j.apsusc.2018.09.104CrossRef

18.

Abdulkhair B, Salih M, Modwi A, Adam F, Elamin N, Seydou M, Rahali S (2020) Adsorption behavior of barium ions onto ZnO surfaces : experiments associated with DFT calculations. J Mol Struct 1223:128991. https://doi.org/10.1016/j.molstruc.2020.128991CrossRef

19.

Dehmani Y, Lgaz H, Alrashdi AA, Lamhasni T, Abouarnadasse S, Chung I (2020) Phenol adsorption mechanism on the zinc oxide surface: experimental, cluster DFT calculations, and molecular dynamics simulations. J Mol Liq 324:114993. https://doi.org/10.1016/j.molliq.2020.114993CrossRef

20.

Perez Adassus M, Spetter CV, Lassalle VL (2022) Biofabrication of ZnO nanoparticles from Sarcocornia ambigua as novel natural source: A comparative analysis regarding traditional chemical preparation and insights on their photocatalytic activity. J Mol Struct. 1256:132460. https://doi.org/10.1016/J.MOLSTRUC.2022.132460CrossRef

21.

Seruga P, Krzywonos M, Pyzanowska J, Urbanowska A, Pawlak-Kruczek H, Niedźwiecki Ł (2019) Removal of ammonia from the municipal waste treatment effuents using natural minerals. Molecules 24:3633. https://doi.org/10.3390/molecules24203633CrossRefPubMedPubMedCentral

22.

Spetter CV, Buzzi NS, Fernández EM, Cuadrado DG, Marcovecchio JE (2015) Assessment of the physicochemical conditions sediments in a polluted tidal flat colonized by microbial mats in Bahía Blanca Estuary (Argentina). Mar Pollut Bull 91:491–505. https://doi.org/10.1016/j.marpolbul.2014.10.008CrossRefPubMed

23.

Ordejo P, Artacho E (1996) Self-consistent order- N density-functional calculations for very large systems. Phys Rev B 53:441–444

24.

Soler M, Artacho E, Gale JD, Garc A, Junquera J, Ordej P, Daniel S (2002) Related content The SIESTA method for ab initio order-N materials simulation The SIESTA method for ab initio order- N materials. J Phys Condensed Matter 14(11):2745ADSCrossRef

25.

Perdew JP, Burke K, Ernzerhof M (1996) Generalized gradient approximation made simple. Phys Rev Lett 77(18):3865ADSCrossRefPubMed

26.

Troullier JL, Martins N (1991) Efficient pseudopotentials for plane-wave calculations. Phys Rev 8:43

27.

Dudarev SL, Botton GA, Savrasov SY, Humphreys CJ, Sutton AP (1998) Electron-energy-loss spectra and the structural stability of nickel oxide. Phys Rev B 57:1505–1509ADSCrossRef

28.

Kumar R, Sharma A (2022) Ferromagnetism in V and Cr doped ScN diluted magnetic semiconductor in B3 phase: a DFT study. Solid State Commun 347:114724. https://doi.org/10.1016/j.ssc.2022.114724CrossRef

29.

Kaur S, Kaur K, Sharma S, Rani A (2020) Materials today : Proceedings emergence of ferrromagnetism in vanadium doped aluminium phosphide using density functional theory. Mater Today Proc. 28:1820–1824. https://doi.org/10.1016/j.matpr.2020.05.260CrossRef

30.

Khan AA (1968) X-ray determination of thermal expansion of zinc oxide. Acta Cryst 403:52. https://doi.org/10.1107/S0567739468000793CrossRef

31.

Abrahams SC, Bernstein JL (1969) Relneasurement of the Structure of Hexagonal ZnO The integrated intensities of 374 reflections, resulting in 141 independent Fracas, were determined. The structure was refined by the method of least squares : the final agreement index R was 0 " 0378. Acta Cryst 25:1233–1236. https://doi.org/10.1107/S0567740869003876CrossRef

32.

Ruckh M, Schmid D, Schock HW (1994) Photoemission studies of the ZnO/CdS interface. J Appl Phys 76:5945–5948. https://doi.org/10.1063/1.358417ADSCrossRef

33.

Ma X, Wu Y, Lv Y, Zhu Y (2013) Correlation effects on lattice relaxation and electronic structure of ZnO within the GGA + U formalism. J Phys Chem C 117(49):26029–26039. https://doi.org/10.1021/jp407281xCrossRef

34.

Zhang H, Lu S, Xu W, Yuan F (2014) Surface science first-principles study of Si atoms adsorbed on ZnO (0001) surface and the effect on electronic and optical properties. Surf Sci 625:30–36. https://doi.org/10.1016/j.susc.2014.03.003ADSCrossRef

35.

Momma K, Izumi F (2011) VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data. J Appl Crystallogr. 44:1272–1276. https://doi.org/10.1107/S0021889811038970ADSCrossRef

36.

Scheverin VN, Russo A, Grünhut M, Horst MF, Jacobo S, Lassalle VL (2022) Novel iron-based nanocomposites for arsenic removal in groundwater: insights from their synthesis to implementation for real groundwater remediation. Environ Earth Sci 81:1–15. https://doi.org/10.1007/s12665-022-10286-zCrossRef

37.

Harun K, Salleh NA, Deghfel B, Yaakob MK, Mohamad AA (2020) DFT + U calculations for electronic, structural, and optical properties of ZnO wurtzite structure: a review. Results Phys 16:102829. https://doi.org/10.1016/j.rinp.2019.102829CrossRef

38.

Sharma D, Jha R (2017) Analysis of structural, optical and magnetic properties of Fe/Co co-doped ZnO nanocrystals. Ceram Int 43:8488–8496. https://doi.org/10.1016/j.ceramint.2017.03.201CrossRef

39.

Saffari J, Mir N, Ghanbari D, Khandan-Barani K, Hassanabadi A, Hosseini-Tabatabaei MR (2015) Sonochemical synthesis of Fe3O4/ZnO magnetic nanocomposites and their application in photo-catalytic degradation of various organic dyes. J Mater Sci Mater Electron 26:9591–9599. https://doi.org/10.1007/s10854-015-3622-yCrossRef

40.

Geurts J (2010) Crystal structure, chemical binding, and lattice properties. Springer Ser Mater Sci 120:7–37. https://doi.org/10.1007/978-3-642-10577-7_2CrossRef

41.

Vaseem M, Umar A, Hahn Y (2010) ZnO nanoparticles: growth, properties, and applications. Metal Oxide Nanostruct Appl 5(1):10–20

42.

Gaffuri P, Dedova T, Appert E, Danilson M, Baillard A, Chaix-Pluchery O, Güell F, Oja-Acik I, Consonni V (2022) Enhanced photocatalytic activity of chemically deposited ZnO nanowires using doping and annealing strategies for water remediation. Appl Surf Sci 582:152323. https://doi.org/10.1016/j.apsusc.2021.152323CrossRef

43.

Azcona P, Zysler R, Lassalle V (2016) Simple and novel strategies to achieve shape and size control of magnetite nanoparticles intended for biomedical applications. Colloids Surfaces A Physicochem Eng Asp 504:320–330. https://doi.org/10.1016/j.colsurfa.2016.05.064CrossRef

44.

Marsalek R (2014) Particle size and zeta potential of ZnO. APCBEE Proc 9:13–17. https://doi.org/10.1016/j.apcbee.2014.01.003CrossRef

45.

Fatehah MO, Aziz HA, Stoll S (2014) Stability of ZnO nanoparticles in solution. Influence of pH, dissolution, aggregation and disaggregation effects. J Colloid Sci Biotechnol 3:75–84. https://doi.org/10.1166/jcsb.2014.1072CrossRef

46.

Yashni G, Al-Gheethi A, Mohamed R, Al-Sahari M (2021) Reusability performance of green zinc oxide nanoparticles for photocatalysis of bathroom greywater. Water Pract Technol 16:364–376. https://doi.org/10.2166/wpt.2020.118CrossRef

47.

Hu SB, Li L, Luo MY, Yun YF, Chang CT (2017) Aqueous norfloxacin sonocatalytic degradation with multilayer flower-like ZnO in the presence of peroxydisulfate. Ultrason Sonochem 38:446–454. https://doi.org/10.1016/j.ultsonch.2017.03.044CrossRefPubMed

48.

Adam RE, Pozina G, Willander M, Nur O (2018) Synthesis of ZnO nanoparticles by co-precipitation method for solar driven photodegradation of Congo red dye at different pH. Photonics Nanostruct Fundam Appl 32:11–18. https://doi.org/10.1016/j.photonics.2018.08.005ADSCrossRef

49.

Zhang F, Chen X, Wu F, Ji Y (2016) High adsorption capability and selectivity of ZnO nanoparticles for dye removal. Colloids Surf Physicochem Eng Asp 509:474–483. https://doi.org/10.1016/j.colsurfa.2016.09.059CrossRef

50.

Dhiman V, Kondal N (2021) ZnO Nanoadsorbents: a potent material for removal of heavy metal ions from wastewater. Colloids Interface Sci Commun 41:100380. https://doi.org/10.1016/j.colcom.2021.100380CrossRef

51.

Akpomie KG, Conradie J, Adegoke KA, Oyedotun KO, Ighalo JO, Amaku JF, Olisah C, Adeola AO, Iwuozor KO (2023) Adsorption mechanism and modeling of radionuclides and heavy metals onto ZnO nanoparticles: a review. Appl Water Sci 13:1–24. https://doi.org/10.1007/s13201-022-01827-9CrossRef

52.

Zhou SL, Zhang S, Liu F, Liu JJ, Xue JJ, Yang DJ, Chang CT (2016) ZnO nanoflowers photocatalysis of norfloxacin: effect of triangular silver nanoplates and water matrix on degradation rates. J Photochem Photobiol A Chem 328:97–104. https://doi.org/10.1016/j.jphotochem.2016.03.037CrossRef

53.

Nguyen LH, Van HT, Chu THH, Nguyen THV, Nguyen TD, Hoang LP, Hoang VH (2021) Paper waste sludge-derived hydrochar modified by iron (III) chloride for enhancement of ammonium adsorption: an adsorption mechanism study. Environ Technol Innov 21:101223. https://doi.org/10.1016/j.eti.2020.101223CrossRef

54.

Gao F, Xue Y, Deng P, Cheng X, Yang K (2015) Removal of aqueous ammonium by biochars derived from agricultural residuals at different pyrolysis temperatures. Chem Speciat Bioavailab 27:92–97. https://doi.org/10.1080/09542299.2015.1087162CrossRef

55.

Freije RH, Spetter CV, Marcovecchio JE, Popovich CA, Arias A, Asteasuain RO (2008) Water chemistry and nutrients of the Bahía Blanca Estuary. In: Neves R, Baretta J, Mateus M (eds) Perspectives on integrated coastal zone management in south america, IST Press, Lisboa, Portugal, Pp 241–254

56.

Kizito S, Wu S, Kipkemoi Kirui W, Lei M, Lu Q, Bah H, Dong R (2015) Evaluation of slow pyrolyzed wood and rice husks biochar for adsorption of ammonium nitrogen from piggery manure anaerobic digestate slurry. Sci Total Environ 505:102–112. https://doi.org/10.1016/j.scitotenv.2014.09.096ADSCrossRefPubMed

57.

Zhang M, Zhang H, Xu D, Han L, Niu D, Tian B, Zhang J, Zhang L, Wu W (2011) Removal of ammonium from aqueous solutions using zeolite synthesized from fly ash by a fusion method. Desalination 271:111–121. https://doi.org/10.1016/j.desal.2010.12.021CrossRef

58.

Li S, Barreto V, Li R, Chen G, Hsieh YP (2018) Nitrogen retention of biochar derived from different feedstocks at variable pyrolysis temperatures. J Anal Appl Pyrolysis 133:136–146. https://doi.org/10.1016/j.jaap.2018.04.010CrossRef

59.

Liu H, Dong Y, Wang H, Liu Y (2010) Adsorption behavior of ammonium by a bioadsorbent–Boston ivy leaf powder. J Environ Sci 22:1513–1518. https://doi.org/10.1016/S1001-0742(09)60282-5CrossRef

60.

Jafari A, Keramat Amirkolaie A, Oraji H, Kousha M (2020) Bio-sorption of ammonium ions by dried red marine algae (Gracilaria persica): application of response surface methodology. Iran J Fish Sci 19:1967–1980. https://doi.org/10.22092/ijfs.2018.124017.1006CrossRef

61.

Wahab MA, Jellali S, Jedidi N (2010) Ammonium biosorption onto sawdust: FTIR analysis, kinetics and adsorption isotherms modeling. Bioresour Technol 101:5070–5075. https://doi.org/10.1016/j.biortech.2010.01.121CrossRefPubMed

62.

Tang Y, Alam MS, Konhauser KO, Alessi DS, Xu S, Tian WJ, Liu Y (2019) Influence of pyrolysis temperature on production of digested sludge biochar and its application for ammonium removal from municipal wastewater. J Clean Prod 209:927–936. https://doi.org/10.1016/j.jclepro.2018.10.268CrossRef

63.

Begum SA, Golam Hyder AHM, Hicklen Q, Crocker T, Oni B (2021) Adsorption characteristics of ammonium onto biochar from an aqueous solution. J Water Supply Res Technol - AQUA 70:113–122. https://doi.org/10.2166/aqua.2020.062CrossRef

64.

Wang B, Lehmann J, Hanley K, Hestrin R, Enders A (2015) Adsorption and desorption of ammonium by maple wood biochar as a function of oxidation and pH. Chemosphere 138:120–126. https://doi.org/10.1016/j.chemosphere.2015.05.062ADSCrossRefPubMed

65.

Gu M, Hao L, Wang Y, Li X, Chen Y, Li W, Jiang L (2020) The selective heavy metal ions adsorption of zinc oxide nanoparticles from dental wastewater. Chem Phys 534:110750. https://doi.org/10.1016/j.chemphys.2020.110750CrossRef

66.

Dantas MS, de Morais Silva LF, Utida Novaes HH, Oliveira SC (2022) Municipal wastewater discharge standards for ammonia nitrogen in Brazil: technical elements to guide decisions. Water Sci Technol 85:3479–3492. https://doi.org/10.2166/wst.2022.183CrossRefPubMed

67.

Zhang W, Wang Z, Liu Y, Feng J, Han J, Yan W (2021) Effective removal of ammonium nitrogen using titanate adsorbent: capacity evaluation focusing on cation exchange. Sci Total Environ 771:144800. https://doi.org/10.1016/j.scitotenv.2020.144800ADSCrossRefPubMed

68.

Lin L, Lei Z, Wang L, Liu X, Zhang Y, Wan C, Lee DJ, Tay JH (2013) Adsorption mechanisms of high-levels of ammonium onto natural and NaCl-modified zeolites. Sep Purif Technol 103:15–20. https://doi.org/10.1016/j.seppur.2012.10.005CrossRef

69.

Abukhadra MR, Mostafa M (2019) Effective decontamination of phosphate and ammonium utilizing novel muscovite/phillipsite composite; equilibrium investigation and realistic application. Sci Total Environ 667:101–111. https://doi.org/10.1016/j.scitotenv.2019.02.362ADSCrossRefPubMed

70.

Liu P, Liu Y, Zhang A, Liu Z, Liu X, Yang L (2022) Adsorption mechanism of high-concentration of ammonium onto chinese natural zeolite by experimental optimization and theoretical computation. Water 14:2413. https://doi.org/10.3390/w14152413CrossRef

71.

Dunn ME, Shields GC (2005) Comparison of model chemistry and density functional theory thermochemical predictions with experiment for formation of ionic clusters of the ammonium cation complexed with water and ammonia; atmospheric implications. J Phys Chem A 4905:4910. https://doi.org/10.1021/jp0514372CrossRef

72.

Rozenberg M, Shoham G (2007) FTIR spectra of solid poly-l-lysine in the stretching NH mode range. Biophys Chem 125:166–171. https://doi.org/10.1016/j.bpc.2006.07.008CrossRefPubMed

73.

Zazoua H, Boudjemaa A, Chebout R, Bachari K (2014) Enhanced photocatalytic hydrogen production under visible light over a material based on magnesium ferrite derived from layered double hydroxides (LDHs). Int J Energy Res. https://doi.org/10.1002/er.3215CrossRef

74.

Wang S, Ai S, Nzediegwu C, Kwak JH, Islam MS, Li Y, Chang SX (2020) Carboxyl and hydroxyl groups enhance ammonium adsorption capacity of iron (III) chloride and hydrochloric acid modified biochars. Bioresour Technol 309:123390. https://doi.org/10.1016/j.biortech.2020.123390CrossRefPubMed

Titel: Studies on elimination of nutrients from aqueous effluents using ZnO nanoparticles: the case of ammonium as a model. Experimental and theoretical insights
verfasst von: María Belén Perez Adassus
Herman Heffner
Ignacio López-Corral
Carla Spetter
Verónica Lassalle
Publikationsdatum: 25.02.2024
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 8/2024
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-024-09421-x

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Graphical Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 8/2024

High energy storage properties of Nd(Mg2/3Nb1/3)O3 modified Bi0.5Na0.5TiO3 lead-free ceramics

Polydopamine adhesion of MXenes to cotton fabric for solar thermal and passive radiative heating

Gradient microporous layer with controllable aperture for high-performance proton-exchange membrane fuel cells

Composition tuning of CdSeXS1−X nanocrystals for enhancing the photovoltaic performance of CdS/CdSeXS1−X quantum dot-sensitized solar cells

Utilizing a one-step hydrothermal method for fabrication and evaluation of radiation shielding characteristics in Pb(ZrO3)-doped zirconia: synthesis and characterization

Investigations on TiO2–NiO@In2O3 nanocomposite thin films (NCTFs) for gas sensing: synthesis, physical characterization, and detection of NO2 and H2S gas sensors

Premium Partner

Marktübersichten