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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 6/2020

01.06.2020 | ORIGINAL PAPER

Study on electrochemical properties of CMC-PVA doped NH4Br based solid polymer electrolytes system as application for EDLC

verfasst von: Norfatihah Mazuki, Anwar P P Abdul Majeed, Ahmad Salihin Samsudin

Erschienen in: Journal of Polymer Research | Ausgabe 6/2020

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Abstract

In the present work, solid polymer electrolytes (SPEs) based CMC-PVA blend doped with various contents of NH4Br were successfully prepared via solution-casting technique. The prepared samples were then characterized with respect to its thermal and conduction properties by using differential scanning calorimetry (DSC) and impedance spectroscopy. The highest dc conductivity at room temperature is observed to be 3.21 × 10−4 S cm−1 for a sample that consists of 20 wt.% NH4Br which demonstrated good thermal stability of Tg. The CMC-PVA doped NH4Br recorded an increment on the ionic conductivity with the increase in temperature, and thus obeys the Arrhenius behavior. The potential window for the highest conducting sample was found to be plateaued at 1.55 V. The performance of the EDLC fabricated with highest ionic conducting CMC-PVA doped NH4Br was also examined through cyclic voltammetry (CV) and it was shown that the specific capacitance increased as the scan rate reduced. Based on the charge-discharge profile, it is apparent that the proposed system has excellent cyclic retention as it is able to keep the performance of the EDLC at ~88% even after 1000 cycles.
Nächster Artikel The impact of acetylation on physical and electrochemical characteristics of cellulose-based quasi-solid polymer electrolytes

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Metadaten
Titel
Study on electrochemical properties of CMC-PVA doped NH4Br based solid polymer electrolytes system as application for EDLC
verfasst von
Norfatihah Mazuki
Anwar P P Abdul Majeed
Ahmad Salihin Samsudin
Publikationsdatum
01.06.2020
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 6/2020
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-02078-5

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