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Journal of Material Cycles and Waste Management

Erschienen in:

01.10.2013 | ORIGINAL ARTICLE

Sunflower stalk, an agricultural waste, as an adsorbent for the removal of lead and cadmium from aqueous solutions

verfasst von: Mohsen Jalali, Fathemeh Aboulghazi

Erschienen in: Journal of Material Cycles and Waste Management | Ausgabe 4/2013

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Abstract

Sunflower residue, an agricultural waste material for the removal of lead (Pb) and cadmium (Cd) from aqueous solutions were investigated using a batch method. Adsorbent was prepared by washing sunflower residue with deionized water until the effluent was colorless. Batch mode experiments were carried out as a function of solution pH, adsorbent dosage, initial concentration and contact time. The results indicated that the adsorbent showed good sorption potential and maximum metal removal was observed at pH 5. Within 150 min of operation about 97 and 87 % of Pb and Cd ions were removed from the solutions, respectively. Lead and Cd sorption curves were well fitted to the modified two-site Langmuir model. The adsorption capacities for Pb and Cd at optimum conditions were 182 and 70 mg g⁻¹, respectively. The kinetics of Pb and Cd adsorption from aqueous solutions were analyzed by fitting the experimental data to a pseudo-second-order kinetic model and the rate constant was found to be 8.42 × 10⁻² and 8.95 × 10⁻² g mg⁻¹ min⁻¹ for Cd and Pb, respectively. The results revealed that sunflower can adsorb considerable amount of Pb and Cd ions and thus could be an economical method for the removal of Pb and Cd from aqueous systems.

Vorheriger Artikel Anaerobic co-digestion of dairy cow manure and high concentrated food processing waste

Nächster Artikel Health risk assessment of heavy metals (Cr, Ni, Cu, Zn, Cd, Pb) in circumjacent soil of a factory for recycling waste electrical and electronic equipment

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Naiya TK, Chowdhury P, Bhattacharya AK, Das SK (2009) Saw dust and neem bark as low-cost natural biosorbent for adsorptive removal of Zn (II) and Cd (II) ions from aqueous solutions. Chem Eng J 148:68–79CrossRef

McGrath SP (1987) Long-term studies of metal transfers following applications of sewage sludge. In: Coughtrey PJ, Martin MH, Unsworth MH (eds) Pollutant transport and fate in ecosystems. Blackwell Scientific, Oxford, pp 301–317

International Agency for Research on Cancer (IARC) (1993) Proceedings of the meeting of the IARC working group on beryllium, cadmium, mercury and exposures in the glass manufacturing industry. Scand J Work Environ Health 19:360

Jin YH, Clark AB, Slebos Robbert JC, Al-Refai H, Taylor JA, Kunkel TA, Resnick MA, Gordenin DA (2003) Cadmium is a mutagen that acts by inhibiting mismatch repair. Nat Genet 34:326CrossRef

Hayes RB (1997) The carcinogenicity of metals in humans. Cancer Causes Control 8:371CrossRef

Hengstler JG, Bolm-Audorff U, Faldum A, Janssen K, Reifenrath M, Götte W, Jung D, Mayer-Popken O, Fuchs J, Gebhard S, Bienfait HG, Schlink K, Dietrich C, Faust D, Epe B, Oesch F (2003) Occupational exposure to heavy metals: DNA damage induction and DNA repair inhibition prove co-exposures to cadmium, cobalt and lead as more dangerous than hitherto expected. Carcinogenesis 24:63CrossRef

Merian E, Anke M, Ihnat M, Stoeppler M (2004) Elements and their compounds in the environment, 2nd edn. Wiley/VCH, Weinheim

Seiler HG, Sigel H, Sigel A (1988) Handbook on toxicity of inorganic compounds. Marcel Dekker, New York

Jalali M, Khanlari ZV (2008) Environmental contamination of Zn, Cd, Ni, Cu, and Pb from industrial areas in Hamadan Province, western Iran. Environ Geol 55:1537–1543CrossRef

10.

Esalah JO, Weber ME, Vera JH (2000) Removal of lead, cadmium and zinc from aqueous solutions by precipitation with sodium di-(n-octyl) phosphinate. Can J Chem Eng 78:948–954CrossRef

11.

Zouboulis AI, Matis KA, Lanara BG, Loos-Neskovic C (1997) Removal of cadmium from dilute solutions by hydroxyapatite. II. Flotation studies. Sep Sci Technol 32:1755–1767CrossRef

12.

Ravindran V, Stevens MR, Badriyha BN, Pirbazari M (1999) Modeling the sorption of toxic metals on chelant-impregnated adsorbent. AIChE J 45:1135–1146CrossRef

13.

Canet L, Llpide M, Seta P (2002) Efficient facilitated transport of lead, cadmium, zinc and silver across a flat sheet-supported liquid membrane mediated by lasalocid A. Sep Sci Technol 37:1851–1860CrossRef

14.

Madhava Rao M, Chandra Rao GP, Seshaiah K, Choudary NV, Wang MC (2008) Activated carbon from Ceiba pentandra hulls, an agricultural waste, as an adsorbent in the removal of lead and zinc from aqueous solutions. Waste Manag 28:849–858CrossRef

15.

Yiaocumi S, Tien C (1995) Kinetics of metal ion adsorption from aqueous solutions: models, algorithms and application. Kluwer Academic Publishers, New YorkCrossRef

16.

Kandah MI (2004) Zinc and cadmium adsorption on low-grade phosphate. Sep Purif Technol 35:61–70CrossRef

17.

Ferro-García MA, Rivera-Utrilla J, Rodríguez-Gordillo J, Bautista-Toledo I (1988) Adsorption of zinc, cadmium, and copper on activated carbons obtained from agricultural by-products. Carbon 26:363–370CrossRef

18.

Sun G, Shi W (1998) Sunflower stalks as adsorbents for the removal of metal ions from waste water. Ind Eng Chem Res 37:1324–1328CrossRef

19.

Low KS, Lee CK, Liew SC (2000) Sorption of cadmium and lead from aqueous solutions by spent grain. Proc Biochem 36:59–64CrossRef

20.

Wu J, Zhang H, He PJ, Yao Q, Shao LM (2010) Cr(VI) removal from aqueous solution by dried activated sludge biomass. J Hazard Mater 176:697–703

21.

Zheng W, Guo M, Chow T, Bennett DN, Rajagopalan N (2010) Sorption properties of greenwaste biochar for two triazine pesticides. J Hazard Mater 181:121–126

22.

Basso MC, Cerrella EG, Cukierman AL (2002) Lignocellulosic materials as potential biosorbents of trace toxic metals from wastewater. Ind Eng Chem Res 41:3580–3585CrossRef

23.

Sciban M, Klasnja M, Skrbic B (2006) Modified hardwood saw dust as adsorbent of heavy metal ions from water. Wood Sci Technol 40:217–227CrossRef

24.

Moussavi G, Barikbin B (2010) Biosorption of chromium (VI) from industrial wastewater onto pistachio hull waste biomass. Chem Eng J 162:893–900

25.

Kurniawan A, Kosasih AN, Febrianto J, Ju Yi-H, Sunarso J, Indraswati N, Ismadji S (2011) Evaluation of cassava peel waste as lowcost biosorbent for Ni-sorption: equilibrium, kinetics, thermodynamics and mechanism. Chem Eng J 172:158–166

26.

Wang FY, Wang H, Ma JW (2010) Adsorption of cadmium (II) ions from aqueous solution by a new low-cost adsorbent—Bamboo charcoal. J Hazard Mater 177:300–306

27.

Bhatnagar A, Minocha AK, Sillanpää M (2010) Adsorptive removal of cobalt from aqueous solution by utilizing lemon peel as biosorbent. Biochem Eng J 48:181–186

28.

Ko DCK, Porter JF, Mckay G (2003) Mass transport model for the fixed bed sorption of metal ions on bone char. Ind Eng Chem Res 42:3458–3469CrossRef

29.

González A, Moreno N, Navia R, Querol X (2011) Development of a non-conventional sorbent from fly ash and its potential use in acid wastewater neutralization and heavy metal removal. Chem Eng J 166:896–905

30.

Eslamzadeh T, Nasernejad B, Pour BB, Zamani A, Bygi ME (2004) Removal of heavy metals from aqueous solution by carrot residues. Iran J Sci Technol Trans A 28:161–167

31.

Liu Y, Naidu R, Ming H (2011) Red mud as an amendment for pollutants in solid and liquid phases. Geoderma 163:1–12

32.

Ho YS, Wang CC (2004) Pseudo-isotherms for the sorption of cadmium ion onto tree fern. Proc Biochem 39:761–765CrossRef

33.

Vlaev L, Petkov P, Dimitrov A, Genieva S (2011) Cleanup of water polluted with crude oil or diesel fuel using rice husks ash. J Taiwan Ins Chem Eng 42:957–964

34.

Martinez M, Miralles N, Hidalgo S, Fiol N, Villaescusa I, Poch J (2006) Removal of lead(II) and cadmium(II) from aqueous solutions using grape stalk waste. J Hazard Mater 133:203–211CrossRef

35.

Aguayo-Villarreal IA, Bonilla-Petriciolet A, Hernández-Montoya V, Montes-Morán MA, Reynel-Avila HE (2011) Batch and column studies of Zn²⁺ removal from aqueous solution using chicken feathers as sorbents. Chem Eng J 167:67–76

36.

Danil de Namor AF, El Gamouz A, Frangie S, Martinez V, Valiente L, Webb OA (2012) Turning the volume down on heavy metals using tuned diatomite: a review of diatomite and modified diatomite for the extraction of heavy metals from water. J Hazard Mater 241–242:14–31

37.

McKay G, El Geundi M, Nassar MM (1987) Equilibrium studies during the removal of dyestuffs from aqueous solutions using bagasse pith. Water Res 21:1513–1520CrossRef

38.

Sun G, Xu X (1997) Sunflower stalks as adsorbents for color removal from textile wastewater. Ind Chem Eng Res 36:808–812CrossRef

39.

Jalali M, Ranjbar F (2009) Rates of decomposition and phosphorus release from organic residues related to residue composition. J Plant Nutr Soil Sci 172:353–359CrossRef

40.

Watkins JW II, Elder RC, Greene B, Darnall DW (1987) Determination of gold binding in an alga biomass using EXAFS and XANES spectroscopies. Inorg Chem 26:1147–1151CrossRef

41.

Sampedro MA, Blanco A, Llama MJ, Serra JL (1995) Sorption of heavy metals to Phormidium laminosum biomass. Biotechnol Appl Biochem 22:355–366

42.

Lujan JR, Darnall DW, Stark PC, Rayson GD, Gardea-Torresdey JL (1994) Metal ion binding by algae and higher plant tissues: a phenomenological study of solution pH dependence. Solvent Extr Ion Exch 12:803–816CrossRef

43.

Paskins-Hurlburt AJ, Tanaka Y, Skoryna SC (1976) Isolation and metal binding properties of fucoidan. Bot Mar 19:327–328

44.

Allison JD, Brown DS, Novo-Gradac KJ (1991) MINTEQA2/PRODEFA2, a geochemical assessment model for environmental systems: version 3.0 users manual. US Environmental Protection Agency, Athens (EPA/600/3-91/021)

45.

Saeed A, Akhter MW, Iqbal M (2005) Removal and recovery of heavy metals from aqueous solution using papaya wood as a new biosorbent. Sep Purif Technol 45:25–31CrossRef

46.

Xiao F, Howard Huang J-Ch (2009) Comparison of biosorbents with inorganic sorbents for removing copper (II) from aqueous solutions. J Environ Manag 90:3105–3109CrossRef

47.

Ho YS, McKay G (1998) A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Trans Inst Chem Eng 76B:332–340

48.

Lehman RG, Harter RD (1984) Assessment of copper–soil bond strength by desorption kinetics. Soil Sci Soc Am J 48:769–772CrossRef

49.

Garg K, Gupta R, Kumar R, Gupta RK (2004) Adsorption of chromium from aqueous solution on treated sawdust. Bioresour Technol 92:79–81CrossRef

50.

Namasivayam C, Prabha D, Kumuthu M (1998) Removal of direct red and acid brilliant blue by adsorption on to banana pith. Bioresour Technol 64:77–79CrossRef

51.

Acharya J, Sahu JN, Sahoo BK, Mohanty CR, Meikap BC (2009) Removal of chromium(VI) from wastewater by activated carbon developed from tamarind wood activated with zinc chloride. Chem Eng J 150:25–39CrossRef

52.

Mata YN, Torres E, Blázquez ML, Ballester A, González F, Muñoz JA (2007) Lead and gold removal using sugar-beet pectin gels with and without immobilized Fucus vesiculosus. J Adv Mater Res 20–21:599–602CrossRef

Titel: Sunflower stalk, an agricultural waste, as an adsorbent for the removal of lead and cadmium from aqueous solutions
verfasst von: Mohsen Jalali
Fathemeh Aboulghazi
Publikationsdatum: 01.10.2013
Verlag: Springer Japan
Erschienen in: Journal of Material Cycles and Waste Management / Ausgabe 4/2013
Print ISSN: 1438-4957
Elektronische ISSN: 1611-8227
DOI: https://doi.org/10.1007/s10163-012-0096-3

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