Skip to main content
Erschienen in: Journal of Sol-Gel Science and Technology 1/2014

01.01.2014 | Original Paper

Superhydrophobic surface fabricated by modifying silica coated multiwalled carbon nanotubes composites

verfasst von: L. Zhao, W. H. Xu, J. Q. Liu, W. L. Liu, J. S. Yao, M. Li, X. Q. Wang, Y. Z. Wu

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A superhydrophobic surface with maximum static water contact angle of 156° and sliding angle of 3.5° was fabricated by modifying the silica coated multiwalled carbon nanotube composites (SiO2/MWCNTs) using a silane coupling agent vinyltriethoxysilane. The structures of SiO2/MWCNTs and superhydrophobic surface were investigated by infrared spectrometer and transmission electron microscopy. The results indicated that silica had been successfully grafted onto MWCNTs and the SiO2/MWCNTs had been chemical modified by vinyl triethoxy successfully. The morphology of our prepared superhydrophobic surface, investigated by scanning electron microscopy, showed a characteristic rough structure. The effects of pH value and exposure time on the stability of the superhydrophobic surface were also investigated. The superhydrophobic film shows reliable acid and alkali resistance and aging resistance, indicating that it will have a wide range of applications.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Wang K, Hu NX, Xu G, Qi Y (2011) Stable superhydrophobic composite coatings made from an aqueous dispersion of carbon nanotubes and a fluoropolymer. Carbon 49:1769–1774CrossRef Wang K, Hu NX, Xu G, Qi Y (2011) Stable superhydrophobic composite coatings made from an aqueous dispersion of carbon nanotubes and a fluoropolymer. Carbon 49:1769–1774CrossRef
2.
Zurück zum Zitat Sui JH, Li J, Yang SJ, Li ZG, Cai W (2013) A facile method to fabricate superparamagnetic γ-Fe2O3/silica nanotubes using multi-walled carbon nanotubes as template. Mater Lett 100:32–35CrossRef Sui JH, Li J, Yang SJ, Li ZG, Cai W (2013) A facile method to fabricate superparamagnetic γ-Fe2O3/silica nanotubes using multi-walled carbon nanotubes as template. Mater Lett 100:32–35CrossRef
3.
Zurück zum Zitat Wu T, Pan Y, Li L (2011) Fabrication of superhydrophobic hybrids from multiwalled carbon nanotubes and poly(vinylidene fluoride). Colloids Surf A 384:47–52CrossRef Wu T, Pan Y, Li L (2011) Fabrication of superhydrophobic hybrids from multiwalled carbon nanotubes and poly(vinylidene fluoride). Colloids Surf A 384:47–52CrossRef
4.
Zurück zum Zitat Aria AI, Gharib M (2011) Reversible tuning of the wettability of carbon nanotube arrays: the effect of ultraviolet/ozone and vacuum pyrolysis treatments. Langmuir 27:9005–9011CrossRef Aria AI, Gharib M (2011) Reversible tuning of the wettability of carbon nanotube arrays: the effect of ultraviolet/ozone and vacuum pyrolysis treatments. Langmuir 27:9005–9011CrossRef
5.
Zurück zum Zitat Lee KG, Wi R, Imran M, Park TJ, Lee J, Lee SY, Kim DH (2010) Functionalization effects of single-walled carbon nanotubes as templates for the synthesis of silica nanorods and study of growing mechanism of silica. ACS Nano 4:3933–3942CrossRef Lee KG, Wi R, Imran M, Park TJ, Lee J, Lee SY, Kim DH (2010) Functionalization effects of single-walled carbon nanotubes as templates for the synthesis of silica nanorods and study of growing mechanism of silica. ACS Nano 4:3933–3942CrossRef
6.
Zurück zum Zitat Baghbanzadeh M, Rashidi A, Rashtchian D, Lotfi R, Amrollahi A (2012) Synthesis of spherical silica/multiwall carbon nanotubes hybrid nanostructures and investigation of thermal conductivity of related nanofluids. Thermochim Acta 549:87–94CrossRef Baghbanzadeh M, Rashidi A, Rashtchian D, Lotfi R, Amrollahi A (2012) Synthesis of spherical silica/multiwall carbon nanotubes hybrid nanostructures and investigation of thermal conductivity of related nanofluids. Thermochim Acta 549:87–94CrossRef
7.
Zurück zum Zitat Whitsitt EA, Barron AR (2003) Silica coated single walled carbon nanotubes. Nano Lett 3:775–778CrossRef Whitsitt EA, Barron AR (2003) Silica coated single walled carbon nanotubes. Nano Lett 3:775–778CrossRef
8.
Zurück zum Zitat Zhang M, Wu YP, Feng XZ, He XW, Chen LX, Zhang YK (2010) Fabrication of mesoporous silica-coated CNTs and application in size-selective protein separation. J Mater Chem 20:5835–5842CrossRef Zhang M, Wu YP, Feng XZ, He XW, Chen LX, Zhang YK (2010) Fabrication of mesoporous silica-coated CNTs and application in size-selective protein separation. J Mater Chem 20:5835–5842CrossRef
9.
Zurück zum Zitat Lu XH, Liu HQ, Deng CH, Yan XM (2010) Facile synthesis and application of mesoporous silica coated magnetic carbon nanotubes. Chem Commun 47:1210–1212CrossRef Lu XH, Liu HQ, Deng CH, Yan XM (2010) Facile synthesis and application of mesoporous silica coated magnetic carbon nanotubes. Chem Commun 47:1210–1212CrossRef
10.
Zurück zum Zitat Yang YK, Qiu SQ, Cui W (2009) A facile method to fabricate silica-coated carbon nanotubes and silica nanotubes from carbon nanotubes templates. J Mater Sci 44:4539–4545CrossRef Yang YK, Qiu SQ, Cui W (2009) A facile method to fabricate silica-coated carbon nanotubes and silica nanotubes from carbon nanotubes templates. J Mater Sci 44:4539–4545CrossRef
11.
Zurück zum Zitat Seeger T, Redlich P, Grobert N (2001) SiOx-coating of carbon nanotubes at room temperature. Chem Phys Lett 339:41–46CrossRef Seeger T, Redlich P, Grobert N (2001) SiOx-coating of carbon nanotubes at room temperature. Chem Phys Lett 339:41–46CrossRef
12.
Zurück zum Zitat Emami B, Bucher TM, Tafreshi HV, Pestov D, Gad-el-Hak M, Tepper GC (2011) Simulation of meniscus stability in superhydrophobic granular surfaces under hydrostatic pressures. Colloids Surf A 385:95–103CrossRef Emami B, Bucher TM, Tafreshi HV, Pestov D, Gad-el-Hak M, Tepper GC (2011) Simulation of meniscus stability in superhydrophobic granular surfaces under hydrostatic pressures. Colloids Surf A 385:95–103CrossRef
13.
Zurück zum Zitat Jin H, Tian XL, Ikkala O, Ras RHA (2013) Preservation of superhydrophobic and superoleophobic properties upon wear damage. ACS Appl Mater Interfaces 5:485–488CrossRef Jin H, Tian XL, Ikkala O, Ras RHA (2013) Preservation of superhydrophobic and superoleophobic properties upon wear damage. ACS Appl Mater Interfaces 5:485–488CrossRef
14.
Zurück zum Zitat Han ZJ, Tay BK, Tan C, Shakerzadeh M, Ostrikov K (2009) Electrowetting control of cassie-to-wenzel transitions in superhydrophobic carbon nanotube-based nanocomposites. ACS Nano 3:3031–3036CrossRef Han ZJ, Tay BK, Tan C, Shakerzadeh M, Ostrikov K (2009) Electrowetting control of cassie-to-wenzel transitions in superhydrophobic carbon nanotube-based nanocomposites. ACS Nano 3:3031–3036CrossRef
15.
Zurück zum Zitat Hsu CP, Chang LY, Chiu CW, Lee PTC, Lin JJ (2013) Facile fabrication of robust superhydrophobic epoxy film with polyamine dispersed carbon nanotubes. ACS Appl Mater Interfaces 5:538–545CrossRef Hsu CP, Chang LY, Chiu CW, Lee PTC, Lin JJ (2013) Facile fabrication of robust superhydrophobic epoxy film with polyamine dispersed carbon nanotubes. ACS Appl Mater Interfaces 5:538–545CrossRef
16.
Zurück zum Zitat Sethi S, Dhinojwala A (2009) Superhydrophobic conductive carbon nanotube coatings for steel. Langmuir 25:4311–4313CrossRef Sethi S, Dhinojwala A (2009) Superhydrophobic conductive carbon nanotube coatings for steel. Langmuir 25:4311–4313CrossRef
17.
Zurück zum Zitat Li LH, Chen Y (2010) Superhydrophobic properties of nonaligned boron nitride nanotube films. Langmuir 26:5135–5140CrossRef Li LH, Chen Y (2010) Superhydrophobic properties of nonaligned boron nitride nanotube films. Langmuir 26:5135–5140CrossRef
18.
Zurück zum Zitat Lin Z, Liu Y, Wong CP (2010) Facile fabrication of superhydrophobic octadecylamine-functionalized graphite oxide film. Langmuir 26:16110–16114CrossRef Lin Z, Liu Y, Wong CP (2010) Facile fabrication of superhydrophobic octadecylamine-functionalized graphite oxide film. Langmuir 26:16110–16114CrossRef
19.
Zurück zum Zitat Zou JH, Chen H, Chunder A, Yu YX, Huo Q, Zhai L (2008) Preparation of a superhydrophobic and conductive nanocomposite coating from a carbon-nanotube-conjugated block copolymer dispersion. Adv Mater 20:3337–3341CrossRef Zou JH, Chen H, Chunder A, Yu YX, Huo Q, Zhai L (2008) Preparation of a superhydrophobic and conductive nanocomposite coating from a carbon-nanotube-conjugated block copolymer dispersion. Adv Mater 20:3337–3341CrossRef
20.
Zurück zum Zitat Gavalas VG, Andrews R, Bhattacharyya D, Bachas LG (2001) Carbon nanotube sol–gel composite materials. Nano Lett 1:719–721CrossRef Gavalas VG, Andrews R, Bhattacharyya D, Bachas LG (2001) Carbon nanotube sol–gel composite materials. Nano Lett 1:719–721CrossRef
21.
Zurück zum Zitat Kanungo M, Isaacs HS, Wong SS (2007) Quantitative control over electrodeposition of silica films onto single-walled carbon nanotube surfaces. J Phys Chem C 111:17730–17742CrossRef Kanungo M, Isaacs HS, Wong SS (2007) Quantitative control over electrodeposition of silica films onto single-walled carbon nanotube surfaces. J Phys Chem C 111:17730–17742CrossRef
22.
Zurück zum Zitat Kim M, Hong J, Lee J, Hong CK, Shim SE (2008) Fabrication of silica nanotubes using silica coated multi-walled carbon nanotubes as the template. J Colloid Interface Sci 322:321–326CrossRef Kim M, Hong J, Lee J, Hong CK, Shim SE (2008) Fabrication of silica nanotubes using silica coated multi-walled carbon nanotubes as the template. J Colloid Interface Sci 322:321–326CrossRef
23.
Zurück zum Zitat Zhang M, Zhang XH, He XW, Chen LX, Zhang YK (2010) A facile method to coat mesoporous silica layer on carbon nanotubes by anionic surfactant. Meter Lett 64:1383–1386CrossRef Zhang M, Zhang XH, He XW, Chen LX, Zhang YK (2010) A facile method to coat mesoporous silica layer on carbon nanotubes by anionic surfactant. Meter Lett 64:1383–1386CrossRef
24.
Zurück zum Zitat Hsieh CT, Wu FL, Yang SY (2008) Superhydrophobicity from composite nano/microstructures: carbon fabrics coated with silica nanoparticles. Surf Coat Technol 202:6103–6108CrossRef Hsieh CT, Wu FL, Yang SY (2008) Superhydrophobicity from composite nano/microstructures: carbon fabrics coated with silica nanoparticles. Surf Coat Technol 202:6103–6108CrossRef
25.
Zurück zum Zitat Yang K, Gu MY, Jin YP, Mu GH, Pan XF (2008) Influence of surface treated multi-walled carbon nanotubes on cure behavior of epoxy nanocomposites. Compos A 39:1670–1678CrossRef Yang K, Gu MY, Jin YP, Mu GH, Pan XF (2008) Influence of surface treated multi-walled carbon nanotubes on cure behavior of epoxy nanocomposites. Compos A 39:1670–1678CrossRef
26.
Zurück zum Zitat Kai Y, Gu MY, Han HB, Mu GH (2008) Influence of chemical processing on the morphology, crystalline content and thermal stability of multi-walled carbon nanotubes. Mater Chem Phys 112:387–392CrossRef Kai Y, Gu MY, Han HB, Mu GH (2008) Influence of chemical processing on the morphology, crystalline content and thermal stability of multi-walled carbon nanotubes. Mater Chem Phys 112:387–392CrossRef
27.
Zurück zum Zitat Sun XL, Fan ZP, Zhang LD, Wang L, Wei ZJ, Wang XQ, Liu WL (2011) Superhydrophobicity of silica nanoparticles modified with polystyrene. Appl Surf Sci 257:2308–2312CrossRef Sun XL, Fan ZP, Zhang LD, Wang L, Wei ZJ, Wang XQ, Liu WL (2011) Superhydrophobicity of silica nanoparticles modified with polystyrene. Appl Surf Sci 257:2308–2312CrossRef
28.
Zurück zum Zitat Zhang LD, Liu WL, Xu WH, Yao JS, Zhao L, Wang XQ, Wu YZ (2012) Synthesis and characterization of superhydrophobic and superparamagnetic film based on maghemite–polystyrene composite nanoparticles. Appl Surf Sci 259:719–725CrossRef Zhang LD, Liu WL, Xu WH, Yao JS, Zhao L, Wang XQ, Wu YZ (2012) Synthesis and characterization of superhydrophobic and superparamagnetic film based on maghemite–polystyrene composite nanoparticles. Appl Surf Sci 259:719–725CrossRef
29.
Zurück zum Zitat Liu WL, Wang L, Zhang LD, Xu WH, Chen SH, Wang XQ, Duan XL (2012) Superhydrophobic surface by immobilization of polystyrene on vinyl-modified titania nanoparticles. J Solgel Sci Technol 62:424–431CrossRef Liu WL, Wang L, Zhang LD, Xu WH, Chen SH, Wang XQ, Duan XL (2012) Superhydrophobic surface by immobilization of polystyrene on vinyl-modified titania nanoparticles. J Solgel Sci Technol 62:424–431CrossRef
30.
Zurück zum Zitat Zhao L, Liu WL, Zhang LD, Yao JS, Xu WH, Wang XQ, Wu YZ (2013) Fabrication of superhydrophobic and conductive surface based on carbon nanotubes. Colloids Surf A 423:69–76CrossRef Zhao L, Liu WL, Zhang LD, Yao JS, Xu WH, Wang XQ, Wu YZ (2013) Fabrication of superhydrophobic and conductive surface based on carbon nanotubes. Colloids Surf A 423:69–76CrossRef
Metadaten
Titel
Superhydrophobic surface fabricated by modifying silica coated multiwalled carbon nanotubes composites
verfasst von
L. Zhao
W. H. Xu
J. Q. Liu
W. L. Liu
J. S. Yao
M. Li
X. Q. Wang
Y. Z. Wu
Publikationsdatum
01.01.2014
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2014
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-013-3192-5

Weitere Artikel der Ausgabe 1/2014

Journal of Sol-Gel Science and Technology 1/2014 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.