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Erschienen in: Journal of Materials Science: Materials in Electronics 23/2020

23.10.2020

Surface-hydrophilic-modified carbon aerogels via surface-initiated electrochemically mediated atom transfer radical polymerization for high-performance supercapacitors

verfasst von: Jian Chang, Hua Li, Lei Yang, Hezhou Liu

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 23/2020

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Abstract

Surface electrolyte-philic functionalization of carbon aerogels (CAs) by surface-initiated electrochemically mediated atom transfer radical polymerization (SI-eATRP) of hydrophilic polymer brushes of poly(N-vinylpyrrolidone) (PVP) was successfully carried out. The modified composite electrode is more hydrophilic with better wettability in an aqueous electrolyte than the pristine CAs. The modified electrodes possess a higher specific capacitance of 279 F/g, excellent rate performance, and good cycling stability due to combining the advantages of both CAs and hydrophilic property. In addition, this study confirmed that higher electrode/electrolyte contact area lead to higher charge/discharge rates during the energy storage progress. Through the simple modification method, hydrophilic CAs with excellent properties were obtained which have promising application in energy conversion and storage fields.

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Metadaten
Titel
Surface-hydrophilic-modified carbon aerogels via surface-initiated electrochemically mediated atom transfer radical polymerization for high-performance supercapacitors
verfasst von
Jian Chang
Hua Li
Lei Yang
Hezhou Liu
Publikationsdatum
23.10.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 23/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-04650-7

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