Skip to main content
Erschienen in: Polymer Bulletin 9/2016

28.04.2016 | Original Paper

Surface wettability of amphiphilic fluorinated polymer thin films

verfasst von: Yu Gao, Huie Zhu, Shunsuke Yamamoto, Tokuji Miyashita, Masaya Mitsuishi

Erschienen in: Polymer Bulletin | Ausgabe 9/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The surface wettability of amphiphilic fluorinated polymer poly(N-1H,1H-pentadecafluorooctylmethacrylamide), (pC7F15MAA) films was investigated. Nanostructured fluorinated polymer pC7F15MAA films were prepared using two bottom-up methods: Langmuir–Blodgett technique and dropcasting. The pC7F15MAA LB films show quite smooth surfaces as low as the surface roughness of 1.16 nm, and the surface has a water contact angle (WCA) of 118°, indicating that the surface is occupied by the CF3 groups. Dropcasting provides pC7F15MAA nanoparticle assemblies with the surface roughness of 230 nm and a WCA of 163°. Results imply that bottom-up approaches with amphiphilic fluorinated polymer are effective to construct nanostructures, thereby controlling the surface wettability.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Barthlott W, Neinhuis C (1997) Purity of the sacred lotus, or escape from contamination in biological surfaces. Planta 201:1CrossRef Barthlott W, Neinhuis C (1997) Purity of the sacred lotus, or escape from contamination in biological surfaces. Planta 201:1CrossRef
2.
3.
Zurück zum Zitat Blossey R (2003) Self-cleaning surfaces—virtual realities. Nat Mater 2:301CrossRef Blossey R (2003) Self-cleaning surfaces—virtual realities. Nat Mater 2:301CrossRef
4.
Zurück zum Zitat Furstner R, Barthlott W, Neinhuis C, Walzel P (2005) Wetting and self-cleaning properties of artificial superhydrophobic surfaces. Langmuir 21:956CrossRef Furstner R, Barthlott W, Neinhuis C, Walzel P (2005) Wetting and self-cleaning properties of artificial superhydrophobic surfaces. Langmuir 21:956CrossRef
5.
Zurück zum Zitat Miwa M, Nakajima A, Fujishima A, Hashimoto K, Watanabe T (2000) Effects of the surface roughness on sliding angles of water droplets on superhydrophobic surfaces. Langmuir 16:5754CrossRef Miwa M, Nakajima A, Fujishima A, Hashimoto K, Watanabe T (2000) Effects of the surface roughness on sliding angles of water droplets on superhydrophobic surfaces. Langmuir 16:5754CrossRef
6.
Zurück zum Zitat Nakajima A, Hashimoto K, Watanabe T, Takai K, Yamauchi G, Fujishima A (2000) Transparent superhydrophobic thin films with self-cleaning properties. Langmuir 16:7044CrossRef Nakajima A, Hashimoto K, Watanabe T, Takai K, Yamauchi G, Fujishima A (2000) Transparent superhydrophobic thin films with self-cleaning properties. Langmuir 16:7044CrossRef
7.
Zurück zum Zitat Otten A, Herminghaus S (2004) How plants keep dry: a physicist's point of view. Langmuir 20:2405CrossRef Otten A, Herminghaus S (2004) How plants keep dry: a physicist's point of view. Langmuir 20:2405CrossRef
8.
Zurück zum Zitat Scardino A, De Nys R, Ison O, OConnor W, Steinberg P (2003) Microtopography and antifouling properties of the shell surface of the bivalve molluscs Mytilus galloprovincialis and Pinctada imbricata. Biofouling 19:221CrossRef Scardino A, De Nys R, Ison O, OConnor W, Steinberg P (2003) Microtopography and antifouling properties of the shell surface of the bivalve molluscs Mytilus galloprovincialis and Pinctada imbricata. Biofouling 19:221CrossRef
9.
Zurück zum Zitat Schultz MP, Kavanagh CJ, Swain GW (1999) Hydrodynamic forces on barnacles: implications on detachment from fouling-release surfaces. Biofouling 13:323CrossRef Schultz MP, Kavanagh CJ, Swain GW (1999) Hydrodynamic forces on barnacles: implications on detachment from fouling-release surfaces. Biofouling 13:323CrossRef
10.
Zurück zum Zitat Saito H, Takai K, Takazawa H, Yamauchi G (1997) A study on snow sticking weight to water-repellent coatings. Mater Sci Res Int 3:216 Saito H, Takai K, Takazawa H, Yamauchi G (1997) A study on snow sticking weight to water-repellent coatings. Mater Sci Res Int 3:216
11.
Zurück zum Zitat Kako T, Nakajima A, Irie H, Kato Z, Uematsu K, Watanabe T, Hashimoto K (2004) Adhesion and sliding of wet snow on a super-hydrophobic surface with hydrophilic channels. J Mater Sci 39:547CrossRef Kako T, Nakajima A, Irie H, Kato Z, Uematsu K, Watanabe T, Hashimoto K (2004) Adhesion and sliding of wet snow on a super-hydrophobic surface with hydrophilic channels. J Mater Sci 39:547CrossRef
12.
Zurück zum Zitat Zielecka M, Bujnowska E (2006) Silicone-containing polymer matrices as protective coatings—properties and applications. Prog Org Coat 55:160CrossRef Zielecka M, Bujnowska E (2006) Silicone-containing polymer matrices as protective coatings—properties and applications. Prog Org Coat 55:160CrossRef
13.
Zurück zum Zitat Coulson SR, Woodward I, Badyal JPS, Brewer SA, Willis C (2000) Super-repellent composite fluoropolymer surfaces. J Phys Chem B 104:8836CrossRef Coulson SR, Woodward I, Badyal JPS, Brewer SA, Willis C (2000) Super-repellent composite fluoropolymer surfaces. J Phys Chem B 104:8836CrossRef
14.
Zurück zum Zitat Nishino T, Meguro M, Nakamae K, Matsushita M, Ueda Y (1999) The lowest surface free energy based on –CF3 alignment. Langmuir 15:4321CrossRef Nishino T, Meguro M, Nakamae K, Matsushita M, Ueda Y (1999) The lowest surface free energy based on –CF3 alignment. Langmuir 15:4321CrossRef
15.
Zurück zum Zitat Sun TL, Feng L, Gao XF, Jiang L (2005) Bioinspired surfaces with special wettability. Acc Chem Res 38:644CrossRef Sun TL, Feng L, Gao XF, Jiang L (2005) Bioinspired surfaces with special wettability. Acc Chem Res 38:644CrossRef
16.
Zurück zum Zitat Gao XF, Jiang L (2004) Water-repellent legs of water striders. Nature 432:36CrossRef Gao XF, Jiang L (2004) Water-repellent legs of water striders. Nature 432:36CrossRef
17.
Zurück zum Zitat Bixler D, Bhushan B (2014) Rice- and butterfly-wing effect inspired self-cleaning and low drag micro/nanopatterned surfaces in water, oil, and air flow. Nanoscale 6:76CrossRef Bixler D, Bhushan B (2014) Rice- and butterfly-wing effect inspired self-cleaning and low drag micro/nanopatterned surfaces in water, oil, and air flow. Nanoscale 6:76CrossRef
18.
Zurück zum Zitat Aminuzzaman M, Mitsuishi M, Miyashita T (2010) Fabrication of fluorinated polymer nanosheets using the Langmuir-Blodgett technique: characterization of their surface properties and applications. Polym Int 59:583 Aminuzzaman M, Mitsuishi M, Miyashita T (2010) Fabrication of fluorinated polymer nanosheets using the Langmuir-Blodgett technique: characterization of their surface properties and applications. Polym Int 59:583
19.
Zurück zum Zitat Aminuzzaman M, Kado Y, Mitsuishi M, Miyashita T (2003) Preparation and characterization of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) Langmuir-Blodgett film. Polym J 35:785CrossRef Aminuzzaman M, Kado Y, Mitsuishi M, Miyashita T (2003) Preparation and characterization of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) Langmuir-Blodgett film. Polym J 35:785CrossRef
20.
Zurück zum Zitat Adamson AW, Gast AP (1990) Physical chemistry of surface. Wiley, New York Adamson AW, Gast AP (1990) Physical chemistry of surface. Wiley, New York
21.
Zurück zum Zitat Yip J, Chan K, Sin KM, Lau KS (2002) Study of physico-chemical surface treatments on dyeing properties of polyamides. Part 1: Effect of tetrafluoromethane low temperature plasma. Color Technol 118:26CrossRef Yip J, Chan K, Sin KM, Lau KS (2002) Study of physico-chemical surface treatments on dyeing properties of polyamides. Part 1: Effect of tetrafluoromethane low temperature plasma. Color Technol 118:26CrossRef
22.
Zurück zum Zitat Dann JR (1970) Forces involved in adhesive process: I. Critical surface tensions of polymeric solids as determined with polar liquids. J Colloid Interface Sci 32:302CrossRef Dann JR (1970) Forces involved in adhesive process: I. Critical surface tensions of polymeric solids as determined with polar liquids. J Colloid Interface Sci 32:302CrossRef
23.
Zurück zum Zitat Graupe M, Takenaga M, Koini T, Colorado R, Lee TR (1999) Oriented surface dipoles strongly influence interfacial wettabilities. J Am Chem Soc 121:3222CrossRef Graupe M, Takenaga M, Koini T, Colorado R, Lee TR (1999) Oriented surface dipoles strongly influence interfacial wettabilities. J Am Chem Soc 121:3222CrossRef
24.
Zurück zum Zitat Gao Y, Chen T, Yamamoto S, Miyashita T, Mitsuishi M (2015) Superhydrophobic porous surfaces: dissolved oxygen sensing. ACS Appl Mater Interfaces 7:3468 Gao Y, Chen T, Yamamoto S, Miyashita T, Mitsuishi M (2015) Superhydrophobic porous surfaces: dissolved oxygen sensing. ACS Appl Mater Interfaces 7:3468
Metadaten
Titel
Surface wettability of amphiphilic fluorinated polymer thin films
verfasst von
Yu Gao
Huie Zhu
Shunsuke Yamamoto
Tokuji Miyashita
Masaya Mitsuishi
Publikationsdatum
28.04.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 9/2016
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-016-1668-5

Weitere Artikel der Ausgabe 9/2016

Polymer Bulletin 9/2016 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.