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Erschienen in: Cellulose 6/2011

01.12.2011

Synthesis and characterization of cellulose fibers grafted with hyperbranched poly(3-methyl-3-oxetanemethanol)

verfasst von: Qiang Yang, Xuejun Pan, Fang Huang, Kecheng Li

Erschienen in: Cellulose | Ausgabe 6/2011

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Abstract

Hyperbranched poly(3-methyl-3-oxetanemethanol) (HBPO) was directly grafted from the surface of cellulose fibers (CF) through a surface hydroxyl group-initiated ring-opening polymerization of 3-methyl-3-oxetanemethanol (MOM). TOF–SIMS, XPS, AFM, ATR-FTIR, and TGA were utilized for characterizing the resultant HBPO-grafted cellulose fibers. The content of grafted HBPO is easily adjustable by controlling feeding dosage of the MOM. To verify the reactivity of hydroxyl groups in the grafted HBPO, poly(ε-caprolactone) (PCL) was further grafted from the HBPO-grafted cellulose surface.

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Literatur
Zurück zum Zitat Barbey R, Lavanant L, Paripovic D, Schüwer N, Sugnaux C, Tugulu S, Klok HA (2009) Polymer brushes via surface-initiated controlled radical polymerization: synthesis, characterization, properties, and applications. Chem Rev 109:5437–5527CrossRef Barbey R, Lavanant L, Paripovic D, Schüwer N, Sugnaux C, Tugulu S, Klok HA (2009) Polymer brushes via surface-initiated controlled radical polymerization: synthesis, characterization, properties, and applications. Chem Rev 109:5437–5527CrossRef
Zurück zum Zitat Barsbay M, Guven G, Stenzel MH, Davis TP, Barner-Kowollik C, Barner L (2007) Verification of controlled grafting of styrene from cellulose via radiation-induced RAFT polymerization. Macromolecules 40(20):7140–7147CrossRef Barsbay M, Guven G, Stenzel MH, Davis TP, Barner-Kowollik C, Barner L (2007) Verification of controlled grafting of styrene from cellulose via radiation-induced RAFT polymerization. Macromolecules 40(20):7140–7147CrossRef
Zurück zum Zitat Carlmark A, Malmstrom E (2002) Atom transfer radical polymerization from cellulose fibers at ambient temperature. J Am Chem Soc 124(6):900–901CrossRef Carlmark A, Malmstrom E (2002) Atom transfer radical polymerization from cellulose fibers at ambient temperature. J Am Chem Soc 124(6):900–901CrossRef
Zurück zum Zitat Carlmark A, Malmstrom EE (2003) ATRP grafting from cellulose fibers to create block-copolymer grafts. Biomacromolecules 4(6):1740–1745CrossRef Carlmark A, Malmstrom EE (2003) ATRP grafting from cellulose fibers to create block-copolymer grafts. Biomacromolecules 4(6):1740–1745CrossRef
Zurück zum Zitat Freire CSR, Silvestre AJD, Neto CP, Gandini A, Fardim P, Holmbom B (2006) Surface characterization by XPS, contact angle measurements and ToF-SIMS of cellulose fibers partially esterified with fatty acids. J Colloid Interf Sci 301(1):205–209CrossRef Freire CSR, Silvestre AJD, Neto CP, Gandini A, Fardim P, Holmbom B (2006) Surface characterization by XPS, contact angle measurements and ToF-SIMS of cellulose fibers partially esterified with fatty acids. J Colloid Interf Sci 301(1):205–209CrossRef
Zurück zum Zitat Habibi Y, Goffin AL, Schiltz N, Duquesne E, Dubois P, Dufresne A (2008) Bionanocomposites based on poly(epsilon-caprolactone)-grafted cellulose nanocrystals by ring-opening polymerization. J Mat Chem 18(41):5002–5010CrossRef Habibi Y, Goffin AL, Schiltz N, Duquesne E, Dubois P, Dufresne A (2008) Bionanocomposites based on poly(epsilon-caprolactone)-grafted cellulose nanocrystals by ring-opening polymerization. J Mat Chem 18(41):5002–5010CrossRef
Zurück zum Zitat Hassan ML (2006) Preparation and thermal stability of new cellulose-based poly(propylene imine) and poly(amido amine) hyperbranched derivatives. J Appl Polym Sci 101(3):2079–2087 Hassan ML (2006) Preparation and thermal stability of new cellulose-based poly(propylene imine) and poly(amido amine) hyperbranched derivatives. J Appl Polym Sci 101(3):2079–2087
Zurück zum Zitat Hassan ML, Moorefield CN, Newkome GR (2004) Regioselective dendritic functionalization of cellulose. Macromol Rapid Commun 25(24):1999–2002CrossRef Hassan ML, Moorefield CN, Newkome GR (2004) Regioselective dendritic functionalization of cellulose. Macromol Rapid Commun 25(24):1999–2002CrossRef
Zurück zum Zitat Hassan ML, Moorefield CN, Kotta K, Newkome GR (2005) Regioselective combinatorial-type synthesis, characterization, and physical properties of dendronized cellulose. Polymer 46(21):8947–8955CrossRef Hassan ML, Moorefield CN, Kotta K, Newkome GR (2005) Regioselective combinatorial-type synthesis, characterization, and physical properties of dendronized cellulose. Polymer 46(21):8947–8955CrossRef
Zurück zum Zitat Heinze T, Pohl M, Schaller J, Meister F (2007) Novel bulky esters of cellulose. Macromol Biosci 7(11):1225–1231CrossRef Heinze T, Pohl M, Schaller J, Meister F (2007) Novel bulky esters of cellulose. Macromol Biosci 7(11):1225–1231CrossRef
Zurück zum Zitat Heinze T, Schobitz M, Pohl M, Meister F (2008) Interactions of ionic liquids with polysaccharides. IV. Dendronization of 6-azido-6-deoxy cellulose. J Polym Sci Part a-Polym Chem 46(11):3853–3859 Heinze T, Schobitz M, Pohl M, Meister F (2008) Interactions of ionic liquids with polysaccharides. IV. Dendronization of 6-azido-6-deoxy cellulose. J Polym Sci Part a-Polym Chem 46(11):3853–3859
Zurück zum Zitat Hou J, Yan DY (2002) Synthesis of a star-shaped copolymer with a hyperbranched poly(3-methyl-3-oxetanemethanol) core and tetrahydrofuran arms by one-pot copolymerization. Macromol Rapid Commun 23(8):456–459CrossRef Hou J, Yan DY (2002) Synthesis of a star-shaped copolymer with a hyperbranched poly(3-methyl-3-oxetanemethanol) core and tetrahydrofuran arms by one-pot copolymerization. Macromol Rapid Commun 23(8):456–459CrossRef
Zurück zum Zitat Hwang SH, Moorefield CN, Wang PS, Jeong KU, Cheng SZD, Kotta KK, Newkome GR (2006) Construction of CdS quantum dots via a regioselective dendritic functionalized cellulose template. Chem Commun (33):3495–3497 Hwang SH, Moorefield CN, Wang PS, Jeong KU, Cheng SZD, Kotta KK, Newkome GR (2006) Construction of CdS quantum dots via a regioselective dendritic functionalized cellulose template. Chem Commun (33):3495–3497
Zurück zum Zitat Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chemie-Int Edn 44(22):3358–3393CrossRef Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chemie-Int Edn 44(22):3358–3393CrossRef
Zurück zum Zitat Lindqvist J, Nystrom D, Ostmark E, Antoni P, Carlmark A, Johansson M, Hult A, Malmstrom E (2008) Intelligent dual-responsive cellulose surfaces via surface-initiated ATRP. Biomacromolecules 9(8):2139–2145CrossRef Lindqvist J, Nystrom D, Ostmark E, Antoni P, Carlmark A, Johansson M, Hult A, Malmstrom E (2008) Intelligent dual-responsive cellulose surfaces via surface-initiated ATRP. Biomacromolecules 9(8):2139–2145CrossRef
Zurück zum Zitat Lonnberg H, Zhou Q, Brumer H, Teeri TT, Malmstrom E, Hult A (2006) Grafting of cellulose fibers with poly(epsilon-caprolactone) and poly(L-lactic acid) via ring-opening polymerization. Biomacromolecules 7(7):2178–2185CrossRef Lonnberg H, Zhou Q, Brumer H, Teeri TT, Malmstrom E, Hult A (2006) Grafting of cellulose fibers with poly(epsilon-caprolactone) and poly(L-lactic acid) via ring-opening polymerization. Biomacromolecules 7(7):2178–2185CrossRef
Zurück zum Zitat Montañez MI, Hed Y, Utsel S, Ropponen J, Malmström E, Wågberg L, Hult A, Malkoch M (2011) Bifunctional dendronized cellulose surfaces as biosensors. Biomacromolecules 12(6):2114–2125 Montañez MI, Hed Y, Utsel S, Ropponen J, Malmström E, Wågberg L, Hult A, Malkoch M (2011) Bifunctional dendronized cellulose surfaces as biosensors. Biomacromolecules 12(6):2114–2125
Zurück zum Zitat Mori H, Böker A, Krausch G, Müller AHE (2001) Surface-grafted hyperbranched polymers via self-condensing atom transfer radical polymerization from silicon surfaces. Macromolecules 34(20):6871–6882 Mori H, Böker A, Krausch G, Müller AHE (2001) Surface-grafted hyperbranched polymers via self-condensing atom transfer radical polymerization from silicon surfaces. Macromolecules 34(20):6871–6882
Zurück zum Zitat Nystrom D, Lindqvist J, Ostmark E, Hult A, Malmstrom E (2006) Superhydrophobic bio-fibre surfaces via tailored grafting architecture. Chem Commun 34:3594–3596 Nystrom D, Lindqvist J, Ostmark E, Hult A, Malmstrom E (2006) Superhydrophobic bio-fibre surfaces via tailored grafting architecture. Chem Commun 34:3594–3596
Zurück zum Zitat Oh SY, Yoo DI, Shin Y, Seo G (2005) FTIR analysis of cellulose treated with sodium hydroxide and carbon dioxide. Carbohydr Res 340(3):417–428CrossRef Oh SY, Yoo DI, Shin Y, Seo G (2005) FTIR analysis of cellulose treated with sodium hydroxide and carbon dioxide. Carbohydr Res 340(3):417–428CrossRef
Zurück zum Zitat Pohl M, Michaelis N, Meister F, Heinze T (2009) Biofunctional surfaces based on dendronized cellulose. Biomacromolecules 10(2):382–389CrossRef Pohl M, Michaelis N, Meister F, Heinze T (2009) Biofunctional surfaces based on dendronized cellulose. Biomacromolecules 10(2):382–389CrossRef
Zurück zum Zitat Roy D, Guthrie JT, Perrier S (2005) Graft polymerization: grafting poly(styrene) from cellulose via reversible addition-fragmentation chain transfer (RAFT) polymerization. Macromolecules 38(25):10363–10372CrossRef Roy D, Guthrie JT, Perrier S (2005) Graft polymerization: grafting poly(styrene) from cellulose via reversible addition-fragmentation chain transfer (RAFT) polymerization. Macromolecules 38(25):10363–10372CrossRef
Zurück zum Zitat Roy D, Semsarilar M, Guthrie JT, Perrier S (2009) Cellulose modification by polymer grafting: a review. Chem Soc Rev 38(7):2046–2064CrossRef Roy D, Semsarilar M, Guthrie JT, Perrier S (2009) Cellulose modification by polymer grafting: a review. Chem Soc Rev 38(7):2046–2064CrossRef
Zurück zum Zitat Van Royen P, Taranu A, Van Vaeck L (2005) Comparison of primary monoatomic with primary polyatomic ions for the characterisation of polyesters with static secondary ion mass spectrometry. Rapid Commun Mass Spectrom 19(4):552–560CrossRef Van Royen P, Taranu A, Van Vaeck L (2005) Comparison of primary monoatomic with primary polyatomic ions for the characterisation of polyesters with static secondary ion mass spectrometry. Rapid Commun Mass Spectrom 19(4):552–560CrossRef
Zurück zum Zitat Voit BI, Lederer A (2009) Hyperbranched and highly branched polymer architectures-synthetic strategies and major characterization aspects. Chem Rev 109(11):5924–5973CrossRef Voit BI, Lederer A (2009) Hyperbranched and highly branched polymer architectures-synthetic strategies and major characterization aspects. Chem Rev 109(11):5924–5973CrossRef
Zurück zum Zitat Wang L, Neoh KG, Kang ET, Shuter B, Wang SC (2009) Superparamagnetic hyperbranched polyglycerol-grafted Fe3O4 nanoparticles as a novel magnetic resonance imaging contrast agent: an in vitro assessment. Adv Funct Mat 19(16):2615–2622CrossRef Wang L, Neoh KG, Kang ET, Shuter B, Wang SC (2009) Superparamagnetic hyperbranched polyglycerol-grafted Fe3O4 nanoparticles as a novel magnetic resonance imaging contrast agent: an in vitro assessment. Adv Funct Mat 19(16):2615–2622CrossRef
Zurück zum Zitat Westlund R, Carlmark A, Hult A, Malmstrom E, Saez IM (2007) Grafting liquid crystalline polymers from cellulose substrates using atom transfer radical polymerization. Soft Mat 3(7):866–871CrossRef Westlund R, Carlmark A, Hult A, Malmstrom E, Saez IM (2007) Grafting liquid crystalline polymers from cellulose substrates using atom transfer radical polymerization. Soft Mat 3(7):866–871CrossRef
Zurück zum Zitat Xu YY, Gao C, Kong H, Yan DY, Jin YZ, Watts PCP (2004) Growing multihydroxyl hyperbranched polymers on the surfaces of carbon nanotubes by in situ ring-opening polymerization. Macromolecules 37(24):8846–8853CrossRef Xu YY, Gao C, Kong H, Yan DY, Jin YZ, Watts PCP (2004) Growing multihydroxyl hyperbranched polymers on the surfaces of carbon nanotubes by in situ ring-opening polymerization. Macromolecules 37(24):8846–8853CrossRef
Zurück zum Zitat Yang Q, Wang L, Xiang WD, Zhou JF, Jiang GH (2007) Modification of carbon black through grafting multihydroxyl hyperbranched polyether onto its surface. J Appl Polym Sci 103(4):2086–2092CrossRef Yang Q, Wang L, Xiang WD, Zhou JF, Jiang GH (2007) Modification of carbon black through grafting multihydroxyl hyperbranched polyether onto its surface. J Appl Polym Sci 103(4):2086–2092CrossRef
Zurück zum Zitat Zeng FW, Zimmerman SC (1997) Dendrimers in supramolecular chemistry: from molecular recognition to self-assembly. Chem Rev 97(5):1681–1712CrossRef Zeng FW, Zimmerman SC (1997) Dendrimers in supramolecular chemistry: from molecular recognition to self-assembly. Chem Rev 97(5):1681–1712CrossRef
Zurück zum Zitat Zhang F, Chen YY, Lin H, Lu YH (2007) Synthesis of an amino-terminated hyperbranched polymer and its application in reactive dyeing on cotton as a salt-free dyeing auxiliary. Colorat Technol 123(6):351–357CrossRef Zhang F, Chen YY, Lin H, Lu YH (2007) Synthesis of an amino-terminated hyperbranched polymer and its application in reactive dyeing on cotton as a salt-free dyeing auxiliary. Colorat Technol 123(6):351–357CrossRef
Zurück zum Zitat Zhang F, Zhang D, Chen Y, Lin H (2009) The antimicrobial activity of the cotton fabric grafted with an amino-terminated hyperbranched polymer. Cellulose 16(2):281–288CrossRef Zhang F, Zhang D, Chen Y, Lin H (2009) The antimicrobial activity of the cotton fabric grafted with an amino-terminated hyperbranched polymer. Cellulose 16(2):281–288CrossRef
Zurück zum Zitat Zhou L, Gao C, Xu WJ (2009) Efficient grafting of hyperbranched polyglycerol from hydroxyl-functionalized multiwalled carbon nanotubes by surface-initiated anionic ring-opening polymerization. Macromol Chem Phy 210(12):1011–1018CrossRef Zhou L, Gao C, Xu WJ (2009) Efficient grafting of hyperbranched polyglycerol from hydroxyl-functionalized multiwalled carbon nanotubes by surface-initiated anionic ring-opening polymerization. Macromol Chem Phy 210(12):1011–1018CrossRef
Metadaten
Titel
Synthesis and characterization of cellulose fibers grafted with hyperbranched poly(3-methyl-3-oxetanemethanol)
verfasst von
Qiang Yang
Xuejun Pan
Fang Huang
Kecheng Li
Publikationsdatum
01.12.2011
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 6/2011
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-011-9587-y

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