nach oben

Journal of Materials Engineering and Performance

Erschienen in:

01.05.2014

Synthesis and Characterization of Nanostructured Platinum Coated Titanium as Electrode Material

verfasst von: K. R. Rasmi, S. C. Vanithakumari, R. P. George, U. Kamachi Mudali

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 5/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The present paper discusses the synthesis and characterization of nanostructured platinum coated titanium as electrode material. The electrodeposition of Pt particles on the Ti substrate was carried out from chloroplatinic acid at room temperature. Based on the cyclic voltammetric studies and UV-visible spectroscopy, direct reduction of Pt(IV) to Pt (0) was confirmed. The morphology of Pt particles was observed in scanning electron microscopy which revealed that the Pt particles with desired size were deposited on Ti from 5 mM electrolyte concentration at 60 s duration. The electrodeposited Pt particle on the Ti substrate subjected to hydrothermal reduction achieved complete coverage. Further microscopic observations and the energy dispersive spectroscopy results showed that the electrodeposited Pt particles acted as nuclei and enhanced further growth and coverage of particles during hydrothermal reduction. Also, morphology and surface coverage of Pt particle after hydrothermal reduction were found to be significantly influenced by the applied potential of the electrodeposition step. The electrochemical activity of the synthesized electrode was tested by conducting hydrogen adsorption-desorption study and oxygen reduction reaction.

Vorheriger Artikel Thermal Stability Study of Ultrafine Grained 304L Stainless Steel Produced by Martensitic Process

Nächster Artikel Actuator Response of Improved Two-Way Memory TiNi Wires Evaluated by Weight Fraction Diagrams

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

H.B. Beer, Dimensionally stable anodes, Electrochemistry in Industry, U. Landu, E. Yeager, D. Kortan, Eds., Plenum Press, New York, 1982, pp. 19–28.

C. Mallika and U. Kamachi, Mudali, Platinum-Modified Titanium Anodes for the Electrolytic Destruction of Nitric Acid, Electrochim. Acta, 2007, 52, p 6656–6664CrossRef

A. Baraka, H.H. Shaarawy, and H.A. Hamed, Electrodeposition of Platinum Metal and Platinum-Rhodium Alloy on Titanium Substrates, J. Mater. Eng. Perform., 2003, 12, p 5–13CrossRef

Q. Zeng, Y. Zhang, H.L. Wang, V. Papaefthymiou, and G.C. Hadjipanayis, Magnetic Properties and Microstructure of Fine Fe-Pt Nanoparticles Prepared by Chemical Reduction, J. Magn. Magn. Mater., 2004, 272, p 1223–1225CrossRef

C.L. Chang, T.C. Chang, W.Y. Ho, J.J. Hwang, and D.Y. Wang, Electrochemical Performance of PEM Fuel Cell with Pt-Ru Electro-Catalyst Layers Deposited by Sputtering, Surf. Coat. Technol., 2006, 201, p 4442–4446CrossRef

G. Lu and G. Zangari, Electrodeposition of Platinum on Highly Oriented Pyrolytic Graphite. Part I: Electrochemical Characterization, J. Phys. Chem. B, 2005, 109, p 7998–8007CrossRef

U. Kamachi Mudali, R.K. Dayal, and J.B. Gnanamoorthy, Mixed RuO₂/TiO₂/PtO₂-Coated Titanium Anodes for the Electrolytic Dissolution of Nuclear Fuels, Nucl. Technol., 1992, 100, p 395–402.

F. Kadirgan, S. Beyhan, and T. Atilan, Preparation and Characterization of Nano-Sized Pt-Pd/C Catalysts and Comparison of their Electro-Activity Toward Methanol and Ethanol Oxidation, Int. J. Hydrog. Energy, 2009, 34, p 4312–4320CrossRef

M. Shao, A. Peles, and K. Shoemaker, Electrocatalysis on Platinum Nanoparticles: Particle Size Effect on Oxygen Reduction Reaction Activity, Nano Lett., 2011, 11, p 3714–3719CrossRef

10.

I.J. Hsu, D.V. Esposito, E.G. Mahoney, A. Black, and J.G. Chen, Particle Shape Control Using Pulse Electrodeposition: Methanol Oxidation as a Probe Reaction on Pt Dendrites and Cubes, J. Power Source, 2011, 196, p 8307–8312CrossRef

11.

X. Fang, T. Ma, G. Guan, M. Akiyama, T. Kida, and E. Abe, Effect of the Thickness of Pt Filim Coated on a Counter Electrode on the Performance of a Dye-Sensitized Solar Cell, J. Electroanal. Chem., 2004, 570, p 257–263CrossRef

12.

P.R. Bueno, E. Joanni, R. Savu, L.M. Garcia, M.S. Goes, F.F. Santiago, and J. Bisquert, Platinum Coated Nanostructured Oxides for Active Catalytic Electrodes, Catal. Commun., 2011, 14, p 58–61CrossRef

13.

O. Antoine, Y. Bultel, and R. Durand, Oxygen Reduction Reaction Kinetics and Mechanism on Platinum Nanoparticles Inside Nafion, J. Electroanal. Chem., 2001, 499, p 85–94CrossRef

14.

J. Jiang and A. Kucernak, Investigations of Fuel Cell Reactions at Thecomposite Microelectrode Solid Polymer Electrolyte Interface. I. Hydrogen Oxidation at the Nanostructured Pt Nafion Membrane Interface, J. Electroanal. Chem., 2004, 567, p 123–137CrossRef

15.

A.L. Cheng, N.H. Kwi, N.B. Minh-Phuong, P. Xuan-Hung, H.H. Myung, I. Muhammad, S.K. Yong, and H.S. Gi, Morphology-Controlled Synthesis and electrocatalytic Characteristics of Platinum Structures on Micro-Patterned Carbon Nanotube Platforms, J. Appl. Electrochem., 2011, 41, p 1425–1431CrossRef

16.

M.G. Hosseini, S.A.S. Sajjadi, and M.M. Momeni, Electrodeposition of Platinum Metal on Titanium and Anodised Titanium from P Salt: Application to Electro-Oxidation of Glycerol, Surf. Eng., 2007, 23, p 419–424CrossRef

17.

C.R.K. Rao and M. Pushpavanam, Electroless Deposition of Platinum on Titanium Substrates, Mater. Chem. Phys., 2001, 68, p 62–65CrossRef

18.

C. Lamy, S. Rousseau, E.M. Belgsir, C. Coutanceau, and J.M. Léger, Recent Progress in the Direct Ethanol Fuel Cell: Development of New Platinum-Tin Electrocatalysts, Electrochim. Acta, 2004, 49, p 3901–3908CrossRef

19.

D. Sthitaprajna, S. Patra, and N. Munichandraiah, Electrooxidation of Formic Acid at Platinum Nanoclusters Electrodeposited on PEDOT Coated Carbon Paper Electrode, J. Appl. Electrochem., 2012, 42, p 59–67CrossRef

20.

A. Kay and M. Grätzel, Low Cost Photovoltaic Modules Based on Dye Sensitized Nanocrystalline Titanium Dioxide and Carbon Powder, Sol. Energy Mater. Sol. Cells, 1996, 44, p 99–117CrossRef

21.

L.A. Bray, J.L. Ryan, and E.J. Wheelwright, Development of the CEPOD Process for Dissolving Plutonium Oxide and Leaching Plutonium from Scrap or Wastes. Pacific Northwest Laboratory, Washington. Report No. PNL-5657 UC-70, 1985

22.

U. Kamachi Mudali, V.R. Raju, and R.K. Dayal, Preparation and Characterization of Platinum and Platinum-Iridium Coated Titanium Electrodes, J. Nucl. Mater., 1999, 277, p 49–56.

23.

F. Baumgartner and H. Schmieder, Use of Electrochemical Processes in Aqueous Reprocessing of Nuclear Fuel, Radiochim. Acta, 1978, 25, p 191–210

24.

X. Peng, K. Koczur, S. Nigro, and A. Chen, Fabrication and Electrochemical Properties of Novel Nanoporous Platinum Network Electrodes, Chem. Commun., 2004, 24, p 2872–2873CrossRef

25.

A.M. Feltham and M. Spiro, Platinized Platinum Electrodes, Chem. Rev., 1971, 71, p 177–193CrossRef

26.

Z. Tang, G. Dongsheng, and L. Gongxuan, A Simple Solution-Phase Reduction Method for the Synthesis of Shape-Controlled Platinum Nanoparticles, Mater. Lett., 2005, 59, p 1567–1570CrossRef

27.

L.M. Plyasova, M.I. Yu, A.N. Gavrilov, S.V. Cherepanova, O.V. Cherstiouk, A. Rudina, E.R. Savinova, and G.A. Tsirlina, Electrodeposited Platinum Revisited: Tuning Nanostructure Via the Deposition Potential, Electrochim. Acta, 2006, 51, p 4477–4488CrossRef

28.

S. Dominguez-Dominguez, J. Arias-Pardilla, A. Berenguer-Murcia, E. Morallon, and D. Cazorla-Amoros, Electrochemical Deposition of Platinum Nanoparticles on Different Carbon Supports and Conducting Polymers, J. Appl. Electrochem., 2008, 38, p 259–268CrossRef

29.

K. Koczkur, Q. Yi, and A. Chen, Nanoporous Pt-Ru Networks and their Electrocatalytical Properties, Adv. Mater., 2007, 19, p 2648–2652CrossRef

30.

V. Stamenkovic, N.M. Markovic, and P.N. Ross, Structure-Relationships in electrocatalysis: Oxygen Reduction and Hydrogen Oxidation Reactions on Pt (111) and Pt(100) in Solutions Containing Chloride Ions, J. Electroanal. Chem., 2001, 500, p 44–51CrossRef

31.

M. Jose, D. Rodriguez, J.A. Herrera, and J.P. Pena, Determination of Real surface Area of Pt Electrodes by Hydrogen Adsorption Using Cyclic Voltammetry, J. Chem Educ., 2000, 77, p 1195–1197CrossRef

32.

A. Pozio, M. De Francesco, A. Cemmi, F. Cardellini, and L. Giorgi, Comparison of High Surface Pt/C Catalysts by Cyclic Voltammetry, J. Power Sources, 2002, 105, p 13–19CrossRef

33.

Y. Xing, Synthesis and Electrochemical Characterization of Uniformly Dispersed High Loading Pt Nanoparticles on Sonochemically Treated Carbon Nanotubes, J Phys. Chem. B, 2004, 108, p 19255–19259CrossRef

34.

G. Chang, M. Oyama, and K. Hirao, In Situ Chemical Reductive Growth of Platinum Nano Particles on Indium Tin Oxide Surfaces and their Electrochemical Applications, J. Phys. Chem. B, 2006, 110, p 1860–1865CrossRef

35.

P.H. Hindle, Q. Yi, G. Wu, K. Koczkur, and A. Chen, Electrocatalytic Activity of Nanoporous Pt-Ir Materials Towards Methanol Oxidation and Oxygen Reduction, J. Electrochem. Soc., 2008, 155, p K5–K9CrossRef

Titel: Synthesis and Characterization of Nanostructured Platinum Coated Titanium as Electrode Material
verfasst von: K. R. Rasmi
S. C. Vanithakumari
R. P. George
U. Kamachi Mudali
Publikationsdatum: 01.05.2014
Verlag: Springer US
Erschienen in: Journal of Materials Engineering and Performance / Ausgabe 5/2014
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-014-0903-1

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 5/2014

In Situ Characterization of NiTi/Ti6Al4V Joints During Reaction-Assisted Diffusion Bonding Using Ni/Ti Multilayers

Adiabatic Shear Bands in Ti-6Al-4V Alloy with Lamellar Microstructure

Modeling Constitutive Relationship of Cu-0.4 Mg Alloy During Hot Deformation

Thermal Stability Study of Ultrafine Grained 304L Stainless Steel Produced by Martensitic Process

Fabrication and Characterization of Nickel Ferrite Based Inert Anodes for Aluminum Electrolysis

Temperature Dependence of Surface Tension of Sn-Ag Alloys

Premium Partner

Marktübersichten