Skip to main content
Erschienen in: Journal of Coatings Technology and Research 6/2018

15.06.2018

Synthesis and characterization of polyurethane/reduced graphene oxide composite deposited on steel

verfasst von: Eric C. Romani, Stefania Nardecchia, Cecilia Vilani, Shaojun Qi, Hanshan Dong, Fernando L. Freire Jr.

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 6/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

There has been an ongoing effort by the coatings industry to improve surface properties in order to increase corrosion and wear resistances, as well as other material properties. In this work, we report a methodology for producing nanocomposite films of polyurethane and graphene oxide and polyurethane and reduced graphene oxide. The coatings were applied on steel. The nanocomposites coatings were characterized by optical microscopy, scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, contact angle measurements, and electrochemical impedance spectroscopy. Corrosion tests reveal that the use of reduced graphene oxide increases corrosion resistance when compared with the use of graphene oxide as filler.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Zurück zum Zitat Li, X, Zhang, S, Liu, Z, Li, Z, Du, C, Dong, C, “Materials Science: Share Corrosion Data.” Nature, 527 441–442 (2013)CrossRef Li, X, Zhang, S, Liu, Z, Li, Z, Du, C, Dong, C, “Materials Science: Share Corrosion Data.” Nature, 527 441–442 (2013)CrossRef
2.
Zurück zum Zitat Moneta, T, Belluci, F, Nicodemo, L, Nicolais, L, “Protective Properties of Epoxy-Based Organic Coatings on Mild Steel.” Prog. Org. Coat., 21 353–369 (1993)CrossRef Moneta, T, Belluci, F, Nicodemo, L, Nicolais, L, “Protective Properties of Epoxy-Based Organic Coatings on Mild Steel.” Prog. Org. Coat., 21 353–369 (1993)CrossRef
3.
Zurück zum Zitat González-García, Y, González, S, Souto, RM, “Electrochemical and Structural Properties of a Polyurethane Coating on Steel Substrate for Corrosion Protection.” Corros. Sci., 49 3514–3526 (2007)CrossRef González-García, Y, González, S, Souto, RM, “Electrochemical and Structural Properties of a Polyurethane Coating on Steel Substrate for Corrosion Protection.” Corros. Sci., 49 3514–3526 (2007)CrossRef
4.
Zurück zum Zitat Cruz, RP, Nishikata, A, Tsuro, T, “Pitting Corrosion Mechanism of Type 304 Stainless Steel Under a Droplet of Chloride-Containing Environments.” Corros. Sci., 49 1394–1407 (2007)CrossRef Cruz, RP, Nishikata, A, Tsuro, T, “Pitting Corrosion Mechanism of Type 304 Stainless Steel Under a Droplet of Chloride-Containing Environments.” Corros. Sci., 49 1394–1407 (2007)CrossRef
5.
Zurück zum Zitat Azeez, AA, Rhee, KY, Park, SJ, “Epoxy Clay Nanocomposites-Processing, Properties and Applications: A Review.” Compos. B Eng., 45 308–320 (2013)CrossRef Azeez, AA, Rhee, KY, Park, SJ, “Epoxy Clay Nanocomposites-Processing, Properties and Applications: A Review.” Compos. B Eng., 45 308–320 (2013)CrossRef
6.
Zurück zum Zitat Alexandre, M, Dubois, P, “Polymer-Layered Silicate Nanocomposites: Preparation, Properties and Uses of a New Class of Materials.” Mater. Sci. Eng. R, 28 1–63 (2000)CrossRef Alexandre, M, Dubois, P, “Polymer-Layered Silicate Nanocomposites: Preparation, Properties and Uses of a New Class of Materials.” Mater. Sci. Eng. R, 28 1–63 (2000)CrossRef
7.
Zurück zum Zitat Shi, X, Nguyen, TA, Suo, Z, Yajun, L, Avci, R, “Effect of Nanoparticles on the Anticorrosion and Mechanical Properties of Epoxy Coating.” Surf. Coat. Technol., 204 237–245 (2009)CrossRef Shi, X, Nguyen, TA, Suo, Z, Yajun, L, Avci, R, “Effect of Nanoparticles on the Anticorrosion and Mechanical Properties of Epoxy Coating.” Surf. Coat. Technol., 204 237–245 (2009)CrossRef
8.
Zurück zum Zitat Palimi, MJ, Rostami, M, Mahdavian, M, Ramezanzadeh, B, “The Corrosion Protection Performance of the Polyurethane Coatings Containing Surface Modified Fe2O3 Nanoparticles.” Corrosion, 71 1012–1026 (2015)CrossRef Palimi, MJ, Rostami, M, Mahdavian, M, Ramezanzadeh, B, “The Corrosion Protection Performance of the Polyurethane Coatings Containing Surface Modified Fe2O3 Nanoparticles.” Corrosion, 71 1012–1026 (2015)CrossRef
9.
Zurück zum Zitat Ladan, M, Basirun, WJ, Kazi, SN, Rahman, FA, Fariza, A, “Corrosion Protection of AISI 1018 Steel Using Co-Doped TiO2/Polypyrrole Nanocomposites in 3.5% NaCl Solution.” Mater. Chem. Phys., 192 361–373 (2017)CrossRef Ladan, M, Basirun, WJ, Kazi, SN, Rahman, FA, Fariza, A, “Corrosion Protection of AISI 1018 Steel Using Co-Doped TiO2/Polypyrrole Nanocomposites in 3.5% NaCl Solution.” Mater. Chem. Phys., 192 361–373 (2017)CrossRef
10.
Zurück zum Zitat Novoselov, KS, Fal’ko, VI, Colombo, PR, Schab, MS, Kim, K, “A Roadmap for Graphene.” Nature, 490 192–200 (2012)CrossRef Novoselov, KS, Fal’ko, VI, Colombo, PR, Schab, MS, Kim, K, “A Roadmap for Graphene.” Nature, 490 192–200 (2012)CrossRef
11.
Zurück zum Zitat Nair, RR, Wu, HA, Jayaram, PN, Grigorieva, IV, Geim, AK, “Unimpeded Permeation of Water Through Helium-Leak–Tight Graphene-Based Membranes.” Science, 335 442–444 (2012)CrossRef Nair, RR, Wu, HA, Jayaram, PN, Grigorieva, IV, Geim, AK, “Unimpeded Permeation of Water Through Helium-Leak–Tight Graphene-Based Membranes.” Science, 335 442–444 (2012)CrossRef
12.
Zurück zum Zitat Prasai, D, Tuberquia, JC, Harl, RR, Jennings, GK, Bolotin, KI, “Graphene: Corrosion-Inhibiting Coating.” ACS Nano, 6 1102–1108 (2012)CrossRef Prasai, D, Tuberquia, JC, Harl, RR, Jennings, GK, Bolotin, KI, “Graphene: Corrosion-Inhibiting Coating.” ACS Nano, 6 1102–1108 (2012)CrossRef
13.
Zurück zum Zitat Schriver, M, Regan, W, Gannett, WJ, Zaniewski, AM, Crommiee, MF, Zettl, A, “Graphene as a Long-Term Metal Oxidation Barrier: Worse Than Nothing.” ACS Nano, 7 5763–5768 (2013)CrossRef Schriver, M, Regan, W, Gannett, WJ, Zaniewski, AM, Crommiee, MF, Zettl, A, “Graphene as a Long-Term Metal Oxidation Barrier: Worse Than Nothing.” ACS Nano, 7 5763–5768 (2013)CrossRef
14.
Zurück zum Zitat John, R, Ashokreddy, A, Vijayan, C, Pradeep, T, “Single- and Few-Layer Graphene Growth on Stainless Steel Substrates by Direct Thermal Chemical Vapour Deposition.” Nanotechnol., 22 165701 (2011)CrossRef John, R, Ashokreddy, A, Vijayan, C, Pradeep, T, “Single- and Few-Layer Graphene Growth on Stainless Steel Substrates by Direct Thermal Chemical Vapour Deposition.” Nanotechnol., 22 165701 (2011)CrossRef
15.
Zurück zum Zitat Park, S, Ruoff, RS, “Chemical Methods for the Production of Graphene.” Nat. Nanotechnol., 4 217–224 (2009)CrossRef Park, S, Ruoff, RS, “Chemical Methods for the Production of Graphene.” Nat. Nanotechnol., 4 217–224 (2009)CrossRef
16.
Zurück zum Zitat Hummers, WS, Jr, Offeman, RE, “Preparation of Graphitic Oxide.” J. Am. Chem. Soc., 80 1339–1339 (1958)CrossRef Hummers, WS, Jr, Offeman, RE, “Preparation of Graphitic Oxide.” J. Am. Chem. Soc., 80 1339–1339 (1958)CrossRef
17.
Zurück zum Zitat Krishnamoorthy, K, Veerapandian, M, Mohan, R, Kim, SJ, “Investigation of Raman and Photoluminescence Studies of Reduced Graphene Oxide Sheets.” Appl. Phys A, 106 501–506 (2012)CrossRef Krishnamoorthy, K, Veerapandian, M, Mohan, R, Kim, SJ, “Investigation of Raman and Photoluminescence Studies of Reduced Graphene Oxide Sheets.” Appl. Phys A, 106 501–506 (2012)CrossRef
18.
Zurück zum Zitat McAllister, MJ, Li, JL, Adamson, DH, Schniepp, HC, Abdala, AA, Liu, J, Herrera-Alonso, M, Milius, DL, Car, R, Prud’homme, RK, Akasay, IA, “Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite.” Chem. Mater., 19 4396–4404 (2007)CrossRef McAllister, MJ, Li, JL, Adamson, DH, Schniepp, HC, Abdala, AA, Liu, J, Herrera-Alonso, M, Milius, DL, Car, R, Prud’homme, RK, Akasay, IA, “Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite.” Chem. Mater., 19 4396–4404 (2007)CrossRef
19.
Zurück zum Zitat Young, RJ, Kinloch, IA, Gong, L, Novoselov, KS, “The Mechanics of Graphene Nanocomposites: A Review.” Compos. Sci. Technol., 72 1459–1476 (2012)CrossRef Young, RJ, Kinloch, IA, Gong, L, Novoselov, KS, “The Mechanics of Graphene Nanocomposites: A Review.” Compos. Sci. Technol., 72 1459–1476 (2012)CrossRef
20.
Zurück zum Zitat Liu, D, Zhao, W, Liu, S, Cen, Q, Xue, Q, “Comparative Tribological and Corrosion Resistance Properties of Epoxy Composite Coatings Reinforced with Functionalized Fullerene C60 and Graphene.” Surf. Coat. Technol., 286 354–364 (2016)CrossRef Liu, D, Zhao, W, Liu, S, Cen, Q, Xue, Q, “Comparative Tribological and Corrosion Resistance Properties of Epoxy Composite Coatings Reinforced with Functionalized Fullerene C60 and Graphene.” Surf. Coat. Technol., 286 354–364 (2016)CrossRef
21.
Zurück zum Zitat Pourhashem, S, Vaezi, MR, Rashidi, A, Bagherzadeh, MA, “Exploring Corrosion Protection Properties of Solvent Based Epoxy-graphene Oxide Nanocomposite Coatings on Mild Steel.” Corros. Sci., 115 78–92 (2017)CrossRef Pourhashem, S, Vaezi, MR, Rashidi, A, Bagherzadeh, MA, “Exploring Corrosion Protection Properties of Solvent Based Epoxy-graphene Oxide Nanocomposite Coatings on Mild Steel.” Corros. Sci., 115 78–92 (2017)CrossRef
22.
Zurück zum Zitat Christopher, G, Kulandainathan, MA, Harichandran, G, “Comparative Study of Effect of Corrosion on Mild Steel with Waterborne Polyurethane Dispersion Containing Graphene Oxide Versus Carbon Black Nanocomposites.” Prog. Org. Coat., 89 199–211 (2015)CrossRef Christopher, G, Kulandainathan, MA, Harichandran, G, “Comparative Study of Effect of Corrosion on Mild Steel with Waterborne Polyurethane Dispersion Containing Graphene Oxide Versus Carbon Black Nanocomposites.” Prog. Org. Coat., 89 199–211 (2015)CrossRef
23.
Zurück zum Zitat Ramezanzadeh, B, Ghasemi, E, Mahdavian, M, Changizi, E, Moghadam, MHM, “Covalently-Grafted Graphene Oxide Nanosheets to Improve Barrier and Corrosion Protection Properties of Polyurethane Coatings.” Carbon, 93 555–573 (2015)CrossRef Ramezanzadeh, B, Ghasemi, E, Mahdavian, M, Changizi, E, Moghadam, MHM, “Covalently-Grafted Graphene Oxide Nanosheets to Improve Barrier and Corrosion Protection Properties of Polyurethane Coatings.” Carbon, 93 555–573 (2015)CrossRef
24.
Zurück zum Zitat Mo, M, Zhao, W, Chen, Z, Yu, Q, Zeng, Z, Wu, X, Xue, Q, “Excellent Tribological and Anti-corrosion Performance of Polyurethane Composite Coatings Reinforced with Functionalized Graphene and Graphene Oxide Nanosheets.” RSC Adv., 5 56486–56497 (2015)CrossRef Mo, M, Zhao, W, Chen, Z, Yu, Q, Zeng, Z, Wu, X, Xue, Q, “Excellent Tribological and Anti-corrosion Performance of Polyurethane Composite Coatings Reinforced with Functionalized Graphene and Graphene Oxide Nanosheets.” RSC Adv., 5 56486–56497 (2015)CrossRef
25.
Zurück zum Zitat Cai, K, Zuo, S, Luo, S, Yao, C, Liu, W, Ma, J, Mao, H, Li, Z, “Preparation of Polyaniline/Graphene Composites with Excellent Anti-corrosion Properties and Their Application in Waterborne Polyurethane Anticorrosive Coatings.” RSC Adv., 6 95965–95972 (2016)CrossRef Cai, K, Zuo, S, Luo, S, Yao, C, Liu, W, Ma, J, Mao, H, Li, Z, “Preparation of Polyaniline/Graphene Composites with Excellent Anti-corrosion Properties and Their Application in Waterborne Polyurethane Anticorrosive Coatings.” RSC Adv., 6 95965–95972 (2016)CrossRef
26.
Zurück zum Zitat Xia, H, Song, M, “Preparation and Characterization of Polyurethane–Carbon Nanotube Composites.” Soft Mater., 1 386–394 (2005)CrossRef Xia, H, Song, M, “Preparation and Characterization of Polyurethane–Carbon Nanotube Composites.” Soft Mater., 1 386–394 (2005)CrossRef
27.
Zurück zum Zitat Yang, D, Velamakanni, A, Bozoku, G, Park, S, Stoller, M, Piner, RD, Stankovich, S, Jung, I, Field, DA, Ventrice, CA, Jr, Ruoff, RS, “Chemical Analysis of Graphene Oxide Films After Heat and Chemical Treatments by X-ray Photoelectron and Micro-Raman Spectroscopy.” Carbon, 47 145–152 (2009)CrossRef Yang, D, Velamakanni, A, Bozoku, G, Park, S, Stoller, M, Piner, RD, Stankovich, S, Jung, I, Field, DA, Ventrice, CA, Jr, Ruoff, RS, “Chemical Analysis of Graphene Oxide Films After Heat and Chemical Treatments by X-ray Photoelectron and Micro-Raman Spectroscopy.” Carbon, 47 145–152 (2009)CrossRef
28.
Zurück zum Zitat Su, C-Y, Xu, Y, Zhang, W, Zhao, J, Tang, X, Tsai, C-H, Li, L-J, “Electrical and Spectroscopic Characterizations of Ultra-large Reduced Graphene Oxide Monolayers.” Chem. Mater., 21 5674–5680 (2009)CrossRef Su, C-Y, Xu, Y, Zhang, W, Zhao, J, Tang, X, Tsai, C-H, Li, L-J, “Electrical and Spectroscopic Characterizations of Ultra-large Reduced Graphene Oxide Monolayers.” Chem. Mater., 21 5674–5680 (2009)CrossRef
29.
Zurück zum Zitat Cançado, LG, Takai, K, Enoki, T, Endo, M, Kim, YA, Mizusaki, H, Jorio, A, Coelho, LN, Magalhães-Paniago, R, Pimenta, MA, “General Equation for the Determination of the Crystallite Size La of Nanographite by Raman Spectroscopy.” Appl. Phys. Lett., 88 163106 (2006)CrossRef Cançado, LG, Takai, K, Enoki, T, Endo, M, Kim, YA, Mizusaki, H, Jorio, A, Coelho, LN, Magalhães-Paniago, R, Pimenta, MA, “General Equation for the Determination of the Crystallite Size La of Nanographite by Raman Spectroscopy.” Appl. Phys. Lett., 88 163106 (2006)CrossRef
31.
Zurück zum Zitat Aneja, KS, Böhm, HLM, Khanna, AS, Böhm, S, “Functionalized Graphene as a Barrier Against Corrosion.” FlatChem, 1 11–19 (2017)CrossRef Aneja, KS, Böhm, HLM, Khanna, AS, Böhm, S, “Functionalized Graphene as a Barrier Against Corrosion.” FlatChem, 1 11–19 (2017)CrossRef
32.
Zurück zum Zitat Qi, K, Sun, Y, Duan, H, Guo, X, “A Corrosion-Protective Coating Based on a Solution-Processable Polymer-Grafted Graphene Oxide Nanocomposite.” Corros. Sci., 98 500–506 (2015)CrossRef Qi, K, Sun, Y, Duan, H, Guo, X, “A Corrosion-Protective Coating Based on a Solution-Processable Polymer-Grafted Graphene Oxide Nanocomposite.” Corros. Sci., 98 500–506 (2015)CrossRef
33.
Zurück zum Zitat Abraham, J, Vasu, KS, Williams, CD, Gopinadhan, K, Su, Y, Cherian, CT, Dix, J, Prestat, E, Haigh, SJ, Grigorieva, IV, Carbone, P, Geim, AK, Nair, RR, “Tunable Sieving of Ions Using Graphene Oxide Membranes.” Nat. Nanotechnol., 12 546–550 (2017)CrossRef Abraham, J, Vasu, KS, Williams, CD, Gopinadhan, K, Su, Y, Cherian, CT, Dix, J, Prestat, E, Haigh, SJ, Grigorieva, IV, Carbone, P, Geim, AK, Nair, RR, “Tunable Sieving of Ions Using Graphene Oxide Membranes.” Nat. Nanotechnol., 12 546–550 (2017)CrossRef
Metadaten
Titel
Synthesis and characterization of polyurethane/reduced graphene oxide composite deposited on steel
verfasst von
Eric C. Romani
Stefania Nardecchia
Cecilia Vilani
Shaojun Qi
Hanshan Dong
Fernando L. Freire Jr.
Publikationsdatum
15.06.2018
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 6/2018
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-018-0088-x

Weitere Artikel der Ausgabe 6/2018

Journal of Coatings Technology and Research 6/2018 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.