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Erschienen in: Polymer Bulletin 8/2010

01.05.2010 | Original Paper

Synthesis and reaction kinetics model of suspension phase grafting polypropylene with dual monomers

verfasst von: Yuying Zheng, Songfang Zhao, Lei Cheng, Baoming Li

Erschienen in: Polymer Bulletin | Ausgabe 8/2010

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Abstract

The grafting polymerization of maleic anhydride (MAH) and styrene (St) onto PP was carried out in suspension phase. Infrared (IR) spectra and 1H-NMR spectra confirmed that MAH and St were successfully grafted onto the PP backbone. The influences, such as monomers concentration, reaction temperature, initiator concentration and reaction time, on the grafting polymerization rate were also studied, and then the polymerization model was obtained to describe the polymerization regularities. The results showed that the model was adequate to reflect the courses, and diffusion and equilibrium adsorption played an important role in suspension polymerization.

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Metadaten
Titel
Synthesis and reaction kinetics model of suspension phase grafting polypropylene with dual monomers
verfasst von
Yuying Zheng
Songfang Zhao
Lei Cheng
Baoming Li
Publikationsdatum
01.05.2010
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 8/2010
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-009-0171-7

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