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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 1/2016

01.04.2016 | Original Paper: Characterization Methods of Sol-Gel and Hybrid Materials

Synthesis, characterization and catalytic properties of La(Ni,Fe)O3–NiO nanocomposites

verfasst von: F. Djani, M. Omari, A. Martínez-Arias

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2016

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Abstract

Nanocomposite structures involving LaNiO3 perovskite partially substituted with iron and segregated NiO are synthesized by sol–gel method using citric acid as chelating agent. Thermogravimetric and differential thermal analysis and X-ray diffraction (XRD) techniques are used to explore precursor decomposition and to establish adequate calcination temperature for the preparation of the nanocomposites. The samples obtained after calcination at 750 °C were characterized by XRD, X-ray photoelectronic spectroscopy, Brunauer–Emmett–Teller surface area analysis, Fourier transform infrared spectroscopy and powder size distribution, and tested for the catalytic oxidation reaction of CO. Optimum catalytic properties are shown to be achieved for nanocomposites with relatively weak Fe/Ni substitution degree in the perovskite interacting with well-dispersed small NiO entities.

Graphical Abstract

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Metadaten
Titel
Synthesis, characterization and catalytic properties of La(Ni,Fe)O3–NiO nanocomposites
verfasst von
F. Djani
M. Omari
A. Martínez-Arias
Publikationsdatum
01.04.2016
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2016
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-015-3929-4

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