Skip to main content
Erschienen in: Interceram - International Ceramic Review 1/2020

01.02.2020 | Research and Development

Synthesis, Dehydroxylation and Sintering of Porous Mg(OH)2-MgO Clusters: Evolution of Microstructure and Physical Properties

verfasst von: Rafael Salomão, C.C. Arruda, Maria L.P. Antunes

Erschienen in: Interceram - International Ceramic Review | Ausgabe 1/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Abstract: Magnesium hydroxide (Mg(OH)2 or brucite) and magnesium oxide (MgO or magnesia) are essential raw materials for many industrial applications. Several studies have explored their production methods and the changes in their properties caused by adjustments in synthesis and calcination conditions. However, the ways the particles' microstructure changes along a full thermal treatment up to sintering remain unclear. This study investigated the effects of thermal treatments (120-1500 °C) on the physical properties and microstructure of clusters of Mg(OH)2 nanoparticles prepared by soluble-Mg-salt precipitation assisted by a surfactant agent.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Interceram - International Ceramic Review

Interceram - Das internationale Fachmagazin für das gesamte Gebiet der keramischen sowie thematisch verwandter Technologien. Jetzt kostenlos testen!

Literatur
[1]
Zurück zum Zitat Shand, M.A. The Chemistry and technology of magnesia. New Jersey: John Wiley & Sons, Inc. (2006), ISBN-13: 978-0-471-65603-6 Shand, M.A. The Chemistry and technology of magnesia. New Jersey: John Wiley & Sons, Inc. (2006), ISBN-13: 978-0-471-65603-6
[2]
Zurück zum Zitat Salomão, R., Pandolfelli, V.C.: Magnesia sinter hydration-dehydration behavior in refractory castables. Ceram. Int. 34 (2008) [8] 1829-1834 Salomão, R., Pandolfelli, V.C.: Magnesia sinter hydration-dehydration behavior in refractory castables. Ceram. Int. 34 (2008) [8] 1829-1834
[3]
Zurück zum Zitat Papich, M.G.: Magnesium hydroxide. In: Sauder's Handbook of Veterinary Drugs (4th Edition). Amsterdam: Elsevier (2016) 467-468, ISBN: 9780323244855 Papich, M.G.: Magnesium hydroxide. In: Sauder's Handbook of Veterinary Drugs (4th Edition). Amsterdam: Elsevier (2016) 467-468, ISBN: 9780323244855
[4]
Zurück zum Zitat Shen, S., Chow, P.S., Chen, F., Tan, R.B.H.: Submicron particles of SBA-15 modified with MgO as carriers for controlled drug delivery. Chem. Pharm. Bull. 55 (2007) [7] 985-991 Shen, S., Chow, P.S., Chen, F., Tan, R.B.H.: Submicron particles of SBA-15 modified with MgO as carriers for controlled drug delivery. Chem. Pharm. Bull. 55 (2007) [7] 985-991
[5]
Zurück zum Zitat Giorgi, R., Chelazzi, D., Baglioni, P.: Conservation of acid waterlogged shipwrecks: Nanotechnologies for de-acidification. App. Phys. A. 83 (2006) 567-571 Giorgi, R., Chelazzi, D., Baglioni, P.: Conservation of acid waterlogged shipwrecks: Nanotechnologies for de-acidification. App. Phys. A. 83 (2006) 567-571
[6]
Zurück zum Zitat Holloway, L.R.: Application of magnesium hydroxide as a flame retardant and smoke suppressant in elastomers. Rubb. Chem. Tech. 61 (1987) [2] 186-193 Holloway, L.R.: Application of magnesium hydroxide as a flame retardant and smoke suppressant in elastomers. Rubb. Chem. Tech. 61 (1987) [2] 186-193
[7]
Zurück zum Zitat Norton, R.N., Hornsby, P.R.: Flame retardant effects of magnesium hydroxide. Pol. Deg. Stab. 54 (1996) 383-385 Norton, R.N., Hornsby, P.R.: Flame retardant effects of magnesium hydroxide. Pol. Deg. Stab. 54 (1996) 383-385
[8]
Zurück zum Zitat Qiu, L., Xie, R., Ding, P., Qu, B.: Preparation and characterization of Mg[OH]2 nanoparticles and flame-retardant property of its nanocomposites with EVA. Compos. Struc. 62 (2003) 391-395 Qiu, L., Xie, R., Ding, P., Qu, B.: Preparation and characterization of Mg[OH]2 nanoparticles and flame-retardant property of its nanocomposites with EVA. Compos. Struc. 62 (2003) 391-395
[9]
Zurück zum Zitat Gui, H., Zhang, X., Liu, Y., Dong, W., Wang, Q., Gao, J., Song, Z., Lai, J., Qiao, J.: Effect of dispersion of nano-magnesium hydroxide on the flammability of flame retardant ternary composites. Compos. Sci. Tech. 67 (2007) 67 974-980 Gui, H., Zhang, X., Liu, Y., Dong, W., Wang, Q., Gao, J., Song, Z., Lai, J., Qiao, J.: Effect of dispersion of nano-magnesium hydroxide on the flammability of flame retardant ternary composites. Compos. Sci. Tech. 67 (2007) 67 974-980
[10]
Zurück zum Zitat Salomão, R., Souza, A.D.V., Cardoso, P.H.L.: A comparison of Al(OH)3 and Mg(OH)2 as inorganic porogenic agents for alumina. Interceram: Int. Cer. Rev. 64 (2015) [4] 193-199 Salomão, R., Souza, A.D.V., Cardoso, P.H.L.: A comparison of Al(OH)3 and Mg(OH)2 as inorganic porogenic agents for alumina. Interceram: Int. Cer. Rev. 64 (2015) [4] 193-199
[11]
Zurück zum Zitat Hüttig, G.F.: Die Kinetic der Alterung von aktivem Magnseiumoxyd. Kolloid-Zeitschrift 124 (1951) [3] 160-163 Hüttig, G.F.: Die Kinetic der Alterung von aktivem Magnseiumoxyd. Kolloid-Zeitschrift 124 (1951) [3] 160-163
[12]
Zurück zum Zitat Finch, G.I., Sinha, K.P.: On reaction in the solid state. Proc. Roy. Soc. A. 239 (1957) 145-153 Finch, G.I., Sinha, K.P.: On reaction in the solid state. Proc. Roy. Soc. A. 239 (1957) 145-153
[13]
Zurück zum Zitat Razouk, R.I., Mikhail, R.S.: The hydration of magnesium oxide from vapor phase. J. Phys. Chem. 62 (1958) 920-925 Razouk, R.I., Mikhail, R.S.: The hydration of magnesium oxide from vapor phase. J. Phys. Chem. 62 (1958) 920-925
[14]
Zurück zum Zitat Glasson, D.R.: Reactivity of lime and related oxides: Hydration of magnesium oxide. J. App. Chem. 13 (1963) [3] 119-123 Glasson, D.R.: Reactivity of lime and related oxides: Hydration of magnesium oxide. J. App. Chem. 13 (1963) [3] 119-123
[15]
Zurück zum Zitat Layden, G.K., Brindley, G.W.: Kinetics of vapor-phase hydration of magnesium oxide. J. Am. Cer. Soc. 46 (1963) [11] 518-522 Layden, G.K., Brindley, G.W.: Kinetics of vapor-phase hydration of magnesium oxide. J. Am. Cer. Soc. 46 (1963) [11] 518-522
[16]
Zurück zum Zitat Anderson, P.J., Horlock, R.F., Oliver, J.F.: Interaction of water with the magnesium oxide surface. Trans. Farad. Soc. 61 (1965) [516] 2754-2762 Anderson, P.J., Horlock, R.F., Oliver, J.F.: Interaction of water with the magnesium oxide surface. Trans. Farad. Soc. 61 (1965) [516] 2754-2762
[17]
Zurück zum Zitat Feitknecht, W., Braum, H.: Der Mechanismus der Hydratation von Magnesiumoxid mit Wasserdampf. Helv. Chim. Act. 50 (1967) [7] 2040-2053 Feitknecht, W., Braum, H.: Der Mechanismus der Hydratation von Magnesiumoxid mit Wasserdampf. Helv. Chim. Act. 50 (1967) [7] 2040-2053
[18]
Zurück zum Zitat Smithson, C.L., Bakhshi, N.N.: The kinetics and mechanism of the hydration of magnesium oxide in a batch reactor. Can. J. Chem. Eng. 47 (1969) [6] 508-513 Smithson, C.L., Bakhshi, N.N.: The kinetics and mechanism of the hydration of magnesium oxide in a batch reactor. Can. J. Chem. Eng. 47 (1969) [6] 508-513
[19]
Zurück zum Zitat Birchal, V.S., Rocha, S.D.F., Mansur, M.B., Ciminelli, V.S.T.: A simplified mechanistic analysis of the hydration of magnesia. Can. J. Chem. Eng. 79 (2001) [4] 507-511 Birchal, V.S., Rocha, S.D.F., Mansur, M.B., Ciminelli, V.S.T.: A simplified mechanistic analysis of the hydration of magnesia. Can. J. Chem. Eng. 79 (2001) [4] 507-511
[20]
Zurück zum Zitat Rocha, S.D.F., Mansur, M.B., Ciminelli, V.S.T.: Kinetics and mechanistic analysis of caustic magnesia hydration. J. Chem. Tech. Biotech. 79 (2004) [8] 816-821 Rocha, S.D.F., Mansur, M.B., Ciminelli, V.S.T.: Kinetics and mechanistic analysis of caustic magnesia hydration. J. Chem. Tech. Biotech. 79 (2004) [8] 816-821
[21]
Zurück zum Zitat Kitamura, A., Onizuka, K., Tanaka, K.: Hydration characteristics of magnesia. Taikabutsu Overs. 16 (1995) [3] 3-11 Kitamura, A., Onizuka, K., Tanaka, K.: Hydration characteristics of magnesia. Taikabutsu Overs. 16 (1995) [3] 3-11
[22]
Zurück zum Zitat Salomão, R., Arruda, C.C., Kawamura, M.A.: A systemic investigation on the hydroxylation behavior of caustic magnesia and magnesia sinter. Ceram. Int. 41 (2015) [10] 13998-14007 Salomão, R., Arruda, C.C., Kawamura, M.A.: A systemic investigation on the hydroxylation behavior of caustic magnesia and magnesia sinter. Ceram. Int. 41 (2015) [10] 13998-14007
[23]
Zurück zum Zitat Liu, J.P., Wang, Y.J., Tian, Q., Zhang, S.Z.: Modeling hydration process of magnesia based on nucleation and growth theory: The isothermal calorimetry study. Thermoch. Act. 550 (2012) [20] 27-32 Liu, J.P., Wang, Y.J., Tian, Q., Zhang, S.Z.: Modeling hydration process of magnesia based on nucleation and growth theory: The isothermal calorimetry study. Thermoch. Act. 550 (2012) [20] 27-32
[24]
Zurück zum Zitat Salomão, R., Arruda, C.C., Souza, A.D.V., Fernandes, L.: Novel insights into MgO hydroxylation: Effects of testing temperature, samples' volume and solid load. Ceram. Int. 40 (2014) [9B] 14809-14815 Salomão, R., Arruda, C.C., Souza, A.D.V., Fernandes, L.: Novel insights into MgO hydroxylation: Effects of testing temperature, samples' volume and solid load. Ceram. Int. 40 (2014) [9B] 14809-14815
[25]
Zurück zum Zitat Chatterji, S.: Mechanism of expansion of conc. due to the presence of dear-burnt CaO and MgO. Cem. Conc. Res. 25 (1995) 51-56 Chatterji, S.: Mechanism of expansion of conc. due to the presence of dear-burnt CaO and MgO. Cem. Conc. Res. 25 (1995) 51-56
[26]
Zurück zum Zitat Salomão, R., Bittencourt, L.R.M., Pandolfelli, V.C.: A novel approach for magnesia hydration assessment in refractory castables. Ceram. Int. 33 (2007) [5] 803-810 Salomão, R., Bittencourt, L.R.M., Pandolfelli, V.C.: A novel approach for magnesia hydration assessment in refractory castables. Ceram. Int. 33 (2007) [5] 803-810
[27]
Zurück zum Zitat Khangaonkar, P.R., Othman, R., Ranjitham, M.: Studies on particle breakage during hydration of calcined magnesite. Min. Eng. 3 (1990) [1-2] 227-235 Khangaonkar, P.R., Othman, R., Ranjitham, M.: Studies on particle breakage during hydration of calcined magnesite. Min. Eng. 3 (1990) [1-2] 227-235
[28]
Zurück zum Zitat Sutcu, M., Akkurt, S., Okur, S.: A microstructural study of surface hydration on a magnesia refractory. Ceram. Int. 36 (2010) [5] 1731-1735 Sutcu, M., Akkurt, S., Okur, S.: A microstructural study of surface hydration on a magnesia refractory. Ceram. Int. 36 (2010) [5] 1731-1735
[29]
Zurück zum Zitat Kaneyasu, A., Yamamoto, S., Yoshida, A.: Magnesia raw materials with improved hydration resistance. Taikabutsu Overs. 17 (1996) [2] 21-26 Kaneyasu, A., Yamamoto, S., Yoshida, A.: Magnesia raw materials with improved hydration resistance. Taikabutsu Overs. 17 (1996) [2] 21-26
[30]
Zurück zum Zitat Amaral, L.F., Oliveira, I.R., Salomão, R., Frollini, E., Pandolfelli, V.C.: Temperature and common-ion effect on magnesium oxide (MgO) hydration. Ceram. Int. 36 (2010) [3] 1047-1054 Amaral, L.F., Oliveira, I.R., Salomão, R., Frollini, E., Pandolfelli, V.C.: Temperature and common-ion effect on magnesium oxide (MgO) hydration. Ceram. Int. 36 (2010) [3] 1047-1054
[31]
Zurück zum Zitat Amaral, L.F., Oliveira, I.R., Bonadia, P., Salomão, R., Pandolfelli, V.C.: Chelants to inhibit magnesia [MgO] hydration. Ceram. Int. 37 (2011) [5] 1537-1542 Amaral, L.F., Oliveira, I.R., Bonadia, P., Salomão, R., Pandolfelli, V.C.: Chelants to inhibit magnesia [MgO] hydration. Ceram. Int. 37 (2011) [5] 1537-1542
[32]
Zurück zum Zitat Salomão, R., Pandolfelli, V.C.: Citric acid as anti-hydration additive for magnesia containing refractory castables. Ceram. Int. 37 (2011) [6] 1839-1842 Salomão, R., Pandolfelli, V.C.: Citric acid as anti-hydration additive for magnesia containing refractory castables. Ceram. Int. 37 (2011) [6] 1839-1842
[33]
Zurück zum Zitat Souza, T.M., Luz, A.P., Pandolfelli, V.C.: Magnesium fluoride role on alumina-magnesia Cem.-bonded castables. Ceram. Int. 40 (2014) [9] 14947-14956 Souza, T.M., Luz, A.P., Pandolfelli, V.C.: Magnesium fluoride role on alumina-magnesia Cem.-bonded castables. Ceram. Int. 40 (2014) [9] 14947-14956
[34]
Zurück zum Zitat Salomão, R. Bittencourt, L.R.M., Pandolfelli, V.C.: A novel magnesia based binder [MBB] for refractory castables. Interceram: Int. Cer. Rev. Refrac. Man. (2009) 21-24 Salomão, R. Bittencourt, L.R.M., Pandolfelli, V.C.: A novel magnesia based binder [MBB] for refractory castables. Interceram: Int. Cer. Rev. Refrac. Man. (2009) 21-24
[35]
Zurück zum Zitat Souza, T.M., Luz, A.P., Bráulio, M.A.L., Pagliosa, C., Pandolfelli, V.C.: Acetic acid role on magnesia hydration for Cem.-free refractory castables. J. Am. Cer. Soc. 97 (2014) [4] 1233-1241 Souza, T.M., Luz, A.P., Bráulio, M.A.L., Pagliosa, C., Pandolfelli, V.C.: Acetic acid role on magnesia hydration for Cem.-free refractory castables. J. Am. Cer. Soc. 97 (2014) [4] 1233-1241
[36]
Zurück zum Zitat Henrist, C., Mathieu, J.P., Vogels, C., Rulmont, A., Cloots, R.: Morphological study of magnesium hydroxide nanoparticles precipitated in dilute aqueous solution. J. Cryst. Grow. 249 (2003) 321-330 Henrist, C., Mathieu, J.P., Vogels, C., Rulmont, A., Cloots, R.: Morphological study of magnesium hydroxide nanoparticles precipitated in dilute aqueous solution. J. Cryst. Grow. 249 (2003) 321-330
[37]
Zurück zum Zitat Lv, J., Qiu, L., Qu, B.: Controlled growth of three morphological structures of magnesium hydroxide nanoparticles by wet precipitation method. J. Cryst. Grow. 267 (2004) 676-684 Lv, J., Qiu, L., Qu, B.: Controlled growth of three morphological structures of magnesium hydroxide nanoparticles by wet precipitation method. J. Cryst. Grow. 267 (2004) 676-684
[38]
Zurück zum Zitat Pokrovsky, O.S., Schott, J.: Experimental study of brucite dissolution and precipitation in aqueous solutions: Surface specification and chemical affinity control. Geochim. Cosmochim. Act. 68 (2004) [1] 31-45 Pokrovsky, O.S., Schott, J.: Experimental study of brucite dissolution and precipitation in aqueous solutions: Surface specification and chemical affinity control. Geochim. Cosmochim. Act. 68 (2004) [1] 31-45
[39]
Zurück zum Zitat Hsu, J.P., Nacu, A.: Preparation of submicron-sized Mg[OH]2 particles through precipitation. Coll. Surf. A. 262 (2005) 220-231 Hsu, J.P., Nacu, A.: Preparation of submicron-sized Mg[OH]2 particles through precipitation. Coll. Surf. A. 262 (2005) 220-231
[40]
Zurück zum Zitat Yan, C., Xue, D., Zou, L., Yan, X., Wang, W.: Preparation of magnesium hydroxide nanoflowers. J. Cryst. Grow. 282 (2005) 448-454 Yan, C., Xue, D., Zou, L., Yan, X., Wang, W.: Preparation of magnesium hydroxide nanoflowers. J. Cryst. Grow. 282 (2005) 448-454
[41]
Zurück zum Zitat Chen, D., Zhu, L., Liu, P., Zhang, H., Xu, K., Chen M.: Rod-like morphological magnesium hydroxide and magnesium oxide via a wet coprecipitation process. J. Por. Mat. 16 (2009) [1] 13-18 Chen, D., Zhu, L., Liu, P., Zhang, H., Xu, K., Chen M.: Rod-like morphological magnesium hydroxide and magnesium oxide via a wet coprecipitation process. J. Por. Mat. 16 (2009) [1] 13-18
[42]
Zurück zum Zitat Wang, W., Qiao, X., Chen, J., Li, H.: Facile synthesis of magnesium oxide nanoplates via chemical precipitation. Mat. Lett. 61 (2007) 3218-3220 Wang, W., Qiao, X., Chen, J., Li, H.: Facile synthesis of magnesium oxide nanoplates via chemical precipitation. Mat. Lett. 61 (2007) 3218-3220
[43]
Zurück zum Zitat Yoshida, T., Tahaka, T., Yoshida, H., Funabiki, T., Yoshida, S., Murata, T.: Study of dehydration of magnesium hydroxide. J. Phys. Chem. 99 (1995) [27] 10890-10896 Yoshida, T., Tahaka, T., Yoshida, H., Funabiki, T., Yoshida, S., Murata, T.: Study of dehydration of magnesium hydroxide. J. Phys. Chem. 99 (1995) [27] 10890-10896
[44]
Zurück zum Zitat Mishakov, I.V., Bedilo, A.F., Richards, R.M., Chesnokov, V.V., Volodin, A.M., Zaikovskii, V.I., Buyanov, R.A., Kladunde, K.J.: Nanocrystalline MgO as a dehydrohalogenation catalyst. J. Cat. 206 (2002) 40-48 Mishakov, I.V., Bedilo, A.F., Richards, R.M., Chesnokov, V.V., Volodin, A.M., Zaikovskii, V.I., Buyanov, R.A., Kladunde, K.J.: Nanocrystalline MgO as a dehydrohalogenation catalyst. J. Cat. 206 (2002) 40-48
[45]
Zurück zum Zitat Gregg, S.J., Razouk, R.I.: Kinetics of thermal decomposition of magnesium hydroxide. J. Chem. Soc. (1949) S36-44 Gregg, S.J., Razouk, R.I.: Kinetics of thermal decomposition of magnesium hydroxide. J. Chem. Soc. (1949) S36-44
[46]
Zurück zum Zitat Brewer, L., Porter, R.F.: A thermodynamic and spectroscopic study of gaseous magnesium oxide. J. Chem. Phys. 22 (1954) 1867-1877 Brewer, L., Porter, R.F.: A thermodynamic and spectroscopic study of gaseous magnesium oxide. J. Chem. Phys. 22 (1954) 1867-1877
[47]
Zurück zum Zitat Goodman, J.F.: The decomposition of magnesium hydroxide in an electron microscope. In: Proc. Roy. Soc. Lon. A. 247 (1958) [1250] 346-352 Goodman, J.F.: The decomposition of magnesium hydroxide in an electron microscope. In: Proc. Roy. Soc. Lon. A. 247 (1958) [1250] 346-352
[48]
Zurück zum Zitat Ball, M.C., Taylor, F.W.: The dehydration of brucite. Min. Mag. and J. Min. Soc. 32 (1961) [253] 754-766 Ball, M.C., Taylor, F.W.: The dehydration of brucite. Min. Mag. and J. Min. Soc. 32 (1961) [253] 754-766
[49]
Zurück zum Zitat Anderson, P.J., Horlock, R.F.: Thermal decomposition of magnesium hydroxide. Trans. Farad. Soc. 58 (1962) [475] 1993-2004 Anderson, P.J., Horlock, R.F.: Thermal decomposition of magnesium hydroxide. Trans. Farad. Soc. 58 (1962) [475] 1993-2004
[50]
Zurück zum Zitat Turner, R.C., Hoffman, I., Chen, D.: Thermogravimetry of the dehydration of Mg[OH]2. Can. J. Chem. 41 (1963) [2] 243-251 Turner, R.C., Hoffman, I., Chen, D.: Thermogravimetry of the dehydration of Mg[OH]2. Can. J. Chem. 41 (1963) [2] 243-251
[51]
Zurück zum Zitat Pampuch, R., Librant, Z., Piekarczyk, J.: Texture and sinterability of MgO powders. Ceram. Inter. 1 (1975) [1] 14-18 Pampuch, R., Librant, Z., Piekarczyk, J.: Texture and sinterability of MgO powders. Ceram. Inter. 1 (1975) [1] 14-18
[52]
Zurück zum Zitat Gordon, R.S., Kingery, W.D.: Thermal decomposition of brucite: I, Electron and optical microscope studies. J. Am. Cer. Soc. 49 (1966) [12] 654-660 Gordon, R.S., Kingery, W.D.: Thermal decomposition of brucite: I, Electron and optical microscope studies. J. Am. Cer. Soc. 49 (1966) [12] 654-660
[53]
Zurück zum Zitat Brett, N.H., Anderson, P.J.: Mechanism of decomposition of brucite. Trans. Farad. Soc. 63 (1967) 2044-2050 Brett, N.H., Anderson, P.J.: Mechanism of decomposition of brucite. Trans. Farad. Soc. 63 (1967) 2044-2050
[54]
Zurück zum Zitat Liu, C., Liu, T., Wang, D.: Non-isothermal kinetics study on the thermal decomposition of brucite by thermogravimetry. J. Therm. Anal. Calor. 134 (2018) 2399-2347 Liu, C., Liu, T., Wang, D.: Non-isothermal kinetics study on the thermal decomposition of brucite by thermogravimetry. J. Therm. Anal. Calor. 134 (2018) 2399-2347
[55]
Zurück zum Zitat Kim, M.G., Dahmen, U., Searcy, A.W.: Structural transformation in decomposition of Mg[OH]2 and MgCO3. J. Am. Cer. Soc. 70 (1987) [3] 146-154 Kim, M.G., Dahmen, U., Searcy, A.W.: Structural transformation in decomposition of Mg[OH]2 and MgCO3. J. Am. Cer. Soc. 70 (1987) [3] 146-154
[56]
Zurück zum Zitat Phillips, V.A., Opperhauser, H., Kolbe, J.L.: Relations among particle size, shape and surface area of Mg[OH]2 and its calcination product. J. Am. Cer. Soc. 61 (1978) [1] 78-81 Phillips, V.A., Opperhauser, H., Kolbe, J.L.: Relations among particle size, shape and surface area of Mg[OH]2 and its calcination product. J. Am. Cer. Soc. 61 (1978) [1] 78-81
[57]
Zurück zum Zitat Green, J.: Calcination of precipitated Mg[OH]2 to active MgO in production of refractory and chemical grade MgO. J. Mat. Sci. 18 (1983) 637-651 Green, J.: Calcination of precipitated Mg[OH]2 to active MgO in production of refractory and chemical grade MgO. J. Mat. Sci. 18 (1983) 637-651
[58]
Zurück zum Zitat Wang, J.A., Novaro, A.O., Bokhimi, X., López, T., Gómez, R., Navarrete, J., Llanos, M.E., López-Salina, E.: Characterizations of the thermal decomposition of brucite prepared by sol-gel technique for synthesis of nanocrystalline MgO. Mat. Lett. 35 (1998) 317-323 Wang, J.A., Novaro, A.O., Bokhimi, X., López, T., Gómez, R., Navarrete, J., Llanos, M.E., López-Salina, E.: Characterizations of the thermal decomposition of brucite prepared by sol-gel technique for synthesis of nanocrystalline MgO. Mat. Lett. 35 (1998) 317-323
[59]
Zurück zum Zitat Kabalah-Amitai, L., Mayzel, B., Kauffmann, Y., Fitch, A.N., Bloch, L., Gilbert, P.U.P.A., Pokroy, B.: Vaterite crystals containing two interspersed crystal structures. Science 340 (2013) [6131] 454-457 Kabalah-Amitai, L., Mayzel, B., Kauffmann, Y., Fitch, A.N., Bloch, L., Gilbert, P.U.P.A., Pokroy, B.: Vaterite crystals containing two interspersed crystal structures. Science 340 (2013) [6131] 454-457
[60]
Zurück zum Zitat Wang, C., He, C., Tong, Z., Liu, X., Ren, B., Zeng, F.: Combination of adsorption by porous CaCO3 microparticles and encapsulation by polyelectrolyte multilayer films for sustained drug delivery. Int. J. Pharm. 308 (2006) 160-167 Wang, C., He, C., Tong, Z., Liu, X., Ren, B., Zeng, F.: Combination of adsorption by porous CaCO3 microparticles and encapsulation by polyelectrolyte multilayer films for sustained drug delivery. Int. J. Pharm. 308 (2006) 160-167
[61]
Zurück zum Zitat Costa, L.M.M., Sakihama, J., Salomão, R.: Characterization of porous calcium hexaluminate produced from calcined alumina and microspheres of Vaterire (µ-CaCO3). J. Eur. Cer. Soc. 38 (2018) 5208-5218 Costa, L.M.M., Sakihama, J., Salomão, R.: Characterization of porous calcium hexaluminate produced from calcined alumina and microspheres of Vaterire (µ-CaCO3). J. Eur. Cer. Soc. 38 (2018) 5208-5218
[62]
Zurück zum Zitat Fernandes, L., Salomão, R.: Preparation and characterization of mullite-alumina structures formed "in situ" from calcined alumina and different grades of synthetic amorphous silica. Mat. Res. 21 (2018) [3] e20170783 Fernandes, L., Salomão, R.: Preparation and characterization of mullite-alumina structures formed "in situ" from calcined alumina and different grades of synthetic amorphous silica. Mat. Res. 21 (2018) [3] e20170783
[63]
Zurück zum Zitat Cimino, A., Porta, P., Valigi, M.: Dependence on the lattice parameter of magnesium oxide on crystallite size. J. Am. Cer. Soc. 49 (1966) [3] 152-156 Cimino, A., Porta, P., Valigi, M.: Dependence on the lattice parameter of magnesium oxide on crystallite size. J. Am. Cer. Soc. 49 (1966) [3] 152-156
[64]
Zurück zum Zitat Guilliat, I.F., Brett, N.H.: X-ray line broadening as a measure of crystallite size in oxide powders. Phil. Mag. 21 (1970) [172] 671-680 Guilliat, I.F., Brett, N.H.: X-ray line broadening as a measure of crystallite size in oxide powders. Phil. Mag. 21 (1970) [172] 671-680
[65]
Zurück zum Zitat Wuensch, B.J., Vasilos, T.: Grain-boundary diffusion in MgO. The American Ceramic Soc. 47 (1964) [2] 63-68 Wuensch, B.J., Vasilos, T.: Grain-boundary diffusion in MgO. The American Ceramic Soc. 47 (1964) [2] 63-68
[66]
Zurück zum Zitat Robertson, W.M.: Kinetics of grain boundary grooving on magnesium oxide. In: Kuczynski, G.C., Hooton, N.A., Gibbon, C.F., eds. Sintering and Related Phenomena. New York. Gordon and Breach, Science Publishers (1965) 215-230. Library of Congress Catalog Card 67-26576. LCCN Permalink: https://lccn.loc.gov/67026576. Robertson, W.M.: Kinetics of grain boundary grooving on magnesium oxide. In: Kuczynski, G.C., Hooton, N.A., Gibbon, C.F., eds. Sintering and Related Phenomena. New York. Gordon and Breach, Science Publishers (1965) 215-230. Library of Congress Catalog Card 67-26576. LCCN Permalink: https://​lccn.​loc.​gov/​67026576.​
[67]
Zurück zum Zitat Lowrie, R.C., Cutler, I.B.: The effect of porosity on the rate of grain growth of magnesia. In: Kuczynski, G.C., Hooton, N.A., Gibbon, C.F., eds. Sintering and Related Phenomena. New York. Gordon and Breach, Science Publishers (1965) 527-539. Library of Congress Catalog Card 67-26576. LCCN Permalink: https://lccn.loc.gov/67026576. Lowrie, R.C., Cutler, I.B.: The effect of porosity on the rate of grain growth of magnesia. In: Kuczynski, G.C., Hooton, N.A., Gibbon, C.F., eds. Sintering and Related Phenomena. New York. Gordon and Breach, Science Publishers (1965) 527-539. Library of Congress Catalog Card 67-26576. LCCN Permalink: https://​lccn.​loc.​gov/​67026576.​
Metadaten
Titel
Synthesis, Dehydroxylation and Sintering of Porous Mg(OH)2-MgO Clusters: Evolution of Microstructure and Physical Properties
verfasst von
Rafael Salomão
C.C. Arruda
Maria L.P. Antunes
Publikationsdatum
01.02.2020
Verlag
Springer Fachmedien Wiesbaden
Erschienen in
Interceram - International Ceramic Review / Ausgabe 1/2020
Print ISSN: 0020-5214
Elektronische ISSN: 2523-8957
DOI
https://doi.org/10.1007/s42411-019-0067-y

Weitere Artikel der Ausgabe 1/2020

Interceram - International Ceramic Review 1/2020 Zur Ausgabe

Industries

Professional

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.