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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 1/2021

17.06.2021 | Original Paper: Sol–gel and hybrid materials for energy, environment and building applications

Synthesis of carboxymethyl β-cyclodextrin bonded Fe3O4@SiO2–NH2 core-shell magnetic nanocomposite adsorbent for effective removal of Pb(II) from wastewater

verfasst von: Ziba Jahanbakhsh, Hossein Hosseinzadeh, Bakhshali Masoumi

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2021

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Abstract

In this work, a novel functionalized magnetic Fe3O4@SiO2 core-shell nanoparticles grafted with carboxymethyl β-cyclodextrin (CM-β-CD) is utilized for adsorption of Pb(II) ions from aqueous solutions. The grafting reaction was performed via carbodimide method by using 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) and N-hydroxysuccinimide (NHS). The as-prepared nanoadsorbents were characterized by FTIR, SEM, TEM, XRD, TGA, and VSM. The grafting CM-β-CD on the Fe3O4@SiO2 core-shell nanoparticles enhances the ion adsorption capacity due to the strong abilities of the enormous –OH and –COOH functional groups in CM-β-CD to adsorb Pb(II) ions. The effects of factors such as the concentration of β-CD, contact time, initial ion concentration, adsorbent dosage, adsorption kinetics, and isotherms on the adsorption behavior were studied properly. The results depicted that the nanoadsorbents had good adsorption with the maximum adsorption capacity of 170 mg g−1 at 25 °C and pH 6.0. All the equilibrium adsorption kinetics of Pb(II) are fitted well to the pseudo-second-order model. The adsorption data were also found to follow the Langmuir adsorption isotherm model. In summary, the experimental Pb(II) ion adsorption data showed the prepared nanocomposites would be as promising adsorbents to remove various heavy metals from wastewater.
Vorheriger Artikel Preparation and thermal performance of ternary carbonates/silica microcomposites as phase change materials
Nächster Artikel Polydimethylsiloxane amino functionalized sponge for adsorption of copper in water

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Metadaten
Titel
Synthesis of carboxymethyl β-cyclodextrin bonded Fe3O4@SiO2–NH2 core-shell magnetic nanocomposite adsorbent for effective removal of Pb(II) from wastewater
verfasst von
Ziba Jahanbakhsh
Hossein Hosseinzadeh
Bakhshali Masoumi
Publikationsdatum
17.06.2021
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2021
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-021-05569-z

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