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Journal of Materials Science
Erschienen in: Journal of Materials Science 18/2018

18.06.2018 | Chemical routes to materials

Synthesis of hierarchical titanium silicalite-1 in the presence of polyquaternium-7 and its application in the hydroxylation of phenol

verfasst von: Zongzhuang Han, Yu Shen, Fumin Wang, Xubin Zhang

Erschienen in: Journal of Materials Science | Ausgabe 18/2018

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Abstract

Hierarchical titanium silicalite-1 (TS-1) without generated anatase TiO2 species was synthesized in the presence of polyquaternium-7 (M550) by one-step hydrothermal crystallization method and characterized by field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray fluorescence (XRF), Fourier transform infrared spectra, ultraviolet visible spectra, Raman spectroscopy and N2 adsorption–desorption measurements. The experimental results show that highly porous TS-1 crystals, with pores of ca. 2.6–4.9 nm diameter, are obtained under hydrothermal conditions by using polyquaternium-7 as the mesopore-directing agent. The polyquaternium-7 has a great influence on both the textural properties and the coordination of Ti species in the framework of TS-1. The catalytic properties and recyclability of the prepared mesoporous TS-1 for hydroxylation of phenol with H2O2 have been evaluated, and their activity has been compared with those of TS-1 with only micropores. The great catalytic activity, selectivity and stability of the hierarchical TS-1 as well as the cheap price and environmental-friendly nature of the used mesopore-directing agent allow to consider this hierarchical TS-1 as a promising catalyst for industry application.
Vorheriger Artikel Potassium-containing hydroxylated hydrotalcite as efficient catalyst for the transesterification of sunflower oil
Nächster Artikel High-efficiency self-repairing anticorrosion coatings with controlled assembly microcapsules

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Metadaten
Titel
Synthesis of hierarchical titanium silicalite-1 in the presence of polyquaternium-7 and its application in the hydroxylation of phenol
verfasst von
Zongzhuang Han
Yu Shen
Fumin Wang
Xubin Zhang
Publikationsdatum
18.06.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 18/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2582-z

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