Skip to main content
Erschienen in: Journal of Sol-Gel Science and Technology 1/2017

15.09.2016 | Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Synthesis of Tb-doped titanium dioxide nanostructures by sol–gel method for environmental photocatalysis applications

verfasst von: Firas J. Al-Maliki, Nora H. Al-Lamey

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this work, synthesis of Tb+3-doped TiO2 nanostructuresby sol–gel method for environmental photocatalysis applications is presented. Titanium (IV) isopropoxide and terbium chloride were used as precursors for titania and Tb+3 ions, respectively. The morphology, composition, particle size, surface area, and energy band gap of the prepared samples were characterized using scanning electron microscopy, Fourier-transform infrared spectroscopy, x-ray diffraction, ultraviolet-visible spectrophotometry and Brunauer-Emmett-Teller analysis. The effect of Tb+3 ions on the photocatalytic properties of TiO2 was investigated and the photocatalytic activity of the prepared samples was assessed by the photocatalytic decomposition of potassium permanganate in aqueous slurry.

Graphical Abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-016-4190-1/MediaObjects/10971_2016_4190_Figa_HTML.gif

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Fujishima A, Rao TN, Tryk DA (2000) Titanium dioxide photocatalysis. J Photochem Photobio. C 1(1):21 Fujishima A, Rao TN, Tryk DA (2000) Titanium dioxide photocatalysis. J Photochem Photobio. C 1(1):21
2.
Zurück zum Zitat Hoffmann MR, Martin ST, Choi W, Bahnemann DW (1995) Environmental applications of semiconductor photocatalysis. Chem Rev 95:69–96CrossRef Hoffmann MR, Martin ST, Choi W, Bahnemann DW (1995) Environmental applications of semiconductor photocatalysis. Chem Rev 95:69–96CrossRef
3.
Zurück zum Zitat Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38CrossRef Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38CrossRef
4.
Zurück zum Zitat Hisanga T, Harada K, Tanaka K (1990) Photocatalytic degradation of organochlorine compounds in suspended TiO2. J Photochem Photobiol A 54:113–118CrossRef Hisanga T, Harada K, Tanaka K (1990) Photocatalytic degradation of organochlorine compounds in suspended TiO2. J Photochem Photobiol A 54:113–118CrossRef
5.
Zurück zum Zitat Mahshid S, Askari M, Ghamsari MS, Afshar N, Lahuti. S (2009) Mixed-phase TiO2 nanoparticles preparation using sol–gel method. J Alloys and Comp 47:586–589CrossRef Mahshid S, Askari M, Ghamsari MS, Afshar N, Lahuti. S (2009) Mixed-phase TiO2 nanoparticles preparation using sol–gel method. J Alloys and Comp 47:586–589CrossRef
6.
Zurück zum Zitat Mashid S, SasaniGhamsari M, Afshar M, Lahuti S (2006) Synthesis of TiO2 nanoparticles by hydrolysis and peptization of tittaniumisopropoxide solution. Semicon Phys, Quantum Electron Optoelectron 9:65–68 Mashid S, SasaniGhamsari M, Afshar M, Lahuti S (2006) Synthesis of TiO2 nanoparticles by hydrolysis and peptization of tittaniumisopropoxide solution. Semicon Phys, Quantum Electron Optoelectron 9:65–68
7.
Zurück zum Zitat Jian S, Xudong W (2011) Growth of rutile titanium dioxide nanowires by pulsed chemical vapour deposition. Cryst Growth Des 11:949–954CrossRef Jian S, Xudong W (2011) Growth of rutile titanium dioxide nanowires by pulsed chemical vapour deposition. Cryst Growth Des 11:949–954CrossRef
8.
Zurück zum Zitat Oh J-K, Lee J-K, Kim SJ, Park K-W (2009) Synthesis of phase-and shape controlled TiO2 nanoparticles via hydrothermal process. J Indust Eng Chem 15:270–274CrossRef Oh J-K, Lee J-K, Kim SJ, Park K-W (2009) Synthesis of phase-and shape controlled TiO2 nanoparticles via hydrothermal process. J Indust Eng Chem 15:270–274CrossRef
9.
Zurück zum Zitat Kanna M, Wongnawa S (2008) Mixed amorphous and nanocrystalline TiO2 powders prepared by sol-gel method: characterization and photocatalytic study”. Mater Chem Phys 110:166–175CrossRef Kanna M, Wongnawa S (2008) Mixed amorphous and nanocrystalline TiO2 powders prepared by sol-gel method: characterization and photocatalytic study”. Mater Chem Phys 110:166–175CrossRef
10.
Zurück zum Zitat Seery MK, George R, Floris P, Pillai SC (2007) Silver doped titanium dioxide nanomaterials for enhanced visible light photocatalysis. J Photochem Photobio A 189:258–263CrossRef Seery MK, George R, Floris P, Pillai SC (2007) Silver doped titanium dioxide nanomaterials for enhanced visible light photocatalysis. J Photochem Photobio A 189:258–263CrossRef
11.
Zurück zum Zitat Nishikiori H, Hayashibe M, Fujii T (2013) Visible light-photocatalytic activity of sulfate-doped titanium dioxide prepared by the sol–gel method. Catalysts 3:363–377CrossRef Nishikiori H, Hayashibe M, Fujii T (2013) Visible light-photocatalytic activity of sulfate-doped titanium dioxide prepared by the sol–gel method. Catalysts 3:363–377CrossRef
12.
Zurück zum Zitat Mekprasart W, Khumtong T, Rattanarak J, Techitdheera W, Pecharapa W (2013) Effect of nitrogen doping on optical and photocatalytic properties of TiO2 thin film prepared by spin coating process”. Energy Procedia 34:746–750CrossRef Mekprasart W, Khumtong T, Rattanarak J, Techitdheera W, Pecharapa W (2013) Effect of nitrogen doping on optical and photocatalytic properties of TiO2 thin film prepared by spin coating process”. Energy Procedia 34:746–750CrossRef
13.
Zurück zum Zitat Zhao Z, Liu Q (2008) Effects of lanthanide doping on electronic structures and optical properties of anatase TiO2 from density functional theory calculation. J Phys D: Appl Phys 41:085417CrossRef Zhao Z, Liu Q (2008) Effects of lanthanide doping on electronic structures and optical properties of anatase TiO2 from density functional theory calculation. J Phys D: Appl Phys 41:085417CrossRef
14.
Zurück zum Zitat Hassan MS, Amna T, Yang O-B, Kim H-C, Khil M-S (2012) TiO2nanofibers doped with rare earth elements and their photocatalytic activity. Ceram Int 38:5925–5930CrossRef Hassan MS, Amna T, Yang O-B, Kim H-C, Khil M-S (2012) TiO2nanofibers doped with rare earth elements and their photocatalytic activity. Ceram Int 38:5925–5930CrossRef
15.
Zurück zum Zitat Zhang Y, Zhang H, Liu G, Battaglia V (2009) Synthesis and electro chemical studies of a layered spherical TiO2 through low temperature solvothermal method. Electro Acta 54:4079–4083CrossRef Zhang Y, Zhang H, Liu G, Battaglia V (2009) Synthesis and electro chemical studies of a layered spherical TiO2 through low temperature solvothermal method. Electro Acta 54:4079–4083CrossRef
16.
Zurück zum Zitat Gregg SJ, Sing KSW (1982) Adsorption, Surface Area and Porosity. Academic Press, London, p 42–84 Gregg SJ, Sing KSW (1982) Adsorption, Surface Area and Porosity. Academic Press, London, p 42–84
17.
Zurück zum Zitat Liang C-H, Hou M-F, Zhou S-G, Li F-B, Liu C-S, Liu T-X, Gao Y-X, Wang X-G, Lü J-L (2006) The effect of erbium on the adsorption and photodegradation of orange I in aqueous Er3+-TiO2 suspension. J Hazard Mater 138:471–478CrossRef Liang C-H, Hou M-F, Zhou S-G, Li F-B, Liu C-S, Liu T-X, Gao Y-X, Wang X-G, Lü J-L (2006) The effect of erbium on the adsorption and photodegradation of orange I in aqueous Er3+-TiO2 suspension. J Hazard Mater 138:471–478CrossRef
18.
Zurück zum Zitat Liang C-H, Liu C-S, Li F-B, Wu F (2009) The effect of praseodymium on the adsorption and photocatalytic degradation of azo dye in aqueous Pr3+-TiO2 suspension. Chem Eng J 147:219–225CrossRef Liang C-H, Liu C-S, Li F-B, Wu F (2009) The effect of praseodymium on the adsorption and photocatalytic degradation of azo dye in aqueous Pr3+-TiO2 suspension. Chem Eng J 147:219–225CrossRef
19.
Zurück zum Zitat Balachandran K, Venckatesh R, Sivaraj R (2010) Synthesis of nanoTiO2-SiO2 composite using sol-gel method: effect of size, surface morphology and thermal stability”. Int J Engng Sci Technol 2(8):3695–3700 Balachandran K, Venckatesh R, Sivaraj R (2010) Synthesis of nanoTiO2-SiO2 composite using sol-gel method: effect of size, surface morphology and thermal stability”. Int J Engng Sci Technol 2(8):3695–3700
20.
Zurück zum Zitat Artizzu F, Near-Infrared Luminescent Lanthanide Complexes of Quinolinol Ligands: Structure/Properties Relationship”, PhD thesis, Universitadegli Studi di Cagliari. Artizzu F, Near-Infrared Luminescent Lanthanide Complexes of Quinolinol Ligands: Structure/Properties Relationship”, PhD thesis, Universitadegli Studi di Cagliari.
22.
Zurück zum Zitat Chatterjee D, Dasgupta S (2005) Visible light induced photocatalytic degradation of organic pollutants. J Photochem Photobiol C 6:186–205CrossRef Chatterjee D, Dasgupta S (2005) Visible light induced photocatalytic degradation of organic pollutants. J Photochem Photobiol C 6:186–205CrossRef
23.
Zurück zum Zitat Yokosuka Y, Oki K, Nishikiori H, Tatsumi Y, Tanaka N, Fujii T (2009) Photocatalytic degradation of trichloroethylene using N-doped TiO2 prepared by a simple sol-gel process. Res Chem Intermed 35:43–53CrossRef Yokosuka Y, Oki K, Nishikiori H, Tatsumi Y, Tanaka N, Fujii T (2009) Photocatalytic degradation of trichloroethylene using N-doped TiO2 prepared by a simple sol-gel process. Res Chem Intermed 35:43–53CrossRef
24.
Zurück zum Zitat Nishikiori H, Fukasawa Y, Yokosuka Y, Fujii T (2011) Nitrogen doping into titanium dioxide by the sol-gel method using nitric acid. Res Chem Intermed 37:869–881CrossRef Nishikiori H, Fukasawa Y, Yokosuka Y, Fujii T (2011) Nitrogen doping into titanium dioxide by the sol-gel method using nitric acid. Res Chem Intermed 37:869–881CrossRef
25.
Zurück zum Zitat Zhao Y, Li C, Liu X, Gu F, Jiang H, Shao W, Zhang L, He Y (2007) Synthesis and optical properties of TiO2 nanoparticles. Mater Lett 61:79–83CrossRef Zhao Y, Li C, Liu X, Gu F, Jiang H, Shao W, Zhang L, He Y (2007) Synthesis and optical properties of TiO2 nanoparticles. Mater Lett 61:79–83CrossRef
26.
Zurück zum Zitat Maira AJ, Coronado JM, Augugliaro V, Yeung KL, Conesa JC, Soria J (2001) Fourier transform infrared study of the performance of nanostructured TiO2 particles for the photocatalytic oxidation of gaseous toluene. J Catalysis 202:413–420CrossRef Maira AJ, Coronado JM, Augugliaro V, Yeung KL, Conesa JC, Soria J (2001) Fourier transform infrared study of the performance of nanostructured TiO2 particles for the photocatalytic oxidation of gaseous toluene. J Catalysis 202:413–420CrossRef
Metadaten
Titel
Synthesis of Tb-doped titanium dioxide nanostructures by sol–gel method for environmental photocatalysis applications
verfasst von
Firas J. Al-Maliki
Nora H. Al-Lamey
Publikationsdatum
15.09.2016
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2017
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-016-4190-1

Weitere Artikel der Ausgabe 1/2017

Journal of Sol-Gel Science and Technology 1/2017 Zur Ausgabe

Original Paper: Industrial and technological applications of sol-gel and hybrid materials

Aqueous sol–gel synthesis and film deposition methods for the large-scale manufacture of coated steel with self-cleaning properties

Original Paper: Industrial and technological applications of sol-gel and hybrid materials

Physical–chemical explanation of fire-fighting efficiency of FHF (fast-hardening foam) based on structured silica particles

Original Paper: Sol-gel and hybrid materials for optical, photonic and optoelectronic applications

Sol-gel preparation and structural investigations of silico-phosphate glasses doped with Fe ions

Original Paper: Sol-gel and hybrid materials with surface modification for applications

Nanostructure-induced icephobic sol–gel coating for glass application

Original Paper: Nano- and macroporous materials (aerogels, xerogels, cryogels, etc.)

Hydrophobic modification of poly(aryl ether ketone ketone) aerogel via poly(dimethylsiloxane)

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.