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Journal of Sol-Gel Science and Technology

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25.10.2023 | Original Paper

Synthesis of zeolitic imidazolate framework-67 aerogel by anion exchange

verfasst von: Yexin Pan, Chong Ouyang, Muhammad A. Ehsan, Ziran Ye, Shunbo Li, Mingjia Zhi

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2024

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Abstract

This work reports the synthesis of a zeolitic imidazolate framework-67 (ZIF-67) aerogel by an anion exchange method. A conventional cobalt hydroxide wet gel is prepared as the precursor. Aging of this precursor in 2-methylimidazole/methanol solution at room temperature initiates an anion exchange process in which the OH- anions in the original gel backbone are gradually replaced by the methylimidazole ligand to form the ZIF-67 phase, while the monolithic gel bulk can be retained. After drying the wet gel in supercritical CO₂, the resulting aerogel contains the pristine crystalline ZIF-67 as the building blocks and inherits the features of microporosity from ZIF-67 itself and mesoporosity from the aerogel structure, resulting in a hieratical pore structure. With such coexisting micropores and mesopores, the ZIF-67 aerogel has shown faster dye adsorption kinetics compared to its powder counterpart, and the derived Co₃O₄ material also has better energy storage performance.

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Titel: Synthesis of zeolitic imidazolate framework-67 aerogel by anion exchange
verfasst von: Yexin Pan
Chong Ouyang
Muhammad A. Ehsan
Ziran Ye
Shunbo Li
Mingjia Zhi
Publikationsdatum: 25.10.2023
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 1/2024
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-023-06242-3

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