Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 8/2020

09.03.2020

Synthesis, single crystal structure, optical, and magnetic properties of mixed-alkali-metal terbium borate Rb2LiTbB2O6

verfasst von: Zhen Jia, Dongwei Wang, Qian Huang, Bo Xu, Xiuling Zhang, Mingjun Xia

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 8/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Mixed-alkali-metal terbium-based borate Rb2LiTbB2O6 crystals were obtained from the Rb2CO3–Li2CO3–Tb4O7–H3BO3 system, meanwhile the polycrystalline samples were synthesized by solid-state reaction. Rb2LiTbB2O6 features a complicated 3D network composed of BO3 and TbO8 anionic groups, spanned by Li+ and Rb+ cations. TbO8 dodecahedra connect BO3 triangles to build the zigzag-type \({}_{\infty }^{1} \left[ {{\text{TbO}}_{5} {\text{BO}}_{3} } \right]^{10 - }\) 1D chains, which further form \({}_{\infty }^{2} \left[ {{\text{TbB}}_{2} {\text{O}}_{6} } \right]^{3 - }\) 2D layers through linkage of another BO3 triangles. In addition, Rb2LiTbB2O6 exhibits a brightly green light emission and typical paramagnetic behavior, indicating that it can be a promising luminescence and magnetic-optical material.
Vorheriger Artikel Effect of silicone grease on electrical tree degradation of silicon rubber under AC electric field
Nächster Artikel The influence of the pyramidal texture uniformity and process optimization on monocrystalline silicon solar cells

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
C.T. Chen, B.C. Wu, A.D. Jiang et al., A new-type ultraviolet Shg crystal—beta-Bab2O4. Sci. Sin. B 28, 235–243 (1985)
2.
S.G. Zhao, P.F. Gong, L. Bai et al., Beryllium-free Li4Sr(BO3)(2) for deep-ultraviolet nonlinear optical applications. Nat. Commun. 5, 7 (2014)CrossRef
3.
M. Mutailipu, M. Zhang, B. Zhang et al., SrB5O7F3 functionalized with [B5O9F3](6-) chromophores: accelerating the rational design of deep-ultraviolet nonlinear optical materials. Angew. Chem. Int. Ed. Engl. 57, 6095–6099 (2018)CrossRef
4.
V.V. Atuchin, A.K. Subanakov, A.S. Aleksandrovsky et al., Structural and spectroscopic properties of new noncentrosymmetric self-activated borate Rb3EuB6O12 with B5O10 units. Mater. Des. 140, 488–494 (2018)CrossRef
5.
V.V. Atuchin, A.K. Subanakov, A.S. Aleksandrovsky et al., Exploration of structural, thermal, vibrational and spectroscopic properties of new noncentrosymmetric double borate Rb3NdB6O12. Adv. Powder. Technol. 28, 1309–1315 (2017)CrossRef
6.
M. Xia, X. Jiang, Z. Lin et al., “All-three-in-one”: a new bismuth–tellurium–borate Bi3TeBO9 exhibiting strong second harmonic generation response. J. Am. Chem. Soc. 138, 14190–14193 (2016)CrossRef
7.
Z. Jia, N. Zhang, Y. Ma et al., Top-seeded solution growth and optical properties of deep-UV birefringent crystal Ba2Ca(B3O6)2. Cryst. Growth. Des. 17, 558–562 (2017)CrossRef
8.
V.V. Atuchin, B.G. Bazarov, T.A. Gavrilova et al., Preparation and structural properties of nonlinear optical borates K2(1−x)Rb2xAl2B2O7, 0%3cx%3c0.75. J. Alloy Compd. 515, 119–122 (2012)CrossRef
9.
D. Wen, J. Shi, A novel narrow-line red emitting Na2Y2B2O7:Ce3+, Tb3+, Eu3+ phosphor with high efficiency activated by terbium chain for near-UV white LEDs. Dalton Trans. 42, 16621–16629 (2013)CrossRef
10.
W.U. Yicheng, C. Chen, Calculation of SHG coefficient of KB5 crystal based on ionic group theory. Acta Phys. Sin. 35, 1 (1986)
11.
C.T. Chen, Y.C. Wu, A.D. Jiang et al., New nonlinear-optical crystal—Lib3O5. J. Opt. Soc. Am. B 6, 616–621 (1989)CrossRef
12.
B.C. Wu, D.Y. Tang, N. Ye et al., Linear and nonlinear optical properties of the KBe2BO3F2 (KBBF) crystal. Opt Mater. 5, 105–109 (1996)CrossRef
13.
Z. Jia, M. Xia, Photoluminescence properties and preferable site occupancy of Ce3+ in apatite-like RbSr4(BO3)3 blue-emitting phosphors for white LEDs. New J Chem. 41, 12416–12421 (2017)CrossRef
14.
H.W. Huang, X.W. Li, J.J. Wang et al., Anionic group self-doping as a promising strategy: band-gap engineering and multi-functional applications of high-performance CO32-doped Bi2O2CO3. ACS Catal. 5, 4094–4103 (2015)CrossRef
15.
F.L. Jing, Y. Wu, P.Z. Fu, Growth of La2CaB10O19 single crystals by top-seeded solution growth technique. J. Cryst. Growth 292, 454–457 (2006)CrossRef
16.
A.A. Filimohov, N.I. Leonyuk, L.B. Meissner et al., Nonlinear optical properties of isomorphic family of crystals with yttrium-aluminium borate (YAB) structure. Krist. Tech. (East Germany) 9, 63–66 (1974)CrossRef
17.
R. Norrestam, M. Nygren, J.O. Bovin, Structural investigations of new calcium—rare earth (R) oxyborates with the composition Ca4RO(BO3)3. Cheminform 23, 737–743 (1992)
18.
M. Iwai, T. Kobayashi, H. Furuya et al., Crystal growth and optical characterization of rare-earth (Re) calcium oxyborate ReCa1O(BO3)(3) (Re=Y or Gd) as new nonlinear optical material. Jpn. J. Appl. Phys. Part. 2 36, L276–L279 (1997)CrossRef
19.
Y. Wu, J. Liu, P. Fu et al., A new lanthanum and calcium borate La2CaB10O19. Chem. Mater. 13, 753–755 (2001)CrossRef
20.
L.L. Cao, Y.Y. Chen, C.J. Lin et al., Preparation of TbBO3 powder and growth of TbBO3. Cryst. Adv. Mater. Res. 306–307, 416–422 (2011)CrossRef
21.
X. Sun, W. Gao, T. Yang et al., Sol-gel syntheses, luminescence, and energy transfer properties of α-GdB5O9:Ce(3+)/Tb(3+) phosphors. Dalton Trans. 44, 2276–2284 (2015)CrossRef
22.
R.K. Li, C.C. Wu, M.J. Xia, LiCaTb5(BO3)6: a new magneto-optical crystal promising as Faraday rotator. Opt. Mater. 62, 452–457 (2016)CrossRef
23.
P.Y. Chen, M.J. Xia, R.K. Li, Mixed alkali neodymium orthoborates: K9Li3Nd3(BO3)(7) and A(2)LiNd(BO3)(2) (A = Rb, Cs). Z. Anorg. Allg. Chem. 642, 424–430 (2016)CrossRef
24.
M.J. Xia, S.P. Shen, J. Lu et al., K3Li3Gd7(BO3)(9): a new gadolinium-rich orthoborate for cryogenic magnetic cooling. Chem-Eur. J. 24, 3147–3150 (2018)CrossRef
25.
G.M. Sheldrick, A short history of SHELX. Acta Crystallogr. A. 64, 112–122 (2008)CrossRef
26.
R.K. Choubey, P. Sen, S. Kar et al., Effect of codoping on crystalline perfection of Mg:Cr:LiNbO3 crystals. Solid State Commun. 140, 120–124 (2006)CrossRef
27.
S. Kar, R.K. Choubey, P. Sen et al., Studies on codoping behavior of Nd:Mg:LiNbO3 crystals. Phys. B 393, 37–42 (2007)CrossRef
28.
J. Zhao, L. Kang, Z. Lin et al., Ba1.31Sr3.69(BO3)3Cl: a new structure type in the M5(BO3)3Cl (M = bivalent cation) system. J. Alloy Compd. 699, 136–143 (2017)CrossRef
29.
Z. Jia, M. Xia, Congruent melt terbium-rich borate Na2Tb2B2O7: synthesis, crystal structure, optical and magnetic properties. J. Alloy Compd. 743, 537–542 (2018)CrossRef
30.
P. Kubelka, F. Munk, An article on optics of paint layers. Z. Tech. Phys. 12, 593–601 (1931)
31.
G.H. Dieke, H.M. Crosswhite, The spectra of the doubly and triply ionized rare earths. Appl. Opt. 2, 675–686 (1963)CrossRef
32.
D. Yuan, Z. Gao, Z. Jia et al., Growth, polarized Raman and fluorescence properties of TbCa4O(BO3)(3) single crystal. Opt. Mater. 42, 435–440 (2015)CrossRef
33.
L.J. Nugent, R.D. Baybarz, J.L. Burnett et al., Electron-transfer and F-D absorption-bands of some lanthanide and actinide complexes and standard (Ii-Iii) oxidation potential for each member of lanthanide and actinide series. J. Phys. Chem. 77, 1528–1539 (1973)CrossRef
34.
V.V. Atuchin, A.S. Aleksandrovsky, O.D. Chimitova et al., Synthesis and spectroscopic properties of multiferroic beta '-Tb-2(MoO4)(3). Opt. Mater. 36, 1631–1635 (2014)CrossRef
35.
G. Blasse, B.C. Grabmaier, Luminescent Materials, pp. X, 232, (Springer, Berlin, 1994).
36.
C.J. O'Connor, Progress in Inorganic Chemistry (Wiley, New York, 2007)
37.
Metadaten
Titel
Synthesis, single crystal structure, optical, and magnetic properties of mixed-alkali-metal terbium borate Rb2LiTbB2O6
verfasst von
Zhen Jia
Dongwei Wang
Qian Huang
Bo Xu
Xiuling Zhang
Mingjun Xia
Publikationsdatum
09.03.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 8/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-03184-2

Weitere Artikel der Ausgabe 8/2020

Journal of Materials Science: Materials in Electronics 8/2020 Zur Ausgabe

OriginalPaper

Novel nanocomposite decoy flare based on super-thermite and graphite particles

OriginalPaper

Investigations on microstructure, optical, magnetic, photocatalytic, and dielectric behaviours of pure and Co-doped ZnO NPs

OriginalPaper

Synthetic process and luminescence properties of Er3+, Yb3+ doping fluoride-based up-conversion phosphors

OriginalPaper

Phonon characteristics and intrinsic properties of single phase ZnWO4 ceramic

OriginalPaper

Synthesis of Se nanowires at room temperature using selenourea as Se source

OriginalPaper

A novel strategy for high color purity virescent Er3+-doped SrLaAlO4 nanocrystals for solid-state lighting applications

Neuer Inhalt

    Bildnachweise