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Journal of Materials Science

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12.03.2019 | Composites

Tailoring the mechanical and thermal properties of polylactic acid-based bionanocomposite films using halloysite nanotubes and polyethylene glycol by solvent casting process

verfasst von: Swati Sharma, Anshu Anjali Singh, Abhijit Majumdar, Bhupendra Singh Butola

Erschienen in: Journal of Materials Science | Ausgabe 12/2019

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Abstract

The inherent brittleness of PLA is a major challenge for its use in various applications. In this study, the effect of incorporation of halloysite nanotube (HNT) and polyethylene glycol (PEG) on mechanical and thermal properties of polylactic acid (PLA) was investigated. Various concentrations of PEG-600 and HNT were used with PLA, and films were prepared by solvent casting method. Mechanical, morphological, and thermal properties of these composite films were investigated to study the effect of PEG and HNT on the properties of PLA. Addition of PEG increased elongation at break, but reduced the tensile strength. However, addition of HNT in PLA/PEG compensated the fall in tensile strength. Addition of 3 wt% HNT into PLA blend involving 5 wt% PEG increased its elongation at break by 640% and tensile strength by 22%, while no significant change in Young’s modulus was observed. Dynamic mechanical thermal analysis (DMTA) showed significant improvement in storage modulus of PLA/PEG/HNT films in the rubbery region. Glass transition temperature decreased for the PEG-plasticized films, while the crystallinity improved as compared to neat PLA. Thermal stability of PLA/PEG/HNT films was higher than those of PLA, PLA/PEG, and PLA/HNT films. The degree of crystallinity obtained using X-ray diffraction analysis showed good agreement with that determined from differential scanning calorimetry (DSC).

Vorheriger Artikel Enhancement of the electrical and thermal properties of unidirectional carbon fibre/epoxy laminates through the addition of graphene oxide

Nächster Artikel Magnetic and tunable dielectric properties of DyCrO3 thin films

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Liu X, Dever M, Fair N, Benson RS (1997) Thermal and mechanical properties of poly(lactic acid) and poly(ethylene/butylene succinate) blends. J Environ Polym Degrad 5:225–235. https://doi.org/10.1007/BF02763666

Raquez J-M, Habibi Y, Murariu M, Dubois P (2013) Polylactide (PLA)-based nanocomposites. Prog Polym Sci 38:1504–1542. https://doi.org/10.1016/j.progpolymsci.2013.05.014 CrossRef

Shah BL, Selke SE, Walters MB, Heiden PA (2008) Effects of wood flour and chitosan on mechanical, chemical, and thermal properties of polylactide. Polym Compos 29:655–663. https://doi.org/10.1002/pc.20415 CrossRef

Auras R, Harte B, Selke S (2004) An overview of polylactides as packaging materials. Macromol Biosci 4:835–864. https://doi.org/10.1002/mabi.200400043 CrossRef

Hassouna F, Raquez JM, Addiego F et al (2011) New approach on the development of plasticized polylactide (PLA): grafting of poly(ethylene glycol) (PEG) via reactive extrusion. Eur Polym J 47:2134–2144. https://doi.org/10.1016/j.eurpolymj.2011.08.001 CrossRef

Kulinski Z, Piorkowska E, Gadzinowska K, Stasiak M (2006) Plasticization of poly(L-lactide) with poly(propylene glycol). Biomacromol 7:2128–2135. https://doi.org/10.1021/bm060089m CrossRef

Al-Mulla EAJ, Yunus WMZW, Ibrahim NAB, Rahman MZA (2010) Properties of epoxidized palm oil plasticized polytlactic acid. J Mater Sci 45:1942–1946. https://doi.org/10.1007/s10853-009-4185-1 CrossRef

Jacobsen S, Fritz HG (1999) Plasticizing polylactide?the effect of different plasticizers on the mechanical properties. Polym Eng Sci 39:1303–1310. https://doi.org/10.1002/pen.11517 CrossRef

Shi X, Zhang G, Phuong TV, Lazzeri A (2015) Synergistic effects of nucleating agents and plasticizers on the crystallization behavior of poly(lactic acid). Molecules 20:1579–1593. https://doi.org/10.3390/molecules20011579 CrossRef

10.

Mohapatra AK, Mohanty S, Nayak SK (2014) Effect of PEG on PLA/PEG blend and its nanocomposites: a study of thermo-mechanical and morphological characterization. Polym Compos 35:283–293. https://doi.org/10.1002/pc.22660 CrossRef

11.

Saura JJ, Gimenez E, Feijoo JL et al (2005) Development of amorphous PLA-montmorillonite nanocomposites. J Mater Sci 40:1785–1788. https://doi.org/10.1007/s10853-005-0694-8 CrossRef

12.

Frone AN, Panaitescu DM, Chiulan I et al (2016) The effect of cellulose nanofibers on the crystallinity and nanostructure of poly(lactic acid) composites. J Mater Sci 51:9771–9791. https://doi.org/10.1007/s10853-016-0212-1 CrossRef

13.

Zhou Y, Lei L, Yang B et al (2018) Preparation and characterization of polylactic acid (PLA) carbon nanotube nanocomposites. Polym Test 68:34–38. https://doi.org/10.1016/j.polymertesting.2018.03.044 CrossRef

14.

De Silva RT, Pasbakhsh P, Mae LS, Kit Y (2015) ZnO deposited/encapsulated halloysite-poly (lactic acid) (PLA) nanocomposites for high performance packaging films with improved mechanical and antimicrobial properties. Appl Clay Sci 111:10–20. https://doi.org/10.1016/j.clay.2015.03.024 CrossRef

15.

Zhang Y, Tang A, Yang H, Ouyang J (2016) Applications and interfaces of halloysite nanocomposites. Appl Clay Sci 119:8–17. https://doi.org/10.1016/j.clay.2015.06.034 CrossRef

16.

Liu M, Jia Z, Jia D, Zhou C (2014) Recent advance in research on halloysite nanotubes-polymer nanocomposite. Prog Polym Sci 39:1498–1525. https://doi.org/10.1016/j.progpolymsci.2014.04.004 CrossRef

17.

Bugatti V, Viscusi G, Naddeo C, Gorrasi G (2017) Nanocomposites based on PCL and halloysite nanotubes filled with lysozyme: effect of draw ratio on the physical properties and release analysis. Nanomater (Basel, Switzerland) 7:213. https://doi.org/10.3390/nano7080213 CrossRef

18.

Gorrasi G, Senatore V, Vigliotta G et al (2014) PET-halloysite nanotubes composites for packaging application: preparation, characterization and analysis of physical properties. Eur Polym J 61:145–156. https://doi.org/10.1016/j.eurpolymj.2014.10.004 CrossRef

19.

Dong Y, Marshall J, Haroosh HJ et al (2015) Polylactic acid (PLA)/halloysite nanotube (HNT) composite mats: influence of HNT content and modification. Compos PART A 76:28–36. https://doi.org/10.1016/j.compositesa.2015.05.011 CrossRef

20.

Esma C, Erpek Y, Ozkoc G, Yilmazer U (2016) Effects of halloysite nanotubes on the performance of plasticized poly(lactic acid)-based composites. Polym Compos 37:3134–3148. https://doi.org/10.1002/pc.23511 CrossRef

21.

Meng X, Nguyen NA, Tekinalp H et al (2017) Supertough PLA-silane nanohybrids by in situ condensation and grafting. ACS Sustain Chem Eng 6:1289–1298. https://doi.org/10.1021/acssuschemeng.7b03650 CrossRef

22.

Herrera N, Mathew AP, Oksman K (2015) Plasticized polylactic acid/cellulose nanocomposites prepared using melt-extrusion and liquid feeding: mechanical, thermal and optical properties. Compos Sci Technol 106:149–155. https://doi.org/10.1016/j.compscitech.2014.11.012 CrossRef

23.

Suryanegara L, Nakagaito AN, Yano H (2009) The effect of crystallization of PLA on the thermal and mechanical properties of microfibrillated cellulose-reinforced PLA composites. Compos Sci Technol 69:1187–1192. https://doi.org/10.1016/j.compscitech.2009.02.022 CrossRef

24.

Majhi SK, Nayak SK, Mohanty S, Unnikrishnan L (2010) Mechanical and fracture behavior of banana fiber reinforced polylactic acid biocomposites. Int J Plast Technol 14:57–75. https://doi.org/10.1007/s12588-010-0010-6 CrossRef

25.

Pillin I, Montrelay N, Grohens Y (2006) Thermo-mechanical characterization of plasticized PLA: Is the miscibility the only significant factor? Polymer 47:4676–4682. https://doi.org/10.1016/j.polymer.2006.04.013 CrossRef

26.

Ozdemir E, Hacaloglu J (2017) Characterizations of PLA-PEG blends involving organically modified montmorillonite. J Anal Appl Pyrolysis 127:343–349. https://doi.org/10.1016/J.JAAP.2017.07.016 CrossRef

27.

Imsombut T, Srisa-Ard M, Baimark Y (2017) Synthesis of star-shaped ε-caprolactone oligomers for use as plasticizers of poly(L-lactide) bioplastic films. Orient J Chem 33:654–663. https://doi.org/10.13005/ojc/330213 CrossRef

28.

Bijarimi M, Ahmad S, Rasid R (2013) Mechanical, thermal and morphological properties of poly(lactic acid)/natural rubber nanocomposites. J Reinf Plast Compos 32:1656–1667. https://doi.org/10.1177/0731684413496487 CrossRef

29.

Wang B, Hina K, Zou H et al (2018) Thermal, crystallization, mechanical and decomposition properties of poly(lactic acid) plasticized with poly(ethylene glycol). J Vinyl Add Tech 24:E154–E163. https://doi.org/10.1002/vnl.21619 CrossRef

30.

Salas-Papayanopolos H, Morales-Cepeda AB, Sanchez S et al (2017) Synergistic effect of silver nanoparticle content on the optical and thermo-mechanical properties of poly(l-lactic acid)/glycerol triacetate blends. Polym Bull 74:4799–4814. https://doi.org/10.1007/s00289-017-1992-4 CrossRef

31.

Singh AA, Geng S, Herrera N, Oksman K (2018) Aligned plasticized polylactic acid cellulose nanocomposite tapes: effect of drawing conditions. Compos Part A Appl Sci Manuf 104:101–107. https://doi.org/10.1016/j.compositesa.2017.10.019 CrossRef

32.

Mohapatra AK, Mohanty S, Nayak SK (2014) Dynamic mechanical and thermal properties of polylactide-layered silicate nanocomposites. J Thermoplast Compos Mater 27:699–716. https://doi.org/10.1177/0892705712454446 CrossRef

33.

Giita Silverajah VS, Ibrahim NA, Yunus WMZW et al (2012) A comparative study on the mechanical, thermal and morphological characterization of poly(lactic acid)/epoxidized palm oil blend. Int J Mol Sci 13:5878–5898. https://doi.org/10.3390/ijms13055878 CrossRef

34.

Ahmed J, Varshney SK, Auras R, Hwang SW (2010) Thermal and rheological properties of L-polylactide/polyethylene glycol/silicate nanocomposites films. J Food Sci 75:N97–N108. https://doi.org/10.1111/j.1750-3841.2010.01809.x CrossRef

35.

Rao YQ, Pochan JM (2007) Mechanics of polymer-clay nanocomposites. Macromolecules 40:290–296. https://doi.org/10.1021/ma061445w CrossRef

36.

Li F-J, Zhang S-D, Liang J-Z, Wang J-Z (2015) Effect of polyethylene glycol on the crystallization and impact properties of polylactide-based blends. Polym Adv Technol 26:465–475. https://doi.org/10.1002/pat.3475 CrossRef

37.

Therias S, Murariu M, Dubois P (2017) Bionanocomposites based on PLA and halloysite nanotubes: from key properties to photooxidative degradation. Polym Degrad Stab 145:60–69. https://doi.org/10.1016/J.POLYMDEGRADSTAB.2017.06.008 CrossRef

38.

Liu M, Zhang Y, Zhou C (2013) Nanocomposites of halloysite and polylactide. Appl Clay Sci 75:52–59. https://doi.org/10.1016/j.clay.2013.02.019 CrossRef

39.

Lai S-M, Wu S-H, Lin G-G, Don T-M (2014) Macromolecular Nanotechnology Unusual mechanical properties of melt-blended poly(lactic acid) (PLA)/clay nanocomposites. Eur Polym J 52:193–206. https://doi.org/10.1016/j.eurpolymj.2013.12.012 CrossRef

40.

Cai N, Dai Q, Wang Z et al (2015) Toughening of electrospun poly(l-lactic acid) nanofiber scaffolds with unidirectionally aligned halloysite nanotubes. J Mater Sci 50:1435–1445. https://doi.org/10.1007/s10853-014-8703-4 CrossRef

41.

Russo V, Tammaro L, Di Marcantonio L et al (2016) Amniotic epithelial stem cell biocompatibility for electrospun poly(lactide-co-glycolide), poly(ε-caprolactone), poly(lactic acid) scaffolds. Mater Sci Eng C 69:321–329. https://doi.org/10.1016/J.MSEC.2016.06.092 CrossRef

Titel: Tailoring the mechanical and thermal properties of polylactic acid-based bionanocomposite films using halloysite nanotubes and polyethylene glycol by solvent casting process
verfasst von: Swati Sharma
Anshu Anjali Singh
Abhijit Majumdar
Bhupendra Singh Butola
Publikationsdatum: 12.03.2019
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 12/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-019-03521-9

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