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Cellulose

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03.04.2017 | Original Paper

The effect of pre-treatment on the production of lignocellulosic nanofibers and their application as a reinforcing agent in paper

verfasst von: Eduardo Espinosa, Juan Domínguez-Robles, Rafael Sánchez, Quim Tarrés, Alejandro Rodríguez

Erschienen in: Cellulose | Ausgabe 6/2017

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Abstract

In this work, three different lignocellulosic nanofibers (LCNF) were produced from unbleached wheat straw soda pulp by using different pre-treatments: mechanical, enzymatic, and TEMPO [(2,2,6,6-tetramethylpiperidin-1-yl) oxy radical]-mediated oxidation processes. The different LCNF were characterized and studied by their chemical composition (FTIR), crystal structure (XRD), thermal degradation behaviour (TGA), morphological (TEM), and their reinforcement effect on papermaking slurries. The pre-treatment used to obtain LCNF showed significant differences on the nanofibrillation yield (37–95%), carboxyl content (74–362 µmol g⁻¹), cationic demand (428–1116 µeq g⁻¹), and on its dimensions (7–14 nm), thermal stability, and structure. Regarding application as reinforcement on papermaking slurries, LCNF obtained by TEMPO-mediated oxidation produced a greater reinforcing effect than the other LCNF. Nevertheless, the obtained LCNF from mechanical process produce a similar increase in the mechanical properties of the papersheets due to its high length, compared with LCNF obtained by TEMPO-mediated oxidation.

Vorheriger Artikel In situ synthesis of MnO2-loaded biocomposite based on microcrystalline cellulose for Pb2+ removal from wastewater

Nächster Artikel Effect of softener and wetting agent on improving the flammability, comfort, and mechanical properties of flame-retardant finished cotton fabric

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Titel: The effect of pre-treatment on the production of lignocellulosic nanofibers and their application as a reinforcing agent in paper
verfasst von: Eduardo Espinosa
Juan Domínguez-Robles
Rafael Sánchez
Quim Tarrés
Alejandro Rodríguez
Publikationsdatum: 03.04.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 6/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1281-2

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