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Erschienen in: Polymer Science, Series D 3/2020

01.07.2020

The Effect of the Phase Structure of Silane-Modified Ethylene Copolymers on Their Surface Energy and Adhesion Properties

verfasst von: S. N. Rusanova, S. Yu. Sof’ina, N. E. Temnikova, V. K. Gerasimov, A. E. Chalykh, I. A. Starostina, Zh. V. Mezhevich, O. V. Stoyanov

Erschienen in: Polymer Science, Series D | Ausgabe 3/2020

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Abstract

Systems consisting of ethylene–vinyl acetate copolymers and (aminoalkoxy)silanes are studied. The diffusion and mutual solubility of their components are investigated, and phase diagrams covering a broad range of composition and temperatures are constructed. We find that the near-surface layers of the modified copolymers are enriched with the organosilicon component. The effects that the phase structure of considered adhesives has on the energetic properties and adhesion strength for different types of substrates are identified.

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Literatur
1.
Zurück zum Zitat I. V. Semenova, G. M. Florianovich, and A. V. Khoroshilov, Corrosion and Corrosion Protection (Fizmatlit, Moscow, 2010) [in Russian]. I. V. Semenova, G. M. Florianovich, and A. V. Khoroshilov, Corrosion and Corrosion Protection (Fizmatlit, Moscow, 2010) [in Russian].
2.
Zurück zum Zitat I. V. Strizhevskii, A. D. Belogolovskii, V. I. Dmitriev, et al., Protection of Underground Metal Structures from Corrosion (Stroiizdat, Moscow, 1990) [in Russian]. I. V. Strizhevskii, A. D. Belogolovskii, V. I. Dmitriev, et al., Protection of Underground Metal Structures from Corrosion (Stroiizdat, Moscow, 1990) [in Russian].
3.
Zurück zum Zitat A. Popelka, I. Novak, and I. Krupa, “Polyolefin adhesion modifications,” in Polyolefin Compounds and Materials. Fundamentals and Industrial Applications (Springer International Publishing, 2016), pp. 201–230. A. Popelka, I. Novak, and I. Krupa, “Polyolefin adhesion modifications,” in Polyolefin Compounds and Materials. Fundamentals and Industrial Applications (Springer International Publishing, 2016), pp. 201–230.
4.
Zurück zum Zitat A. A. Ioffe, S. G. Niz’ev, A. I. Ekimov, E. V. Kalugina, and M. L. Katsevman, “Russia-made materials for factory polyethylene insulation of steel pipes,” Polim. Truby, No. 2 (2015). A. A. Ioffe, S. G. Niz’ev, A. I. Ekimov, E. V. Kalugina, and M. L. Katsevman, “Russia-made materials for factory polyethylene insulation of steel pipes,” Polim. Truby, No. 2 (2015).
5.
Zurück zum Zitat S. V. Shtepa and V. K. Skubin, “Innovative external coating Metalen PE-21 for pipe insulation,” Gazov. Prom-st., Suppl. 2, 96–98 (2015). S. V. Shtepa and V. K. Skubin, “Innovative external coating Metalen PE-21 for pipe insulation,” Gazov. Prom-st., Suppl. 2, 96–98 (2015).
6.
Zurück zum Zitat R. V. Kurbanova, Yu. N. Kakhramanly, N. T. Kakhramanov, and V. S. Osipchik, “Finished polymer nanocomposites based on low density polyethylene and kaolin,” Plast. Massy, Nos. 11–12, 40–43 (2017). R. V. Kurbanova, Yu. N. Kakhramanly, N. T. Kakhramanov, and V. S. Osipchik, “Finished polymer nanocomposites based on low density polyethylene and kaolin,” Plast. Massy, Nos. 11–12, 40–43 (2017).
7.
Zurück zum Zitat J. J. Chruściel and E. Lésniak, “Modification of epoxy resins with functional silanes, polysiloxanes, silsesquioxanes, silica and silicates,” Prog. Polym. Sci. 41, 67–121 (2015).CrossRef J. J. Chruściel and E. Lésniak, “Modification of epoxy resins with functional silanes, polysiloxanes, silsesquioxanes, silica and silicates,” Prog. Polym. Sci. 41, 67–121 (2015).CrossRef
8.
Zurück zum Zitat W. Kaewsakul, K. Sahakaro, W. K. Dierkes, and J. W. M. Noordermeer, “Mechanistic aspects of silane coupling agents with different functionalities on reinforcement of silica-filled natural rubber compounds,” Polym. Eng. Sci. 55 (4), 836–842 (2015).CrossRef W. Kaewsakul, K. Sahakaro, W. K. Dierkes, and J. W. M. Noordermeer, “Mechanistic aspects of silane coupling agents with different functionalities on reinforcement of silica-filled natural rubber compounds,” Polym. Eng. Sci. 55 (4), 836–842 (2015).CrossRef
9.
Zurück zum Zitat R. I. Lyga, V. M. Mikhal’chuk, D. V. Gurtovoi, A. A. Atamanova, and M. V. Saifutdinova, “Features of the formation and properties of epoxy-silica composites of amine curing,” Vestn. Novgorod. Gos. Univ., No. 6, 81–85 (2015). R. I. Lyga, V. M. Mikhal’chuk, D. V. Gurtovoi, A. A. Atamanova, and M. V. Saifutdinova, “Features of the formation and properties of epoxy-silica composites of amine curing,” Vestn. Novgorod. Gos. Univ., No. 6, 81–85 (2015).
10.
Zurück zum Zitat A. N. Ekimenko, “Prospects for the use of organosilanes in thermoplastic composites with vegetative filler,” Plast. Massy, No. 1, 28–33 (2018). A. N. Ekimenko, “Prospects for the use of organosilanes in thermoplastic composites with vegetative filler,” Plast. Massy, No. 1, 28–33 (2018).
11.
Zurück zum Zitat O. S. Aikasheva, O. E. Babkin, L. A. Babkina, A. G. Esenovskii, and S. V. Proskuryakov, “A method of increasing the adhesive strength of UV-curing coatings,” Lakokras. Mater. Ikh Primen., No. 12, 54–57 (2011). O. S. Aikasheva, O. E. Babkin, L. A. Babkina, A. G. Esenovskii, and S. V. Proskuryakov, “A method of increasing the adhesive strength of UV-curing coatings,” Lakokras. Mater. Ikh Primen., No. 12, 54–57 (2011).
12.
Zurück zum Zitat Yu. N. Khakimullin, V. S. Minkin, and R. Ya. Deberdeev, Sealants Based on Polysulfide Oligomers: Synthesis, Properties, and Application (Nauka, Moscow, 2007) [in Russian]. Yu. N. Khakimullin, V. S. Minkin, and R. Ya. Deberdeev, Sealants Based on Polysulfide Oligomers: Synthesis, Properties, and Application (Nauka, Moscow, 2007) [in Russian].
13.
Zurück zum Zitat A. F. Nabiullin, V. S. Osipchik, A. I. Kochetkov, A. F. Zhukov, and I. S. Kryl’tsov, “Development of an epoxy-silicone binder for fiberglass production,” Usp. Khim. Khim. Tekhnol. 32 (6), 100–102 (2018). A. F. Nabiullin, V. S. Osipchik, A. I. Kochetkov, A. F. Zhukov, and I. S. Kryl’tsov, “Development of an epoxy-silicone binder for fiberglass production,” Usp. Khim. Khim. Tekhnol. 32 (6), 100–102 (2018).
14.
Zurück zum Zitat D. Chernyshov, “Organosilicon modifiers for producing polyurethane coatings with improved properties,” Lakokras. Mater. Ikh Primen., Nos. 1–2, 20–24 (2017). D. Chernyshov, “Organosilicon modifiers for producing polyurethane coatings with improved properties,” Lakokras. Mater. Ikh Primen., Nos. 1–2, 20–24 (2017).
15.
Zurück zum Zitat M. S. Lisanevich, R. Yu. Galimzyanova, S. N. Rusanova, Yu. N. Khakimullin, and O. V. Stoyanov, “Hot-melt sealants of curable type based on butyl rubber and ethylene–vinyl acetate copolymer,” Polym. Sci., Ser. D 11, 359–362 (2018). M. S. Lisanevich, R. Yu. Galimzyanova, S. N. Rusanova, Yu. N. Khakimullin, and O. V. Stoyanov, “Hot-melt sealants of curable type based on butyl rubber and ethylene–vinyl acetate copolymer,” Polym. Sci., Ser. D 11, 359–362 (2018).
16.
Zurück zum Zitat S. Mitachi, A. Ito, and K. Kimura, “Highly moisture-resistant, silane-modified, cyanogen-free optical adhesives, and their reliability,” J. Mater. Eng. Perform. 23 (5), 1544–1550 (2014).CrossRef S. Mitachi, A. Ito, and K. Kimura, “Highly moisture-resistant, silane-modified, cyanogen-free optical adhesives, and their reliability,” J. Mater. Eng. Perform. 23 (5), 1544–1550 (2014).CrossRef
17.
Zurück zum Zitat I. A. Petlin, A. G. Minsafina, A. I. Kurkin, and Yu. N. Khakimullin, “The effect of the ratio of components in the synthesis of stp-polymer on the properties of sealants based on it,” Vestn. Kazan. Tekhnol. Univ. 18 (17), 11–13 (2015). I. A. Petlin, A. G. Minsafina, A. I. Kurkin, and Yu. N. Khakimullin, “The effect of the ratio of components in the synthesis of stp-polymer on the properties of sealants based on it,” Vestn. Kazan. Tekhnol. Univ. 18 (17), 11–13 (2015).
18.
Zurück zum Zitat V. V. Safonov, Structure, Properties, and Application of Organosilicon Compounds (Ross. Gos. Univ. im. A.N. Kosygina, Moscow, 2018) [in Russian]. V. V. Safonov, Structure, Properties, and Application of Organosilicon Compounds (Ross. Gos. Univ. im. A.N. Kosygina, Moscow, 2018) [in Russian].
19.
Zurück zum Zitat R. M. Khuzakhanov, Doctoral Dissertation in Engineering (Kazan, 2013). R. M. Khuzakhanov, Doctoral Dissertation in Engineering (Kazan, 2013).
20.
Zurück zum Zitat N. E. Temnikova, O. V. Stoyanov, A. E. Chalykh, V. K. Gerasimov, and S. N. Rusanova, “The influence of the phase structure of polymer systems on their adhesive characteristics,” Vestn. Kazan. Tekhnol. Univ. 17 (14), 317–320 (2014). N. E. Temnikova, O. V. Stoyanov, A. E. Chalykh, V. K. Gerasimov, and S. N. Rusanova, “The influence of the phase structure of polymer systems on their adhesive characteristics,” Vestn. Kazan. Tekhnol. Univ. 17 (14), 317–320 (2014).
21.
Zurück zum Zitat N. E. Temnikova, S. N. Rusanova, S. Yu. Sof’ina, O. V. Stoyanov, R. M. Garipov, A. E. Chalykh, and V. K. Gerasimov, “The effect of aminoalkoxy and glycidoxyalkoxy silanes on adhesion characteristics of double and triple copolymers of ethylene,” Polym. Sci., Ser. D 7 (3), 184–187 (2014). N. E. Temnikova, S. N. Rusanova, S. Yu. Sof’ina, O. V. Stoyanov, R. M. Garipov, A. E. Chalykh, and V. K. Gerasimov, “The effect of aminoalkoxy and glycidoxyalkoxy silanes on adhesion characteristics of double and triple copolymers of ethylene,” Polym. Sci., Ser. D 7 (3), 184–187 (2014).
22.
Zurück zum Zitat A. A. Shcherbina, M. V. Vokal’, and A. E. Chalykh, “On the mechanism of translational mobility of macromolecules,” Russ. Chem. Bull. 64, 791–793 (2015).CrossRef A. A. Shcherbina, M. V. Vokal’, and A. E. Chalykh, “On the mechanism of translational mobility of macromolecules,” Russ. Chem. Bull. 64, 791–793 (2015).CrossRef
23.
Zurück zum Zitat A. E. Chalykh, A. I. Zagaitov, V. V. Gromov, and D. N. Korotchenko, Optical Diffuser ODA-2 (Inst. Fiz. Khim. Ross. Akad. Nauk, Moscow, 1996) [in Russian]. A. E. Chalykh, A. I. Zagaitov, V. V. Gromov, and D. N. Korotchenko, Optical Diffuser ODA-2 (Inst. Fiz. Khim. Ross. Akad. Nauk, Moscow, 1996) [in Russian].
24.
Zurück zum Zitat G. Schimmel, Elektronenmikroskopische Methodik (Springer, Berlin, 1969; Mir, Moscow, 1972). G. Schimmel, Elektronenmikroskopische Methodik (Springer, Berlin, 1969; Mir, Moscow, 1972).
25.
Zurück zum Zitat E. Kraus, B. Baudrit, P. Heidemeyer, M. Bastian, D. A. Nguen, I. Starostina, and O. Stoyanov, “Perspektiven der Saure-Base-Methode zur Untersuchung der Oberflacheneigenschaften von Polymeren,” Chem. Ing. Tech. 87 (10), 1334–1341 (2015).CrossRef E. Kraus, B. Baudrit, P. Heidemeyer, M. Bastian, D. A. Nguen, I. Starostina, and O. Stoyanov, “Perspektiven der Saure-Base-Methode zur Untersuchung der Oberflacheneigenschaften von Polymeren,” Chem. Ing. Tech. 87 (10), 1334–1341 (2015).CrossRef
26.
Zurück zum Zitat I. Starostina, O. Stoyanov, and R. Deberdeev, Polymer Surfaces and Interfaces. Acid-Base Interactions and Adhesion in Polymer-Metal Systems (Apple Academic Press Inc., Toronto, 2015). I. Starostina, O. Stoyanov, and R. Deberdeev, Polymer Surfaces and Interfaces. Acid-Base Interactions and Adhesion in Polymer-Metal Systems (Apple Academic Press Inc., Toronto, 2015).
27.
Zurück zum Zitat N. E. Temnikova, S. N. Rusanova, Y. S. Tafeeva, S. Y. Sof’ina, and O. V. Stoyanov, “The effect of an amino-containing modifier on properties of ethylene copolymers,” Polym. Sci., Ser. D 6 (1), 19–25 (2013). N. E. Temnikova, S. N. Rusanova, Y. S. Tafeeva, S. Y. Sof’ina, and O. V. Stoyanov, “The effect of an amino-containing modifier on properties of ethylene copolymers,” Polym. Sci., Ser. D 6 (1), 19–25 (2013).
Metadaten
Titel
The Effect of the Phase Structure of Silane-Modified Ethylene Copolymers on Their Surface Energy and Adhesion Properties
verfasst von
S. N. Rusanova
S. Yu. Sof’ina
N. E. Temnikova
V. K. Gerasimov
A. E. Chalykh
I. A. Starostina
Zh. V. Mezhevich
O. V. Stoyanov
Publikationsdatum
01.07.2020
Verlag
Pleiades Publishing
Erschienen in
Polymer Science, Series D / Ausgabe 3/2020
Print ISSN: 1995-4212
Elektronische ISSN: 1995-4220
DOI
https://doi.org/10.1134/S1995421220030156

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