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Erschienen in: Optical and Quantum Electronics 5/2024

01.05.2024

The impact of TiO2 on physical, optical characteristics and shielding qualities against γ-ray features of titanium bismo-borate glasses

verfasst von: Norah A. M. Alsaif, Nada Alfryyan, Hanan Al-Ghamdi, Adel M. El-Refaey, R. A. Elsad, M. S. Shams, Y. S. Rammah, M. S. Sadeq, Shaaban M. Shaaban, Islam M. Nabil

Erschienen in: Optical and Quantum Electronics | Ausgabe 5/2024

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Abstract

In this study, the role of TiO2 on the physica, and optical properties as well as the γ-ray protection features of a set of six glass samples with the chemical formula (65-X)B2O3–15BaO–5Bi2O3–15ZnO–XTiO2, where X = 0–10 mol% in the step of 2% have been investigated. The density (ρ) increased gradually from 3.70 to 3.93 g/cm3 and the molar volume (Vm) reduced from 27.71 to 26.72 cm3/mol as the TiO2 content increased from 0 to 10 mol%. By the inclusion of TiO2 in the glass networks, some absorption bands in the ultraviolet and visible regions are formed. Values of the indirect optical band gaps (Eg) were 2.550, 2.510, 2.470, 2.370, 2.270, and 2.180 eV for Ti-0.0, Ti-2.0, Ti-4.0, Ti-6.0, Ti-8.0, and Ti-10.0 glasses, respectively. The linear refractive index (n0) calculated values varied from 2.515 to 2.631. The linear-attenuation coefficient (\(\upmu )\) followed the order: Ti-0.0 < Ti-2.0 < Ti-4.0 < Ti-6.0 < Ti-8.0 < Ti-10.0. The sample coded as Ti-10.0 glass sample (highest content of TiO2) has the lowest half (HVL) and tenth (TVL) value layer. Within the investigated energy range of within the range: 51.590–19.480, 50.676–19.722, 50.696–19.833, 50.271–20.012, 49.860–20.193, and 49.460–20.376 for the prepared samples Ti-0.0, Ti-2.0, Ti-4.0, Ti-6.0, Ti-8.0, and Ti-10.0 glasses, respectively. Results confirmed that the suggested titanium bismo-borate glasses can be used in the optical field and as alternative materials for radiation shielding applications.

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Metadaten
Titel
The impact of TiO2 on physical, optical characteristics and shielding qualities against γ-ray features of titanium bismo-borate glasses
verfasst von
Norah A. M. Alsaif
Nada Alfryyan
Hanan Al-Ghamdi
Adel M. El-Refaey
R. A. Elsad
M. S. Shams
Y. S. Rammah
M. S. Sadeq
Shaaban M. Shaaban
Islam M. Nabil
Publikationsdatum
01.05.2024
Verlag
Springer US
Erschienen in
Optical and Quantum Electronics / Ausgabe 5/2024
Print ISSN: 0306-8919
Elektronische ISSN: 1572-817X
DOI
https://doi.org/10.1007/s11082-024-06702-2

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