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Journal of Coatings Technology and Research
Erschienen in: Journal of Coatings Technology and Research 6/2021

10.09.2021

The influence of methacrylic acid and urethane methacrylate on the film properties of hybrid urethane–acrylic latexes

verfasst von: Anisa Cobaj, Mark D. Soucek

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 6/2021

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Abstract

A non-isocyanate pathway was used to synthesize a urethane methacrylate monomer, 2-((methylcarbamoyl)oxy)ethyl methacrylate (MEM) and methacrylic acid (MAA). The MEM and MAA mixture was copolymerized with MMA and BA in a semicontinuous monomer-starved process to prepare latexes via emulsion polymerization. Varying amounts of MEM and MAA monomers were introduced to the latex, and their effect on the thermal properties, film formation, viscoelastic, mechanical and morphological properties was examined. The upper limit functionality concentration was evaluated based on the latex stability. Incorporation of MEM and MAA in latexes enhanced film formation properties displayed by lowering MFFT. MEM and MAA functionalized latexes exhibited enhanced Young’s modulus, tensile strength and hardness compared to the control latex without any MEM and MAA.
Vorheriger Artikel Effect of humidity on curing of alkoxysilane-functionalized alkyd coatings
Nächster Artikel Polymerizable allyl anionic and nonionic emulsifier: synthesis and properties of its emulsion for architectural coating

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Metadaten
Titel
The influence of methacrylic acid and urethane methacrylate on the film properties of hybrid urethane–acrylic latexes
verfasst von
Anisa Cobaj
Mark D. Soucek
Publikationsdatum
10.09.2021
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 6/2021
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-021-00497-7

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