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Journal of Nanoparticle Research
Erschienen in: Journal of Nanoparticle Research 8/2014

01.08.2014 | Research Paper

The preparation of nickel nanoparticles through a novel solid-state intramolecular reaction of polynuclear nickel(II) complex

verfasst von: Seyed Abolghasem Kahani, Massumeh Khedmati

Erschienen in: Journal of Nanoparticle Research | Ausgabe 8/2014

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Abstract

A novel solid-state reaction involving [Ni6(N2H4)6(SO4)4(OH)2(H2O)8](SO4)(H2O)10 has been used to prepare nickel nanoparticles. The reaction of [Ni6(N2H4)6(SO4)4(OH)2(H2O)8](SO4)(H2O)10 via NaOH, KOH, and/or Na2CO3 as a reactant was carried out in the solid state. The complex undergoes an intramolecular two-electron oxidation–reduction reaction at room temperature, producing metallic nickel nanoparticles (Ni1, Ni2 and Ni3). The aforementioned complex contains nickel(II) that is an oxidizing agent and also hydrazine ligand as a reducing agent. Other products produced include sodium azide and ammonia gas. The nickel metal nanoparticles were characterized using X-ray powder diffraction, scanning electron microscopy, and vibrating sample magnetometer. The synthesized nickel nanoparticles have similar morphologies; however, their particle size distributions are different.
Vorheriger Artikel Biofunctionalization of silica-coated magnetic particles mediated by a peptide
Nächster Artikel Controlled synthesis and optical properties of Cu/C core/shell nanoparticles

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Metadaten
Titel
The preparation of nickel nanoparticles through a novel solid-state intramolecular reaction of polynuclear nickel(II) complex
verfasst von
Seyed Abolghasem Kahani
Massumeh Khedmati
Publikationsdatum
01.08.2014
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 8/2014
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-014-2544-6

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