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Erschienen in: Colloid and Polymer Science 7/2018

27.05.2018 | Original Contribution

The properties of FeOOH precipitates formed in CTAB-rich FeCl3 solutions at various pH and ethanol contents

verfasst von: Wen Wei, Haibing Cong, Huixin Xiong

Erschienen in: Colloid and Polymer Science | Ausgabe 7/2018

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Abstract

Iron oxyhydroxides as an important adsorbent, catalyzer, or electrode material can be commonly prepared in surfactant-rich ferric solutions. Herein in this work, we investigated influences of pH and the ethanol/water volume ratio on iron precipitates produced in FeCl3 solutions with cetyltrimethyl ammonium bromide (CTAB) at 40 °C. The resulting iron oxyhydroxides were characterized and their properties were also analyzed. Results consistently indicated that mineral phases and crystallinities of the products in CTAB-rich FeCl3 solutions were mainly influenced by pH, and the unstable phase of ferrihydrite was favorable to transform to goethite as the pH values increased. Ethanol addition could have a negative impact on phases and crystallinities of the formed iron oxyhydroxides and also inhibit aggregation of the product particles resulting from CTAB action. Differences in particle morphologies and sizes could be mainly attributed to phases and crystallinities of the formed FeOOH, as well as presence of CTAB and ethanol.

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Literatur
1.
Zurück zum Zitat Cornell RM, Schwertmann U (2003) The iron oxides. Wiley-VCH, WeinHeimCrossRef Cornell RM, Schwertmann U (2003) The iron oxides. Wiley-VCH, WeinHeimCrossRef
2.
Zurück zum Zitat Karimian N, Johnston SG, Burton ED (2017) Effect of cyclic redox oscillations on water quality in freshwater acid sulfate soil wetlands. Sci Total Environ 581–582:314–327CrossRefPubMed Karimian N, Johnston SG, Burton ED (2017) Effect of cyclic redox oscillations on water quality in freshwater acid sulfate soil wetlands. Sci Total Environ 581–582:314–327CrossRefPubMed
3.
Zurück zum Zitat McAllister SM, Barnett JM, Heiss JW, Findlay AJ, MacDonald DJ, Dow CL, Luther GW, Michael HA, Chan CS (2015) Dynamic hydrologic and biogeochemical processes drive microbially enhanced iron and sulfur cycling within the intertidal mixing zone of a beach aquifer. Limnol Oceanogr 60(1):329–345CrossRef McAllister SM, Barnett JM, Heiss JW, Findlay AJ, MacDonald DJ, Dow CL, Luther GW, Michael HA, Chan CS (2015) Dynamic hydrologic and biogeochemical processes drive microbially enhanced iron and sulfur cycling within the intertidal mixing zone of a beach aquifer. Limnol Oceanogr 60(1):329–345CrossRef
4.
Zurück zum Zitat Johnston SG, Morgan B, Burton ED (2016) Legacy impacts of acid sulfate soil runoff on mangrove sediments: reactive iron accumulation, altered sulfur cycling and trace metal enrichment. Chem Geol 427:43–53CrossRef Johnston SG, Morgan B, Burton ED (2016) Legacy impacts of acid sulfate soil runoff on mangrove sediments: reactive iron accumulation, altered sulfur cycling and trace metal enrichment. Chem Geol 427:43–53CrossRef
5.
Zurück zum Zitat Liu YY, Liu XM, Zhao YP, Dionysiou DD (2017) Aligned α-FeOOH nanorods anchored on a graphene oxide-carbon nanotubes aerogel can serve as an effective Fenton-like oxidation catalyst. Appl Catal B Environ 213:74–86CrossRef Liu YY, Liu XM, Zhao YP, Dionysiou DD (2017) Aligned α-FeOOH nanorods anchored on a graphene oxide-carbon nanotubes aerogel can serve as an effective Fenton-like oxidation catalyst. Appl Catal B Environ 213:74–86CrossRef
6.
Zurück zum Zitat Hasan S, Ghosh A, Race K, Schreiber R, Prelas M (2014) Dispersion of FeOOH on chitosan matrix for simultaneous removal of As(III) and As(V) from drinking water. Sep Sci Technol 49(18):2863–2877CrossRef Hasan S, Ghosh A, Race K, Schreiber R, Prelas M (2014) Dispersion of FeOOH on chitosan matrix for simultaneous removal of As(III) and As(V) from drinking water. Sep Sci Technol 49(18):2863–2877CrossRef
7.
Zurück zum Zitat Rahimi S, Moattari RM, Rajabi L, Derakhshan AA, Keyhani M (2015) Iron oxide/hydroxide (α, γ-FeOOH) nanoparticles as high potential adsorbents for lead removal from polluted aquatic media. J Ind Eng Chem 23:33–43CrossRef Rahimi S, Moattari RM, Rajabi L, Derakhshan AA, Keyhani M (2015) Iron oxide/hydroxide (α, γ-FeOOH) nanoparticles as high potential adsorbents for lead removal from polluted aquatic media. J Ind Eng Chem 23:33–43CrossRef
8.
Zurück zum Zitat Xu YQ, Yang M, He CD, Xiong HX (2013) Characterization and spectral analysis of the stable mineral phases α, β-FeOOH included in iron oxyhydroxides. Spectrosc Spect Anal 33(12):3330–3333 Xu YQ, Yang M, He CD, Xiong HX (2013) Characterization and spectral analysis of the stable mineral phases α, β-FeOOH included in iron oxyhydroxides. Spectrosc Spect Anal 33(12):3330–3333
9.
Zurück zum Zitat Chen KF, Chen X, Xue DF (2015) Hydrothermal route to crystallization of FeOOH nanorods via FeCl3·6H2O: effect of Fe3+ concentration on pseudocapacitance of iron-based materials. CrystEngComm 17(9):1906–1910CrossRef Chen KF, Chen X, Xue DF (2015) Hydrothermal route to crystallization of FeOOH nanorods via FeCl3·6H2O: effect of Fe3+ concentration on pseudocapacitance of iron-based materials. CrystEngComm 17(9):1906–1910CrossRef
10.
Zurück zum Zitat Li DY, Hu XZ, Sun YK, Su SB, Xia AL, Ge HL (2015) Goethite (α-FeOOH) nanopowders synthesized via a surfactant-assisted hydrothermal method: morphology, magnetic properties and conversion to rice-like α-Fe2O3 after annealing. RSC Adv 5(34):27091–27096CrossRef Li DY, Hu XZ, Sun YK, Su SB, Xia AL, Ge HL (2015) Goethite (α-FeOOH) nanopowders synthesized via a surfactant-assisted hydrothermal method: morphology, magnetic properties and conversion to rice-like α-Fe2O3 after annealing. RSC Adv 5(34):27091–27096CrossRef
11.
Zurück zum Zitat Bumajdad A, Ali S, Mathew A (2011) Characterization of iron hydroxide/oxide nanoparticles prepared in microemulsions stabilized with cationic/non-ionic surfactant mixtures. J Colloid Interface Sci 355:282–292CrossRefPubMed Bumajdad A, Ali S, Mathew A (2011) Characterization of iron hydroxide/oxide nanoparticles prepared in microemulsions stabilized with cationic/non-ionic surfactant mixtures. J Colloid Interface Sci 355:282–292CrossRefPubMed
12.
Zurück zum Zitat Wei CZ, Nan ZD (2011) Effects of experimental conditions on one-dimensional single-crystal nanostructure of β-FeOOH. Mater Chem Phys 127:220–226CrossRef Wei CZ, Nan ZD (2011) Effects of experimental conditions on one-dimensional single-crystal nanostructure of β-FeOOH. Mater Chem Phys 127:220–226CrossRef
13.
Zurück zum Zitat Rădiţoiu V, Diamandescu L, Corobea MC, Rădiţoiu A, Popescu-Pogrion N, Nicolae CA (2012) A facile hydrothermal route for the synthesis of α-FeOOH with controlled morphology. J Cryst Growth 348:40–46CrossRef Rădiţoiu V, Diamandescu L, Corobea MC, Rădiţoiu A, Popescu-Pogrion N, Nicolae CA (2012) A facile hydrothermal route for the synthesis of α-FeOOH with controlled morphology. J Cryst Growth 348:40–46CrossRef
14.
Zurück zum Zitat Ristić M, Opačak I, Štajdohar J, Musić S (2015) The influence of CTAB and gum arabic on the precipitation of α-FeOOH in a highly alkaline medium. J Mol Struct 1090:129–137CrossRef Ristić M, Opačak I, Štajdohar J, Musić S (2015) The influence of CTAB and gum arabic on the precipitation of α-FeOOH in a highly alkaline medium. J Mol Struct 1090:129–137CrossRef
15.
Zurück zum Zitat Zhang JH, Zhu XM, Yu K (2014) Surfactant-assisted nanorod synthesis of α-FeOOH and its adsorption characteristics for methylene blue. J Mater Res 29(4):509–518CrossRef Zhang JH, Zhu XM, Yu K (2014) Surfactant-assisted nanorod synthesis of α-FeOOH and its adsorption characteristics for methylene blue. J Mater Res 29(4):509–518CrossRef
16.
Zurück zum Zitat Xiong HX, Guo R (2011) Effects of chloride acclimation on iron oxyhydroxides and cell morphology during cultivation of Acidithiobacillus ferrooxidans. Environ Sci Technol 45(1):235–240CrossRefPubMed Xiong HX, Guo R (2011) Effects of chloride acclimation on iron oxyhydroxides and cell morphology during cultivation of Acidithiobacillus ferrooxidans. Environ Sci Technol 45(1):235–240CrossRefPubMed
17.
Zurück zum Zitat Chan CS, Fakra SC, Edwards DC, Emerson D, Banfield JF (2009) Iron oxyhydroxide mineralization on microbial extracellular polysaccharides. Geochim Cosmochim Acta 73(13):3807–3818CrossRef Chan CS, Fakra SC, Edwards DC, Emerson D, Banfield JF (2009) Iron oxyhydroxide mineralization on microbial extracellular polysaccharides. Geochim Cosmochim Acta 73(13):3807–3818CrossRef
18.
Zurück zum Zitat Ghose SK, Waychunas GA, Trainor TP, Eng PJ (2010) Hydrated goethite (α-FeOOH) (100) interface structure: ordered water and surface functional groups. Geochim Cosmochim Acta 74(7):1943–1953CrossRef Ghose SK, Waychunas GA, Trainor TP, Eng PJ (2010) Hydrated goethite (α-FeOOH) (100) interface structure: ordered water and surface functional groups. Geochim Cosmochim Acta 74(7):1943–1953CrossRef
19.
Zurück zum Zitat Wang B, Wu HB, Yu L, Xu R, Lim TT, Lou XW (2012) Template-free formation of uniform urchin-like α-FeOOH hollow spheres with superior capability for water treatment. Adv Mater 24(8):1111–1116CrossRefPubMed Wang B, Wu HB, Yu L, Xu R, Lim TT, Lou XW (2012) Template-free formation of uniform urchin-like α-FeOOH hollow spheres with superior capability for water treatment. Adv Mater 24(8):1111–1116CrossRefPubMed
20.
Zurück zum Zitat JCPDS (Joint Committee on Powder Diffraction Standards) (2002) Mineral powder diffraction files. International Center for Diffraction Data, Swarthmore JCPDS (Joint Committee on Powder Diffraction Standards) (2002) Mineral powder diffraction files. International Center for Diffraction Data, Swarthmore
21.
Zurück zum Zitat Canhisares-Filho JE, Carneiro CEA, de Santana H, Urbano A, da Costa ACS, Zaia CTBV, Zaia DAM (2015) Characterization of the adsorption of nucleic acid bases onto ferrihydrite via Fourier transform infrared and surface-enhanced Raman spectroscopy and X-ray diffractometry. Astrobiology 15(9):728–738CrossRefPubMed Canhisares-Filho JE, Carneiro CEA, de Santana H, Urbano A, da Costa ACS, Zaia CTBV, Zaia DAM (2015) Characterization of the adsorption of nucleic acid bases onto ferrihydrite via Fourier transform infrared and surface-enhanced Raman spectroscopy and X-ray diffractometry. Astrobiology 15(9):728–738CrossRefPubMed
22.
Zurück zum Zitat Christensen G, Younes H, Hong HP, Smith P (2015) Effects of solvent hydrogen bonding, viscosity, and polarity on the dispersion and alignment of nanofluids containing Fe2O3 nanoparticles. J Appl Phys 118(21):214302(1)–214302(9)CrossRef Christensen G, Younes H, Hong HP, Smith P (2015) Effects of solvent hydrogen bonding, viscosity, and polarity on the dispersion and alignment of nanofluids containing Fe2O3 nanoparticles. J Appl Phys 118(21):214302(1)–214302(9)CrossRef
Metadaten
Titel
The properties of FeOOH precipitates formed in CTAB-rich FeCl3 solutions at various pH and ethanol contents
verfasst von
Wen Wei
Haibing Cong
Huixin Xiong
Publikationsdatum
27.05.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 7/2018
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-018-4340-9

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