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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 10/2017

24.08.2017 | Original Contribution

The reinforcing and characteristics of interphase as the polymer chains adsorbed on the nanoparticles in polymer nanocomposites

verfasst von: Nafiseh Nikfar, Milad Esfandiar, Mohammad Reza Shahnazari, Navid Mojtahedi, Yasser Zare

Erschienen in: Colloid and Polymer Science | Ausgabe 10/2017

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Abstract

In this study, the adsorbed polymer chains on the nanoparticle surface are assumed as an interphase layer, which increases the reinforcing efficiency of nanoparticles in polymer nanocomposites. The interphase is taken into account to enhance the effective volume fraction of nanoparticles, which is determined by the Maxwell model for Young’s modulus of composites. Also, the modulus and strength of interphase are calculated by proper models. The interphase properties are estimated and discussed for various samples containing different nanoparticles. The present methodology gives fine agreement between the experimental results of mechanical properties and the calculations. Also, the acceptable results for interphase properties are obtained which confirm the validity of the presented models. The small nanoparticles and thick interphase significantly increase the nanocomposite reinforcement. Additionally, Young’s modulus of nanoparticles causes negligible effect on the modulus of nanocomposites in spite of the interphase properties such as thickness and interfacial area.
Vorheriger Artikel Weibull statistics of lap-shear strength development at partially self-healed polymer−polymer interfaces: a long-term contact
Nächster Artikel Mechanochemical synthesis of chloroapatite and its characterization by powder X-ray diffractometory and attenuated total reflection-infrared spectroscopy

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Metadaten
Titel
The reinforcing and characteristics of interphase as the polymer chains adsorbed on the nanoparticles in polymer nanocomposites
verfasst von
Nafiseh Nikfar
Milad Esfandiar
Mohammad Reza Shahnazari
Navid Mojtahedi
Yasser Zare
Publikationsdatum
24.08.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 10/2017
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4164-z

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