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Erschienen in: European Journal of Wood and Wood Products 4/2017

27.10.2016 | Original

Thermal studies of wood impregnated with ZnCl2

verfasst von: Nestor Tancredi, Mauricio Gabús, María I. Yoshida, Andrés Cuña Suárez

Erschienen in: European Journal of Wood and Wood Products | Ausgabe 4/2017

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Abstract

In this work the thermal behavior of wood impregnated with ZnCl2 is studied. Impregnation of wood with ZnCl2 is a treatment used in activated carbon production, and liquefaction and fast pyrolysis of biomass. Frequently, the impregnated wood is dried for several hours at temperatures above 370 K and then it is carbonized. Catalytic pyrolysis occurs, giving rise to a complex set of reactions. A TG/DTA study was done on the raw material, the activated carbon, the pure ZnCl2 and the intermediate products in order to study the mass and thermal changes occurring. Elemental analysis and SEM analysis were also carried out. An exothermic torrefaction develops during the drying step; the torrefied product is carbonized in an endothermic process that involves ZnCl2 volatilization. The washed impregnated wood carbonizes through an exothermic process that may involve the decomposition of cellulose, lignin and the solid product of hemicellulose torrefaction.

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Literatur
Zurück zum Zitat Beall FC, Eickner HW (1970) Thermal degradation of wood components: a review of the literature. U.S.D.A. Forest Service Research Paper, FPL 130 Beall FC, Eickner HW (1970) Thermal degradation of wood components: a review of the literature. U.S.D.A. Forest Service Research Paper, FPL 130
Zurück zum Zitat Bridgeman TG, Jones JM, Shield I, Williams PT (2008) Torrefaction of reed canary grass, wheat straw and willow to enhance solid fuel qualities and combustion properties. Fuel 87:844–856CrossRef Bridgeman TG, Jones JM, Shield I, Williams PT (2008) Torrefaction of reed canary grass, wheat straw and willow to enhance solid fuel qualities and combustion properties. Fuel 87:844–856CrossRef
Zurück zum Zitat Chen Y, Zhu Y, Wang Z, Li Y, Wang L, Ding L, Gao X, Ma Y, Guo Y (2011) Application studies of activated carbon derived from rice husks produced by chemical-thermal process—a review. Adv Colloid Interface Sci 163:39–52CrossRefPubMed Chen Y, Zhu Y, Wang Z, Li Y, Wang L, Ding L, Gao X, Ma Y, Guo Y (2011) Application studies of activated carbon derived from rice husks produced by chemical-thermal process—a review. Adv Colloid Interface Sci 163:39–52CrossRefPubMed
Zurück zum Zitat Danish M, Hashim R, Ibrahim MNM, Sulaiman O (2013) Effect of acidic activating agents on surface area and surface functional groups of activated carbons produced from Acacia mangium wood. J Anal Appl Pyrol 104:418–425CrossRef Danish M, Hashim R, Ibrahim MNM, Sulaiman O (2013) Effect of acidic activating agents on surface area and surface functional groups of activated carbons produced from Acacia mangium wood. J Anal Appl Pyrol 104:418–425CrossRef
Zurück zum Zitat Dean JA (1999) Lange´s Handbook of chemistry. McGraw-Hill, New York Dean JA (1999) Lange´s Handbook of chemistry. McGraw-Hill, New York
Zurück zum Zitat Huang Y, Zhao G (2016) A novel method for the production of mesoporous activated carbon fibers from liquefied wood. Mater Lett 178:190–192CrossRef Huang Y, Zhao G (2016) A novel method for the production of mesoporous activated carbon fibers from liquefied wood. Mater Lett 178:190–192CrossRef
Zurück zum Zitat Karimnezhad L, Haghighi M, Fatehifar E (2014) Adsorption of benzene and toluene from waste gas using activated carbon activated by ZnCl2. Front Environ Sci Eng 8:835–844CrossRef Karimnezhad L, Haghighi M, Fatehifar E (2014) Adsorption of benzene and toluene from waste gas using activated carbon activated by ZnCl2. Front Environ Sci Eng 8:835–844CrossRef
Zurück zum Zitat Lide DR (2004) CRC Handbook of chemistry and physics. Chemical Rubber Company Press, Boca Raton Lide DR (2004) CRC Handbook of chemistry and physics. Chemical Rubber Company Press, Boca Raton
Zurück zum Zitat Lu Q, Wang Z, Dong C, Zhang Z, Zhang Y, Yang Y, Zhu X (2011) Selective fast pyrolysis of biomass impregnated with ZnCl2: furfural production together with acetic acid and activated carbon as by-products. J Anal Appl Pyrol 91:273–279CrossRef Lu Q, Wang Z, Dong C, Zhang Z, Zhang Y, Yang Y, Zhu X (2011) Selective fast pyrolysis of biomass impregnated with ZnCl2: furfural production together with acetic acid and activated carbon as by-products. J Anal Appl Pyrol 91:273–279CrossRef
Zurück zum Zitat Ma L, Wang T, Liu Q, Zhang X, Ma W, Zhang Q (2012) A review of thermal–chemical conversion of lignocellulosic biomass in China. Biotechnol Adv 30:859–873CrossRefPubMed Ma L, Wang T, Liu Q, Zhang X, Ma W, Zhang Q (2012) A review of thermal–chemical conversion of lignocellulosic biomass in China. Biotechnol Adv 30:859–873CrossRefPubMed
Zurück zum Zitat Marsh H, Rodriguez-Reinoso F (2006) Activated carbon. Elsevier, Amsterdam Marsh H, Rodriguez-Reinoso F (2006) Activated carbon. Elsevier, Amsterdam
Zurück zum Zitat Mohammadi SZ, Karimi MA, Afzali D, Mansouri F (2010) Removal of Pb(II) from aqueous solutions using activated carbon from Sea-buckthorn stones by chemical activation. Desalination 262:86–93CrossRef Mohammadi SZ, Karimi MA, Afzali D, Mansouri F (2010) Removal of Pb(II) from aqueous solutions using activated carbon from Sea-buckthorn stones by chemical activation. Desalination 262:86–93CrossRef
Zurück zum Zitat Nieto-Delgado C, Terrones M, Rangel-Méndez JR (2011) Development of highly microporous activated carbon from the alcoholic beverage industry organic by-products. Biomass Bioenerg 35:103–112CrossRef Nieto-Delgado C, Terrones M, Rangel-Méndez JR (2011) Development of highly microporous activated carbon from the alcoholic beverage industry organic by-products. Biomass Bioenerg 35:103–112CrossRef
Zurück zum Zitat Rangabhashiyam S, Selvaraju N (2015) Adsorptive remediation of hexavalent chromium from synthetic wastewater by a natural and ZnCl2 activated Sterculia guttata shell. J Mol Liquids 207:39–49CrossRef Rangabhashiyam S, Selvaraju N (2015) Adsorptive remediation of hexavalent chromium from synthetic wastewater by a natural and ZnCl2 activated Sterculia guttata shell. J Mol Liquids 207:39–49CrossRef
Zurück zum Zitat Rhee SW, Park H (2010) Effect of mixing ratio of woody waste and food waste on the characteristics of carbonization residue. J Mater Cycles Waste Manag 12:220–226CrossRef Rhee SW, Park H (2010) Effect of mixing ratio of woody waste and food waste on the characteristics of carbonization residue. J Mater Cycles Waste Manag 12:220–226CrossRef
Zurück zum Zitat Rufford TE, Hulicova-Jurcakova D, Khosla K, Zhu Z, Lu GQ (2010) Microstructure and electrochemical double-layer capacitance of carbon electrodes prepared by zinc chloride activation of sugar cane bagasse. J Power Sources 195:912–918CrossRef Rufford TE, Hulicova-Jurcakova D, Khosla K, Zhu Z, Lu GQ (2010) Microstructure and electrochemical double-layer capacitance of carbon electrodes prepared by zinc chloride activation of sugar cane bagasse. J Power Sources 195:912–918CrossRef
Zurück zum Zitat Ruiz-Fernández M, Alexandre-Franco M, Fernández-González C, Gómez-Serrano V (2011) Development of activated carbon from vine shoots by physical and chemical activation methods. Some insight into activation mechanisms. Adsorption 17:621–629CrossRef Ruiz-Fernández M, Alexandre-Franco M, Fernández-González C, Gómez-Serrano V (2011) Development of activated carbon from vine shoots by physical and chemical activation methods. Some insight into activation mechanisms. Adsorption 17:621–629CrossRef
Zurück zum Zitat Shopova N, Minkova V, Markova K (1997) Evaluation of the thermochemical changes in agricultural by-products and in the carbon adsorbents obtained from them. J Therm Anal 48:309–320CrossRef Shopova N, Minkova V, Markova K (1997) Evaluation of the thermochemical changes in agricultural by-products and in the carbon adsorbents obtained from them. J Therm Anal 48:309–320CrossRef
Zurück zum Zitat Strezov V, Moghtaderi B, Lucas JA (2003) Thermal study of decomposition of selected biomass samples. J Therm Anal Calorim 72:1041–1048CrossRef Strezov V, Moghtaderi B, Lucas JA (2003) Thermal study of decomposition of selected biomass samples. J Therm Anal Calorim 72:1041–1048CrossRef
Zurück zum Zitat Tazibet S, Boucheffa Y, Lodewyckx P, Velasco LF, Boutillara Y (2016) Evidence for the effect of the cooling down step on activated carbon adsorption properties. Microporous Mesoporous Mat 221:67–75CrossRef Tazibet S, Boucheffa Y, Lodewyckx P, Velasco LF, Boutillara Y (2016) Evidence for the effect of the cooling down step on activated carbon adsorption properties. Microporous Mesoporous Mat 221:67–75CrossRef
Zurück zum Zitat Wang S, Liu Q, Luo Z, Wen L, Cen K (2007) Mechanism study on cellulose pyrolysis using thermogravimetric analysis coupled with infrared spectroscopy. Front Energ Power Eng China 1:1–7CrossRef Wang S, Liu Q, Luo Z, Wen L, Cen K (2007) Mechanism study on cellulose pyrolysis using thermogravimetric analysis coupled with infrared spectroscopy. Front Energ Power Eng China 1:1–7CrossRef
Zurück zum Zitat Wang G, Luo Y, Deng J, Kuang JH, Zhang Y (2011) Pretreatment of biomass by torrefaction. Chin Sci Bull 56:1442–1448CrossRef Wang G, Luo Y, Deng J, Kuang JH, Zhang Y (2011) Pretreatment of biomass by torrefaction. Chin Sci Bull 56:1442–1448CrossRef
Zurück zum Zitat Zhang H, Yan Y, Yang L (2010) Preparation of activated carbon from sawdust by zinc chloride activation. Adsorption 16:161–166CrossRef Zhang H, Yan Y, Yang L (2010) Preparation of activated carbon from sawdust by zinc chloride activation. Adsorption 16:161–166CrossRef
Metadaten
Titel
Thermal studies of wood impregnated with ZnCl2
verfasst von
Nestor Tancredi
Mauricio Gabús
María I. Yoshida
Andrés Cuña Suárez
Publikationsdatum
27.10.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
European Journal of Wood and Wood Products / Ausgabe 4/2017
Print ISSN: 0018-3768
Elektronische ISSN: 1436-736X
DOI
https://doi.org/10.1007/s00107-016-1113-3

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