nach oben

Journal of Polymer Research

Erschienen in:

01.05.2021 | ORIGINAL PAPER

Thermo- and pH-responsive copolymer of N-isopropylacrylamide with acryloylvaline: synthesis and properties in aqueous solutions

verfasst von: E. Tarabukina, V. Harabagiu, G. Fundueanu, M. Constantin, A. Filippov

Erschienen in: Journal of Polymer Research | Ausgabe 5/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

N-acryloyl-L-valine (AV) was synthesized as a pH-sensitive monomer possessing both acrylamide and isopropyl sequences similar to the chemical architecture of N-isopropylacrylamide (NIPAAm). Poly(NIPAAm-co-AV) copolymer contained 5.03 mol % randomly introduced AV units was prepared and analyzed. The sample with molar mass M_w = 24,000 g/mol was studied in aqueous solutions using static and dynamic light scattering and optical transmittance methods. Temperature dependences of scattered light intensity and turbidity as well as hydrodynamic radii of dissolved species and their relative contributions to the light scattering were obtained to determine the temperatures of phase separation in aqueous media of various acidities. The dependence of the phase separation onset temperatures on pH corresponded to that obtained for anionic pH-responsive polymers. Aggregated structures were observed in solutions; moreover, in a strongly acidic medium, with an increase in temperature, the compaction of aggregates predominated, and with an increase in pH, the formation of new aggregates dominated over their compaction.

Vorheriger Artikel Nanocomposite synthesis of silver doped magnesium oxide incorporated in PVC matrix for photocatalytic applications

Nächster Artikel Preparation and property evaluations of PCL/PLA composite films

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Gil ES, Hudson SM (2004) Stimuli-reponsive polymers and their bioconjugates. Prog Polym Sci 29:1173–1222. https://doi.org/10.1016/j.progpolymsci.08.003CrossRef

Dimitrov I, Trzebnicka B, Muller AHE, Dworak A, Tsvetanov CB (2007) Thermosensitive water-soluble copolymers with doubly responsive reversibly interacting entities. Prog Polym Sci 32:1275–1343. https://doi.org/10.1016/j.progpolymsci.2007.07.001CrossRef

Theato P, Sumerlin BS, O’Reilly RK, Epps TH (2013) Stimuli responsive materials. Chem Soc Rev 42:7055. https://doi.org/10.1039/c3cs90057fCrossRefPubMed

Honey PJ, Rijo J, Anju A, Anoop KR (2014) Smart polymers for the controlled delivery of drugs – a concise overview. Acta Pharm Sin B 4(2):120–127. https://doi.org/10.1016/j.apsb.2014.02.005CrossRef

Aseyev VO, Tenhu H, Winnik FM (2006) Temperature dependence of the colloidal stability of neutral amphiphilic polymers in water. Adv Polym Sci 196:1–85. https://doi.org/10.1007/12_052CrossRef

Hirokawa Y, Tanaka T (1984) Volume phase transition in a nonionic gel. J Chem Phys 81:6379–6380. https://doi.org/10.1063/1.447548CrossRef

Widom B, Bhimalapuram B, Koga K (2003) The hydrophobic effect. Phys. Chem Phys 5:3085–3093. https://doi.org/10.1039/B304038KCrossRef

Solis FJ, Weiss-Malik R, Vernon B (2005) Local monomer activation model for phase behavior and calorimetric properties of LCST gel-forming polymers. Macromolecules 38:4456–4464. https://doi.org/10.1021/ma047895aCrossRef

Heskins M, Guillet JE (1968) Solution properties of poly (N-isopropylacrylamide). J Macromol Sci Part A: Chem 2:1441–1455. https://doi.org/10.1080/10601326808051910CrossRef

10.

Schild HG (1992) Poly (N-Isopropylacrylamide) – experiment, theory and application Prog Polym Sci 17:163−249. https://doi.org/10.1016/0079-6700(92)90023-R.

11.

Fujishide S (1987) Intrinsic viscosity – molecular weight relationships for poly(N-isopropylacrylamide) solutions. Polym J 192:97–300

12.

Ye J, Xu J, Hu J, Wang X, Zhang G, Liu S, Wu C (2008) Comparative study of temperature-induced association of cyclic and linear poly(N-isopropylacrylamide) chains in dilute solutions by laser light scattering and stopped-flow temperature jump. Macromolecules 41:4416–4422. https://doi.org/10.1021/ma702196gCrossRef

13.

Otake K, Inomata H, Konno M, Saito S (1990) Thermal analysis of the volume phase transition with N-isopropylacrylamide gels. Macromolecules 23:283–289. https://doi.org/10.1021/ma00203a049CrossRef

14.

Winnik FM (1990) Fluorescence studies of aqueous solutions of poly(N-isopropylacrylamide) below and above their LCST. Macromolecules 23(1):233–242. https://doi.org/10.1021/ma00203a040CrossRef

15.

Rimmer S, Soutar I, Swanson L (2009) Switching the conformational behaviour of poly(N-isopropyl acrylamide). Polym Int 58:273–278. https://doi.org/10.1002/pi.2537CrossRef

16.

Inomata H, Goto S, Saito S (1990) Phase transition of N-substituted acrylamide gels. Macromolecules 23:4887–4888. https://doi.org/10.1021/ma00224a023CrossRef

17.

Shibayama M, Mizutani S, Nomura S (1996) Thermal properties of copolymer gels containing N-Isopropylacrylamide. Macromolecules 29:2019–2024. https://doi.org/10.1021/ma951390qCrossRef

18.

Winnik F (1990) Phase transition of aqueous poly-(N-isopropylacrylamide) solutions: a study by non-radiative energy transfer. Polymer 31:2125–2134. https://doi.org/10.1016/0032-3861(90)90085-DCrossRef

19.

Kubota K, Fujishige S, Ando I (1990) Single-chain transition of poly(N-isopropylacrylamide) in water. J Phys Chem 94:5154–5158. https://doi.org/10.1021/j100375a070CrossRef

20.

Wang X, Wu C (1999) Light-scattering study of coil-to-globule transition of a poly(N-isopropylacrylamide) chain in deuterated water. Macromolecules 32:4299–4301. https://doi.org/10.1021/ma9902450CrossRef

21.

Okada Y, Tanaka F (2005) Cooperative hydration, chain collapse, and flat LCST behavior in aqueous poly(N-isopropylacrylamide) solutions. Macromolecules 38:4465–4471. https://doi.org/10.1021/ma0502497CrossRef

22.

Kocak G, Tuncer C, Bütün V (2017) pH-Responsive polymers. Polym Chem 8:144–176. https://doi.org/10.1039/C6PY01872FCrossRef

23.

Yoo MK, Sung YK, Lee YM, Cho CS (2000) Effect of polyelectrolyte on the lower critical solution temperature of poly(Nisopropylacrylamide) in the poly(NIPAAm-co-acrylic acid) hydrogel. Polymer 41:5713–5719. https://doi.org/10.1016/S0032-3861(99)00779-XCrossRef

24.

Petrusic S, Jovancic P, Lewandowski M, Giraud S, Grujic S, Ostojic S, Bugarski B, Koncar V (2013) Properties and drug release profile of poly(N-isopropylacrylamide) microgels functionalized with maleic anhydride and alginate. J Mater Sci 48(22):7935–7948. https://doi.org/10.1007/s10853-013-7604-2CrossRef

25.

Taşdelen B, Kayaman-Apohan N, Guven O, Baysal BM (2004) pH-thermoreversible hydrogels. I. Synthesis and characterization of poly(N-isopropylacrylamide/maleic acid) copolymeric hydrogels. Radiat Phys Chem 69(4): 303−310. https://doi.org/10.1016/j.radphyschem.2003.07.004.

26.

Xu Y, Shi V, Ma R, Zhang W, An Y, Zhu XX (2007) Synthesis and micellization of thermo- and pH-responsive block copolymer of poly(N-isopropylacrylamide)-block-poly(4-vinylpyridine). Polymer 48:1711–1717. https://doi.org/10.1016/j.polymer.2007.01.022CrossRef

27.

Deen GR, Zhen QL, Hao MC, Loh XJ (2013) Influence of multiple stimuli on the lower critical solution temperature of new cationic poly(N-acryloyl-N’-ethylpiperazine-co-N-isopropylacrylamide) solutions. J Polym Sci Part B: Polym Phys 51:1175–1183. https://doi.org/10.1002/polb.23316CrossRef

28.

Castro-Hernández A, Cortez-Lemus NA (2019) Thermo/pH responsive star and linear copolymers containing a cholic acid-derived monomer, N-isopropylacrylamide and acrylic acid: synthesis and solution properties. Polymers (Basel) 11(11):1859. https://doi.org/10.3390/polym11111859CrossRef

29.

Gao X, Cao Y, Song X, Zhang Z, Xiao C, He C, Chen X (2013) pH- and thermo-responsive poly(N-isopropylacrylamide-co-acrylic acid derivative) copolymers and hydrogelswith LCST dependent on pH and alkyl side groups. J Mater Chem B 1:5578–5587. https://doi.org/10.1039/c3tb20901fCrossRefPubMed

30.

Filippov AP, Tarabukina EB, Simonova MA, Kirila TU, Fundueanu G, Harabagiu V, Constantin M, Popescu I (2015) Synthesis and investigation of double stimuli-responsive behavior of N-isopropylacrylamide and maleic acid copolymer. J Macromol Sci Part B: Phys 54(9):1105–1121. https://doi.org/10.1080/00222348.2015.1057444CrossRef

31.

Tarabukina EB, Simonova MA, Bucatariu S, Harabagiu V, Fundueanu G (2015) Filippov AP Behavior of thermo- and pH-responsive copolymer of N-isopropylacrylamide and maleic acid in aqueous solutions. Int J Polym Anal Char 21:11–17. https://doi.org/10.1080/1023666X.2015.1089459CrossRef

32.

Tarabukina E, Seyednov E, Filippov A, Constantin M, Harabagiu V, Fundueanu G (2017) Thermoresponsive properties of N-isopropylacrylamide with methacrylic acid copolymer in media of different acidity. Macromol Res 25(7):680–688. https://doi.org/10.1007/s13233-017-5077-xCrossRef

33.

Tarabukina E, Rozanova A, Filippov A, Constantin M, Harabagiu V, Fundueanu G (2018) Thermo- and pH-responsive phase separation of N-isopropylacrylamide with 4-vinylpyridine random copolymer in aqueous solutions. J Colloid Polym Sci 296:557–565. https://doi.org/10.1007/s00396-018-4269-zCrossRef

34.

Dutta P, Dey J, Ghosh G, Nayak RR (2009) Self-association and microenvironment of random amphiphilic copolymers of sodium N-acryloyl-L-valinate and N-dodecylacrylamide in aqueous solution. Polymer 50:1516–1525. https://doi.org/10.1016/j.polymer.2008.12.049CrossRef

35.

Kratochvil P (1987) Classical light scattering from polymer solution. Elsevier, Amsterdam

36.

Schärtl W (2007) Light scattering from polymer solutions and nanoparticle dispersions. Springer-Verlag, Berlin

37.

Huang C, Li Y, Duan L, Wang L, Ren X, Gaoa G (2017) Enhancing the self-recovery and mechanical property of hydrogels by macromolecular microspheres with thermal and redox initiation systems. RSC Adv 7:16015–16021. https://doi.org/10.1039/c7ra00317jCrossRef

38.

Bivigou-Koumba AM, Görnitz E, Laschewsky A, Müller-Buschbaum P, Papadakis CM (2010) Thermoresponsive amphiphilic symmetrical triblock copolymers with a hydrophilic middle block made of poly(N-isopropylacrylamide): synthesis, self-organization, and hydrogel formation. Colloid Polym Sci 288:499–517. https://doi.org/10.1007/s00396-009-2179-9CrossRef

39.

Boerman MA, Van der Laan HL, Bender JCME, Hoogenboom R, Jansen JA, Leeuwenburgh SC, Van Hest JCM (2016) Synthesis of pH- and thermoresponsive poly(2-n-propyl-2-oxazoline) based copolymers. J Polym Sci Part A: Polym Chem 54:1573–1582. https://doi.org/10.1002/pola.28011CrossRef

40.

Tarabukina E, Rozanova A, Fundueanu G, Constantin M, Harabagiu V, Filippov A (2020) Thermo-sensitivity of poly-N-isopropylacrylamide with statistically introduced D, L-allylglycine betainic units. J Macromol Sci, Part B: Phys 59:100–120. https://doi.org/10.1080/00222348.2019.1695379CrossRef

41.

Filippov A, Tarabukina E, Kudriavtseva A, Fatullaev E, Kurlykin M, Tenkovtsev A (2019) Molecular brushes with poly-2-ethyl-2-oxazoline side chains and aromatic polyester backbone manifesting double stimuli-responsiveness. Colloid Polym Sci 297:1445–1454. https://doi.org/10.1007/s00396-019-04558-7CrossRef

42.

Amirova A, Rodchenko S, Filippov A (2016) Time dependence of the aggregation of star-shaped poly(2-isopropyl-2-oxazolines) in aqueous solutions. J Polym Res 23(11):221. https://doi.org/10.1007/s10965-016-1112-4CrossRef

Titel: Thermo- and pH-responsive copolymer of N-isopropylacrylamide with acryloylvaline: synthesis and properties in aqueous solutions
verfasst von: E. Tarabukina
V. Harabagiu
G. Fundueanu
M. Constantin
A. Filippov
Publikationsdatum: 01.05.2021
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 5/2021
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-021-02515-z

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 5/2021

Kinetic and thermal study of ethylene-propylene copolymerization catalyzed by ansa-zirconocene activated with Alkylaluminium/borate: Effects of linear and branched alkylaluminium compounds as cocatalyst

The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separation

A (4,12)-connected coordination polymer: photocatalytic degradation of dyes and effects on cerebral edema care by regulating superoxide dismutase activity

Effect of anion on CO2 capture in PVC–g–P[VBIm][X] ionomers: experimental and density functional theory studies

Microwave assisted quaternized cyclodextrin grafted chitosan (QCD-g-CH) nanoparticles entrapping ciprofloxacin

Functionalization of polyhydromethylsiloxane with nitrogen-containing organic compounds

Premium Partner

Marktübersichten