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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2016

01.06.2016 | Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

Thermochromic performances of tungsten-doping porous VO2 thin films

verfasst von: Changlin Zhao, Haizheng Tao, Fei Peng, Ruikun Pan, Xiujian Zhao

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2016

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Abstract

Using the vanadium oxyacetylacetone (VO(AcAc)2) as the precursor and white powdery tungstic acid as the doping W source, we fabricated the W-doped porous VO2 films by spin-coating method followed by annealing under the N2 atmosphere at 550 °C for half an hour. Compared to the pure VO2 film, the 5 at.% W-doped film exhibits a simultaneous enhancement of the near-IR switching efficiency at 2000 nm from 47.5 to 55.0 % and the maximum value of visible transmittance at 30 °C from 39.5 to 46.7 % as well as the one at 90 °C from 44.7 to 58.1 %, which further confirmed the practicability of introducing pores into the VO2 film as a strategy to enhance the thermochromic properties. In addition, a possible connection is presented about the relationship of metal–insulator transition process and the evolution of the phase compositions and morphology.

Graphical Abstract

A possible connection between the morphology and the thermochromic performance for the W-doped VO2 films was presented.
Vorheriger Artikel Large room-temperature magnetoresistance in epitaxial La0.7Ca0.25Sr0.05MnO3 thin films prepared by sol–gel method
Nächster Artikel Structure and properties of the V-doped TiO2 thin films obtained by sol–gel and microwave-assisted sol–gel method

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Literatur
1.
Morin FJ (1959) Oxides which show a metal-to-insulator transition at the Neel temperature. Phys Rev Lett 3(1):34–36CrossRef
2.
Goodenough JB (1971) The two components of the crystallographic transition in VO2. J Solid State Chem 3(4):490–500CrossRef
3.
Jin P, Nakao S, Tanemura S (1998) High-energy W ion implantation into VO2 thin film. Nucl Instrum Methods Phys Res B 141:419–424CrossRef
4.
Kim BJ, Lee YW, Choi S (2008) Micrometer X-ray diffraction study of VO2 films: separation between metal-insulator transition and structural phase transition. Phys Rev B 77:235401CrossRef
5.
Lysenko S, Rua A, Vikhnin V (2007) Insulator-to-metal phase transition and recovery processes in VO2 thin films after femtosecond laser excitation. Phys Rev B 76:035104CrossRef
6.
Qazilbash MM, Brehm M, Chae BG (2007) Mott transition in VO2 revealed by infrared spectroscopy and nano-imaging. Science 318(5857):1750–1753CrossRef
7.
Granqvist CG (1990) Chromogenic materials for transmittance control of large-area windows. Crit Rev Solid State Mater Sci 16:291CrossRef
8.
Fan LL, Chen S, Luo ZL (2014) Strain dynamics of ultrathin VO2 film grown on TiO2 (001) and the associated phase transition modulation. Nano Lett 14(7):4036–4043CrossRef
9.
Mlyuka NR, Niklasson GA, Granqvist CG (2009) Mg doping of thermochromic VO2 films enhances the optical transmittance and decreases the metal-insulator transition temperature. Appl Phys Lett 7:171909CrossRef
10.
Lee MH, Cho JS (2000) Better thermochromic glazing of windows with anti-reflection coating. Thin Solid Films 365(1):5–6CrossRef
11.
Binions R, Hyett G, Piccirillo C (2007) Doped and un-doped vanadium dioxide thin films prepared by atmospheric pressure chemical vapour deposition from vanadyl acetylacetonate and tungsten hexachloride: the effects of thickness and crystallographic orientation on thermochromic properties. J Mater Chem 17(44):4652–4660CrossRef
12.
Zhou M, Bao J, Tao MS (2013) Periodic porous thermochromic VO2(M) films with enhanced visible transmittance. Chem Commun 49(54):6021–6023CrossRef
13.
Oka Y, Yao T, Yamamoto N (1991) Structural phase transition of VO2(B) to VO2(A). J Mater Chem 1(5):815–818CrossRef
14.
Leroux C, Nihoul G, Van Tendeloo G (1998) From VO2(B) to VO2(R): theoretical structures of VO2 polymorphs and in situ electron microscopy. Phys Rev B 57(9):5111CrossRef
15.
Hagrman D, Zubieta J, Warren CJ (1998) A new polymorph of VO2 prepared by soft chemical methods. J Solid State Chem 138(1):178–182CrossRef
16.
Liu L, Cao F, Yao T (2012) New-phase VO2 micro/nanostructures: investigation of phase transformation and magnetic property. New J Chem 36(3):619–625CrossRef
17.
Zhang ZT, Gao YF, Chen Z (2010) Thermochromic VO2 thin films: solution-based processing, improved optical properties, and lowered phase transformation temperature. Langmuir 26(13):10738–10744CrossRef
18.
Jin P, Tanemura S (1995) Relationship between transition temperature and x in V1−x W x O2 films deposited by dual-target magnetron sputtering. Jpn J Appl Phys 34:2459CrossRef
19.
Strelcov E, Tselev A, Ivanov I (2012) Doping-based stabilization of the M2 phase in free-standing VO2 nanostructures at room temperature. Nano Lett 12:6198–6205CrossRef
20.
Park JH, Coy JM, Kasirga TS (2013) Measurement of a solid-state triple point at the metal-insulator transition in VO2. Nature 500(7463):431–434CrossRef
21.
Jeong J, Aetukuri N, Graf T, Parkin SSP (2013) Suppression of metal-insulator transition in VO2 by electric field-induced oxygen vacancy formation. Science 339(6126):1402–1405CrossRef
22.
Pan M, Zhong HM, Wang SW (2004) Properties of VO2 thin film prepared with precursor VO(AcAc)2. J Cryst Growth 265:121–126CrossRef
23.
Liu YK, Tao HZ, Chu XH (2014) Effects of addition of tungsten chloride on optical properties of VO2-based thermochromic films prepared by sol–gel method. J Non Cryst Solids 383(1):116–120CrossRef
24.
Peng ZF, Jiang W, Liu H (2007) Synthesis and electrical properties of tungsten-doped vanadium dioxide nanopowders by thermolysis. J Phys Chem C 111(3):1119–1122CrossRef
25.
Griffiths CH, Eastwood HK (1974) Influence of stoichiometry on the metal-semiconductor transition in vanadium dioxide. J Appl Phys 45(5):2201–2206CrossRef
26.
Guinneton F, Sauques L, Valmalette JC (2005) Role of surface defects and microstructure in infrared optical properties of thermochromic VO2 materials. J Phys Chem Solids 66(1):63–73CrossRef
27.
Xu G, Jin P, Tazawa M (2004) Tailoring of luminous transmittance upon switching for thermochromic VO2 films by thickness control. Jpn J Appl Phys, Part 1 43(1):186–187CrossRef
28.
Xu G, Jin P, Tazawa M (2004) Optimization of antireflection coating for VO2-based energy efficient window. Sol Energy Mater Sol Cells 83(1):29–37CrossRef
29.
Jin P, Xu G, Tazawa M (2003) Design, formation and characterization of a novel multifunctional window with VO2 and TiO2 coatings. Appl Phys A Mater Sci Process 77(3–4):455–459
30.
Lappalainen J, Jantunen H, Heinilehto S (2008) Microstructure dependent switching properties of VO2 thin films. Sens Actuators, A 142(1):250–255CrossRef
31.
32.
Xu G, Jin P, Tazawa M (2005) Thickness dependence of optical properties of VO2 thin films epitaxially grown on sapphire (0001). Appl Surf Sci 244(1):449–452CrossRef
33.
Kang LT, Gao YF, Zhang ZT (2010) Effects of annealing parameters on optical properties of thermochromic VO2 films prepared in aqueous solution. J Phys Chem C 114:1901–1911CrossRef
34.
Aetukuri NB, Gray AX, Drouard M (2013) Control of the metal-insulator transition in vanadium dioxide by modifying orbital occupancy. Nat Phys 9(10):661–666CrossRef
35.
Tan X, Yao T, Long R (2012) Unraveling metal-insulator transition mechanism of VO2 triggered by tungsten doping. Sci Rep 2:466. doi:10.​1038/​srep00466
36.
Suh JY, Lopez R, Feldman LC, Haglund RF (2004) Semiconductor to metal phase transition in the nucleation and growth of nanoparticles and thin films. J Appl Phys 96:1209–1213CrossRef
37.
Metadaten
Titel
Thermochromic performances of tungsten-doping porous VO2 thin films
verfasst von
Changlin Zhao
Haizheng Tao
Fei Peng
Ruikun Pan
Xiujian Zhao
Publikationsdatum
01.06.2016
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2016
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-016-3976-5

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