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Journal of Coatings Technology and Research
Erschienen in: Journal of Coatings Technology and Research 1/2015

01.01.2015

Titanium dioxide/conducting polymers composite pigments for corrosion protection of cold rolled steel

verfasst von: Niteen Jadhav, Victoria Gelling

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 1/2015

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Abstract

Titanium dioxide (TiO2)/conducting polymers composite pigments were synthesized by chemical oxidative polymerization technique in a simple and eco-friendly manner. These composite pigments were characterized for morphology by scanning electron microscopy and transmission electron microscopy, for conductivity by four point probe and conductive-atomic force microscopy, for elemental composition by X-ray photoelectron spectroscopy, and for chemical composition by Fourier transform infrared spectroscopy. Three different types of composite pigments were synthesized, namely TiO2/polypyrrole composite pigment, TiO2/polypyrrole composite pigment doped with tungstate anion, and TiO2/polyaniline composite pigment. Core and shell morphology was obtained for TiO2/polypyrrole composite pigment and TiO2/polypyrrole composite pigment doped with tungstate anion. Coatings based on these pigments were formulated and applied on a cold rolled steel substrate. Constant immersion in 5% sodium chloride was employed for studying the corrosion resistance offered by composite pigments-based coatings. The corrosion resistance of the coatings was monitored by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization technique. EIS results demonstrated increased corrosion protection for the core and shell TiO2/polypyrrole composite, TiO2/polypyrrole (tungstate doped) composite, and TiO2/polyaniline composite. Additionally, potentiodynamic scan results demonstrated passivation achieved by synthesized composite pigments-based coatings, suggesting improved corrosion protection.
Vorheriger Artikel A quantitative study of nanoparticle release from nanocoatings exposed to UV radiation
Nächster Artikel Preparation and characterization of anticorrosion polyurethane paints and coatings based on novel Zn-free phosphates

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Metadaten
Titel
Titanium dioxide/conducting polymers composite pigments for corrosion protection of cold rolled steel
verfasst von
Niteen Jadhav
Victoria Gelling
Publikationsdatum
01.01.2015
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 1/2015
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-014-9613-8

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