2007 | OriginalPaper | Buchkapitel
Titanium through Rutherfordium
Erschienen in: Inorganic Reactions in Water
Verlag: Springer Berlin Heidelberg
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Water. Titanium(III) salts are in general readily soluble in H
2
O, forming a winered to violet solution, depending on the acidity. Water, above pH 7, and Ti
2
O
3
⋅ aq form TiO
2
⋅ aq and H
2
, catalyzed by 3d
II
, Pt and Li+ and Na+. Titanium dioxide is insoluble in H
2
O. The hydrated oxide, TiO
2
⋅ aq, is slightly amphoteric, with both basic and acidic salts hydrolyzing readily to TiO
2
⋅ aq. Boiling makes it less hydrated and less soluble.