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2016 | OriginalPaper | Buchkapitel

Transition Metal-Catalyzed Carboxylation of Organic Substrates with Carbon Dioxide

verfasst von : Marcel Brill, Faïma Lazreg, Catherine S. J. Cazin, Steven P. Nolan

Erschienen in: Carbon Dioxide and Organometallics

Verlag: Springer International Publishing

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Abstract

The development of sustainable chemical processes is a long-standing challenge. Carbon dioxide represents a renewable C1 building block for organic synthesis and industrial applications as an alternative to other common feedstocks which are based on natural gas, petroleum oil, or coal. Apart from the advantages associated with the nontoxicity and abundance of CO₂, its utilization further enables the reduction in its atmospheric content, which contributes significantly to the greenhouse effect. Although widespread application of CO₂ in organic synthesis – even on an industrial scale – will not be able to fully compensate for the steadily increasing atmospheric quantities produced (mainly by the combustion of fuels), ecological and economical factors make its usage highly desirable. Therefore, tremendous efforts toward activation and utilization of CO₂ have been made by the scientific community over the last 30 years, and, as a result, the number of highly efficient transition metal-catalyzed CO₂-incorporative reactions has increased dramatically, especially within the last decade. The achievements in the development of sustainable and economic chemical processes for the carboxylation of organic molecules with CO₂ are presented in detail in this chapter.

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Vorheriges Kapitel Ni-Catalyzed Synthesis of Acrylic Acid Derivatives from CO2 and Ethylene

Nächstes Kapitel Recent Progress in Carbon Dioxide Reduction Using Homogeneous Catalysts

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Titel: Transition Metal-Catalyzed Carboxylation of Organic Substrates with Carbon Dioxide
verfasst von: Marcel Brill
Faïma Lazreg
Catherine S. J. Cazin
Steven P. Nolan
Verlag: Springer International Publishing
Buch: Carbon Dioxide and Organometallics
Print ISBN: 978-3-319-22077-2

Electronic ISBN: 978-3-319-22078-9

Copyright-Jahr: 2016
DOI: https://doi.org/10.1007/3418_2015_110

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