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Erschienen in: Tribology Letters 2/2014

01.05.2014 | Original Paper

Tribological Investigation of MC PA6 Reinforced by Boron Nitride of Single Layer

verfasst von: Bingli Pan, Ning Li, Guangcheng Chu, Fengjun Wei, Jichun Liu, Junkai Zhang, Yongzhen Zhang

Erschienen in: Tribology Letters | Ausgabe 2/2014

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Abstract

Monomer casting polyamide 6 (MC PA6)/boron nitride of single layer (SBN) nanocomposites were successfully synthesized by in situ ring-opening polymerization. SBN was prepared by sonication assisted with solution beforehand. Studies on frictional and wear performance of the nanocomposites were carried out on a block-on-ring tester. The results showed that the nanocomposites had lower wear rates and friction coefficients in comparison with neat MC PA6. The incorporation of 0.25 wt% SBN into MC PA6 significantly reduced wear and friction under dry sliding; however, with further increasing the SBN loading, both wear rate and friction coefficient began to increase. The SEM micrographs of the worn surface revealed their friction and wear mechanisms. Pure MCPA6 was characterized by severe lamellar spalling with adhesive wear being the major wear form which caused high friction and wear. The wear modes of the nanocomposites became mainly abrasive wear with lower content of SBN and displayed fatigue wear with higher content of SBN. The morphology of a uniform transfer film on the counterpart ring and fine wear debris for the nanocomposites corresponded to the improved tribological performance.

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Literatur
1.
Zurück zum Zitat Briscoe, B.J., Sinha, S.K.: Chapter 1—Tribological applications of polymers and their composites—past, present and future prospects. In: Tribology of polymeric nanocomposites (Second Edition). pp. 1–22. Butterworth-Heinemann, Oxford (2013) Briscoe, B.J., Sinha, S.K.: Chapter 1—Tribological applications of polymers and their composites—past, present and future prospects. In: Tribology of polymeric nanocomposites (Second Edition). pp. 1–22. Butterworth-Heinemann, Oxford (2013)
2.
Zurück zum Zitat Novoselov, K.S., Jiang, D., Schedin, F., Booth, T.J., Khotkevich, V.V., Morozov, S.V., Geim, A.K.: Two-dimensional atomic crystals. Proc. Natl. Acad. Sci. U.S.A. 102(30), 10451–10453 (2005). doi:10.1073/pnas.0502848102 CrossRef Novoselov, K.S., Jiang, D., Schedin, F., Booth, T.J., Khotkevich, V.V., Morozov, S.V., Geim, A.K.: Two-dimensional atomic crystals. Proc. Natl. Acad. Sci. U.S.A. 102(30), 10451–10453 (2005). doi:10.​1073/​pnas.​0502848102 CrossRef
5.
Zurück zum Zitat Lee, C., Li, Q.Y., Kalb, W., Liu, X.Z., Berger, H., Carpick, R.W., Hone, J.: Frictional characteristics of atomically thin sheets. Science 328, 76–80 (2010)CrossRef Lee, C., Li, Q.Y., Kalb, W., Liu, X.Z., Berger, H., Carpick, R.W., Hone, J.: Frictional characteristics of atomically thin sheets. Science 328, 76–80 (2010)CrossRef
6.
Zurück zum Zitat Filleter, T., Mcchesney, J.L., Bostwick, A., Rotenberg, E., Emtsev, K.V., Seyller, T., Horn, K., Bennewitz, R.: Friction and dissipation in epitaxial graphene films. Phys. Rev. Lett. 102, 1–4 (2009)CrossRef Filleter, T., Mcchesney, J.L., Bostwick, A., Rotenberg, E., Emtsev, K.V., Seyller, T., Horn, K., Bennewitz, R.: Friction and dissipation in epitaxial graphene films. Phys. Rev. Lett. 102, 1–4 (2009)CrossRef
7.
Zurück zum Zitat Ko, J.-H., Kwon, S., Byun, I.-S., Choi, J.S., Park, B.H., Kim, Y.-H., Park, J.Y.: Nanotribological properties of fluorinated, hydrogenated, and oxidized graphenes. Tribol. Lett. 50(2), 137–144 (2013). doi:10.1007/s11249-012-0099-1 Ko, J.-H., Kwon, S., Byun, I.-S., Choi, J.S., Park, B.H., Kim, Y.-H., Park, J.Y.: Nanotribological properties of fluorinated, hydrogenated, and oxidized graphenes. Tribol. Lett. 50(2), 137–144 (2013). doi:10.​1007/​s11249-012-0099-1
8.
Zurück zum Zitat Ou, J., Wang, Y., Wang, J., Liu, S., Li, Z., Yang, S.: Self-assembly of octadecyltrichlorosilane on graphene oxide and the tribological performances of the resultant film. J. Phys. Chem. C 115(20), 10080–10086 (2011). doi:10.1021/jp200597k CrossRef Ou, J., Wang, Y., Wang, J., Liu, S., Li, Z., Yang, S.: Self-assembly of octadecyltrichlorosilane on graphene oxide and the tribological performances of the resultant film. J. Phys. Chem. C 115(20), 10080–10086 (2011). doi:10.​1021/​jp200597k CrossRef
9.
Zurück zum Zitat Ou, J., Liu, L., Wang, J., Wang, F., Xue, M., Li, W.: Fabrication and tribological investigation of a novel hydrophobic polydopamine/graphene oxide multilayer film. Tribol. Lett. 48(3), 407–415 (2012). doi:10.1007/s11249-012-0021-x CrossRef Ou, J., Liu, L., Wang, J., Wang, F., Xue, M., Li, W.: Fabrication and tribological investigation of a novel hydrophobic polydopamine/graphene oxide multilayer film. Tribol. Lett. 48(3), 407–415 (2012). doi:10.​1007/​s11249-012-0021-x CrossRef
10.
Zurück zum Zitat Pu, J., Wan, S., Zhao, W., Mo, Y., Zhang, X., Wang, L., Xue, Q.: Preparation and tribological study of functionalized graphene-IL nanocomposite ultrathin lubrication films on si substrates. J. Phys. Chem. C 115(27), 13275–13284 (2011). doi:10.1021/jp111804a CrossRef Pu, J., Wan, S., Zhao, W., Mo, Y., Zhang, X., Wang, L., Xue, Q.: Preparation and tribological study of functionalized graphene-IL nanocomposite ultrathin lubrication films on si substrates. J. Phys. Chem. C 115(27), 13275–13284 (2011). doi:10.​1021/​jp111804a CrossRef
11.
Zurück zum Zitat Kim, K.-S., Lee, H.-J., Lee, C., Lee, S.-K., Jang, H., Ahn, J.-H., Kim, J.-H., Lee, H.-J.: Chemical vapor deposition-grown graphene: the thinnest solid lubricant. ACS Nano 5(6), 5107–5114 (2011). doi:10.1021/nn2011865 CrossRef Kim, K.-S., Lee, H.-J., Lee, C., Lee, S.-K., Jang, H., Ahn, J.-H., Kim, J.-H., Lee, H.-J.: Chemical vapor deposition-grown graphene: the thinnest solid lubricant. ACS Nano 5(6), 5107–5114 (2011). doi:10.​1021/​nn2011865 CrossRef
13.
Zurück zum Zitat Wang, Y., Pu, J., Xia, L., Ding, J., Yuan, N., Zhu, Y., Cheng, G.: Fabrication and tribological study of graphene oxide/multiply-alkylated cyclopentanes multilayer lubrication films on si substrates. 1–8 (2013). doi:10.1007/s11249-013-0258-z Wang, Y., Pu, J., Xia, L., Ding, J., Yuan, N., Zhu, Y., Cheng, G.: Fabrication and tribological study of graphene oxide/multiply-alkylated cyclopentanes multilayer lubrication films on si substrates. 1–8 (2013). doi:10.​1007/​s11249-013-0258-z
14.
Zurück zum Zitat Song, H.-J., Li, N., Yang, J., Min, C.-Y., Zhang, Z.-Z.: Preparation and tribological behaviors of poly (ether ether ketone) nanocomposite films containing graphene oxide nanosheets. J. Nanopart. Res. 15(2), 1–10 (2013). doi:10.1007/s11051-013-1433-8 Song, H.-J., Li, N., Yang, J., Min, C.-Y., Zhang, Z.-Z.: Preparation and tribological behaviors of poly (ether ether ketone) nanocomposite films containing graphene oxide nanosheets. J. Nanopart. Res. 15(2), 1–10 (2013). doi:10.​1007/​s11051-013-1433-8
15.
Zurück zum Zitat Pan, B., Zhao, J., Zhang, Y., Zhang, Y.: Wear performance and mechanisms of polyphenylene sulfide/polytetrafluoroethylene wax composite coatings reinforced by graphene. J. Macromol. Sci. B 51(6), 1218–1227 (2012). doi:10.1080/00222348.2011.627821 CrossRef Pan, B., Zhao, J., Zhang, Y., Zhang, Y.: Wear performance and mechanisms of polyphenylene sulfide/polytetrafluoroethylene wax composite coatings reinforced by graphene. J. Macromol. Sci. B 51(6), 1218–1227 (2012). doi:10.​1080/​00222348.​2011.​627821 CrossRef
18.
Zurück zum Zitat Zhang, W., Zhou, M., Zhu, H., Tian, Y., Wang, K., Wei, J., Ji, F., Li, X., Li, Z., Zhang, P., Wu, D.: Tribological properties of oleic acid-modified graphene as lubricant oil additives. J. Phys. D: Appl. Phys. 44(20) (2011). doi:10.1088/0022-3727/44/20/205303 Zhang, W., Zhou, M., Zhu, H., Tian, Y., Wang, K., Wei, J., Ji, F., Li, X., Li, Z., Zhang, P., Wu, D.: Tribological properties of oleic acid-modified graphene as lubricant oil additives. J. Phys. D: Appl. Phys. 44(20) (2011). doi:10.​1088/​0022-3727/​44/​20/​205303
20.
Zurück zum Zitat Liu, H., Li, Y., Wang, T., Wang, Q.: In situ synthesis and thermal, tribological properties of thermosetting polyimide/graphene oxide nanocomposites. J. Mater. Sci. 47(4), 1867–1874 (2012). doi:10.1007/s10853-011-5975-9 CrossRef Liu, H., Li, Y., Wang, T., Wang, Q.: In situ synthesis and thermal, tribological properties of thermosetting polyimide/graphene oxide nanocomposites. J. Mater. Sci. 47(4), 1867–1874 (2012). doi:10.​1007/​s10853-011-5975-9 CrossRef
21.
23.
Zurück zum Zitat Song, H.J., Li, N., Li, Y., Min, C., Wang, Z.: Preparation and tribological properties of graphene/poly(ether ether ketone) nanocomposites. J. Mater. Sci. 47(17), 6436–6443 (2012). doi:10.1007/s10853-012-6574-0 CrossRef Song, H.J., Li, N., Li, Y., Min, C., Wang, Z.: Preparation and tribological properties of graphene/poly(ether ether ketone) nanocomposites. J. Mater. Sci. 47(17), 6436–6443 (2012). doi:10.​1007/​s10853-012-6574-0 CrossRef
25.
26.
Zurück zum Zitat Huang, T., Xin, Y., Li, T., Nutt, S., Su, C., Chen, H., Liu, P., Lai, Z.: Modified graphene/polyimide nanocomposites: reinforcing and tribological effects. ACS Appl Mater Interfaces 5(11), 4878–4891 (2013). doi:10.1021/am400635x CrossRef Huang, T., Xin, Y., Li, T., Nutt, S., Su, C., Chen, H., Liu, P., Lai, Z.: Modified graphene/polyimide nanocomposites: reinforcing and tribological effects. ACS Appl Mater Interfaces 5(11), 4878–4891 (2013). doi:10.​1021/​am400635x CrossRef
28.
Zurück zum Zitat Coleman, J.N., Lotya, M., O’Neill, A., Bergin, S.D., King, P.J., Khan, U., Young, K., Gaucher, A., De, S., Smith, R.J., Shvets, I.V., Arora, S.K., Stanton, G., Kim, H.-Y., Lee, K., Kim, G.T., Duesberg, G.S., Hallam, T., Boland, J.J., Wang, J.J., Donegan, J.F., Grunlan, J.C., Moriarty, G., Shmeliov, A., Nicholls, R.J., Perkins, J.M., Grieveson, E.M., Theuwissen, K., McComb, D.W., Nellist, P.D., Nicolosi, V.: Two-dimensional nanosheets produced by liquid exfoliation of layered materials. Science 331(6017), 568–571 (2011). doi:10.1126/science.1194975 CrossRef Coleman, J.N., Lotya, M., O’Neill, A., Bergin, S.D., King, P.J., Khan, U., Young, K., Gaucher, A., De, S., Smith, R.J., Shvets, I.V., Arora, S.K., Stanton, G., Kim, H.-Y., Lee, K., Kim, G.T., Duesberg, G.S., Hallam, T., Boland, J.J., Wang, J.J., Donegan, J.F., Grunlan, J.C., Moriarty, G., Shmeliov, A., Nicholls, R.J., Perkins, J.M., Grieveson, E.M., Theuwissen, K., McComb, D.W., Nellist, P.D., Nicolosi, V.: Two-dimensional nanosheets produced by liquid exfoliation of layered materials. Science 331(6017), 568–571 (2011). doi:10.​1126/​science.​1194975 CrossRef
31.
Zurück zum Zitat Wang, S., Li, Q., Zhang, S., Pan, L.: Tribological behavior of poly (phenyl p-hydroxybenzoate)/polytetrafluoroethylene composites filled with hexagonal boron nitride under dry sliding condition. Mater. Des. 43, 507–512 (2013). doi:10.1016/j.matdes.2012.07.048 CrossRef Wang, S., Li, Q., Zhang, S., Pan, L.: Tribological behavior of poly (phenyl p-hydroxybenzoate)/polytetrafluoroethylene composites filled with hexagonal boron nitride under dry sliding condition. Mater. Des. 43, 507–512 (2013). doi:10.​1016/​j.​matdes.​2012.​07.​048 CrossRef
34.
Zurück zum Zitat Berlin, A.A., Volfson, S.A., Enikolopian, N.S., Negmatov, S.S.: Chapter 3-polymer composites: manufacturing principles principles. In: polymer composites series: polymers—properties and applications, Vol. 10, (First Edition). pp. 100–103. Springer, Berlin (1986) Berlin, A.A., Volfson, S.A., Enikolopian, N.S., Negmatov, S.S.: Chapter 3-polymer composites: manufacturing principles principles. In: polymer composites series: polymers—properties and applications, Vol. 10, (First Edition). pp. 100–103. Springer, Berlin (1986)
35.
Zurück zum Zitat Sturzel, M., Kempe, F., Thomann, Y., Mark, S., Enders, M., Mulhaupt, R.: Novel graphene UHMWPE nanocomposites prepared by polymerization filling using single-site catalysts supported on functionalized graphene nanosheet dispersions. Macromolecules 45(17), 6878–6887 (2012). doi:10.1021/ma301376q CrossRef Sturzel, M., Kempe, F., Thomann, Y., Mark, S., Enders, M., Mulhaupt, R.: Novel graphene UHMWPE nanocomposites prepared by polymerization filling using single-site catalysts supported on functionalized graphene nanosheet dispersions. Macromolecules 45(17), 6878–6887 (2012). doi:10.​1021/​ma301376q CrossRef
36.
Zurück zum Zitat Jian, L., Ning, L., Yang, S., Wang, J., Hua, M.: Triboelectrification electrostatic potential of MC nylon 6 under point contact dry sliding. Tribol. Lett. 36(3), 199–208 (2009). doi:10.1007/s11249-009-9473-z CrossRef Jian, L., Ning, L., Yang, S., Wang, J., Hua, M.: Triboelectrification electrostatic potential of MC nylon 6 under point contact dry sliding. Tribol. Lett. 36(3), 199–208 (2009). doi:10.​1007/​s11249-009-9473-z CrossRef
37.
Zurück zum Zitat Kang, S.-C., Kang, S.-C., Chung, D.-W.: Improvement of frictional properties and abrasive wear resistance of nylon/graphite composite by oil impregnation. Wear 254(1–2), 103–110 (2003)CrossRef Kang, S.-C., Kang, S.-C., Chung, D.-W.: Improvement of frictional properties and abrasive wear resistance of nylon/graphite composite by oil impregnation. Wear 254(1–2), 103–110 (2003)CrossRef
38.
Zurück zum Zitat Samyn, P., De Baets, P., Schoukens, G., Van Driessche, I.: Friction, wear and transfer of pure and internally lubricated cast polyamides at various testing scales. Wear 262(11–12), 1433–1449 (2007)CrossRef Samyn, P., De Baets, P., Schoukens, G., Van Driessche, I.: Friction, wear and transfer of pure and internally lubricated cast polyamides at various testing scales. Wear 262(11–12), 1433–1449 (2007)CrossRef
39.
Zurück zum Zitat Zheng, L.-Y., Zhao, L.-X., Zhang, J–.J.: The effect of fiber oxidation on the tribological behavior of 3D-braided carbon fiber/nylon composites. Wear 262(7–8), 1026–1030 (2007)CrossRef Zheng, L.-Y., Zhao, L.-X., Zhang, J–.J.: The effect of fiber oxidation on the tribological behavior of 3D-braided carbon fiber/nylon composites. Wear 262(7–8), 1026–1030 (2007)CrossRef
40.
Zurück zum Zitat Li, D.-X., Deng, X., Wang, J., Yang, J., Li, X.: Mechanical and tribological properties of polyamide 6–polyurethane block copolymer reinforced with short glass fibers. Wear 269(3–4), 262–268 (2010)CrossRef Li, D.-X., Deng, X., Wang, J., Yang, J., Li, X.: Mechanical and tribological properties of polyamide 6–polyurethane block copolymer reinforced with short glass fibers. Wear 269(3–4), 262–268 (2010)CrossRef
41.
Zurück zum Zitat Ning, L., Jian, L., Yang, S., Wang, J., Ren, J., Wang, J.: Effect of carbon black on triboelectrification electrostatic potential of MC nylon composites. Tribol. Int. 43(3), 568–576 (2010)CrossRef Ning, L., Jian, L., Yang, S., Wang, J., Ren, J., Wang, J.: Effect of carbon black on triboelectrification electrostatic potential of MC nylon composites. Tribol. Int. 43(3), 568–576 (2010)CrossRef
42.
Zurück zum Zitat Khan, U., May, P., O’Neill, A., Bell, A.P., Boussac, E., Martin, A., Semple, J., Coleman, J.N.: Polymer reinforcement using liquid-exfoliated boron nitride nanosheets. Nanoscale 5(2), 581–587 (2013). doi:10.1039/c2nr33049k CrossRef Khan, U., May, P., O’Neill, A., Bell, A.P., Boussac, E., Martin, A., Semple, J., Coleman, J.N.: Polymer reinforcement using liquid-exfoliated boron nitride nanosheets. Nanoscale 5(2), 581–587 (2013). doi:10.​1039/​c2nr33049k CrossRef
46.
Zurück zum Zitat Bahadur, S., Sunkara, C.: Effect of transfer film structure, composition and bonding on the tribological behavior of polyphenylene sulfide filled with nano particles of TiO2, ZnO, CuO and SiC. Wear 258(9), 1411–1421 (2005). doi:10.1016/j.wear.2004.08.009 CrossRef Bahadur, S., Sunkara, C.: Effect of transfer film structure, composition and bonding on the tribological behavior of polyphenylene sulfide filled with nano particles of TiO2, ZnO, CuO and SiC. Wear 258(9), 1411–1421 (2005). doi:10.​1016/​j.​wear.​2004.​08.​009 CrossRef
Metadaten
Titel
Tribological Investigation of MC PA6 Reinforced by Boron Nitride of Single Layer
verfasst von
Bingli Pan
Ning Li
Guangcheng Chu
Fengjun Wei
Jichun Liu
Junkai Zhang
Yongzhen Zhang
Publikationsdatum
01.05.2014
Verlag
Springer US
Erschienen in
Tribology Letters / Ausgabe 2/2014
Print ISSN: 1023-8883
Elektronische ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-014-0324-1

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