Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 1/2021

07.06.2021 | Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Two-dimensional Bi nanosheets as an enhanced electrocatalyst for hydrogen evolution reaction

verfasst von: Chenguang Duan, Huating Liu, Zongyu Huang, Hui Qiao, Yang Zhou, Gengcheng Liao, Yundan Liu, Xiang Qi

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Electrocatalytic hydrogen evolution is an exercisable way to achieve large-scale application of hydrogen energy. It is of great significance to develop an effect, stable, and cost-effective electrocatalyst. Here, we applied the two-dimensional (2D) bismuth (Bi) to the electrocatalytic hydrogen evolution, and proposed the strategies to enhance the catalytic performance of the catalyst. Due to more active sites located along the edges of 2D structure, Bi nanosheets revealed a higher electrocatalytic activity (overpotential of −958 mV vs RHE at 10 mA cm−2, Tafel slope of 122 mV/dec) than the bulk counterpart. To further evaluate the electrocatalytic performance of Bi nanosheets, the typical parameters measured in different H+ concentration (C[H+]) are carried out. The improved catalytic activity obtained in 0.5 M H2SO4 is attributed to enhancing the hydrogen adsorption and accelerating the charge transport on the surface of catalyst. Moreover, the durability of Bi nanosheets has been texted, where the current is not evident fluctuation during the 40,000 s electrolysis measurement indicating its excellent stability. The present work expands the application of Bi in the catalysis and provides the simple strategies to improve its hydrogen evolution performance.
Vorheriger Artikel Preparation of aerogel Mg(OH)2 nanosheets by a combined sol–gel-hydrothermal process and its calcined MgO towards enhanced degradation of paraoxon pollutants
Nächster Artikel Phosphotungestic acid supported mesoporous MCM-41 coated NiFe2O4 magnetic nanoparticles as highly effective green nanocatalysts for coumarin and xanthene synthesis

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Mallouk TE (2013) Water electrolysis: divide and conquer. Nat Chem 5:362–363CrossRef
2.
Kadi MW, Mohamed RM (2019) Synthesis of BaCeO3 nanoneedles and the effect of V, Ag, Au, Pt doping on the visible light hydrogen evolution in the photocatalytic water splitting reaction. J Sol-Gel Sci Techn 91:138–145CrossRef
3.
Turner JA (2004) Sustainable hydrogen production. Science 305:972–974CrossRef
4.
Kibsgaard J, Chorkendorff I (2019) Considerations for the scaling-up of water splitting catalysts. Nat Energy 4:430CrossRef
5.
An L, Han X, Li Y, Hou C, Wang H, Zhang Q (2019) ZnS–CdS–TaON nanocomposites with enhanced stability and photocatalytic hydrogen evolution activity. J Sol-Gel Sci Techn 91:82–91CrossRef
6.
Zhu J, Hu L, Zhao P, Lee LYS, Wong K-Y (2019) Recent advances in electrocatalytic hydrogen evolution using nanoparticles. Chem Rev 120:851–918CrossRef
7.
Yan J, Huang Y, Zhang L, Zhou M, Yang P, Chen W, Deng X, Yang H (2020) Preparation of MoS2-Graphene-NiO@Ni foam composite by sol coating for (photo) electrocatalytic hydrogen evolution reaction. J Sol-Gel Sci Techn 93:462–470CrossRef
8.
Yan Y, Xia B, Xu Z, Wang X (2014) Recent development of molybdenum sulfides as advanced electrocatalysts for hydrogen evolution reaction. ACS Catal 4:1693–1705CrossRef
9.
Di J, Yan C, Handoko AD, Seh ZW, Li H, Liu Z (2018) Ultrathin two-dimensional materials for photo-and electrocatalytic hydrogen evolution. Mater Today 21:749–770CrossRef
10.
Li X, Fang Y, Wang J, Wei B, Qi K, Hoh HY, Hao Q, Sun T, Wang Z, Yin Z (2019) High-yield electrochemical production of large-sized and thinly layered NiPS3 flakes for overall water splitting. Small 15:1902427CrossRef
11.
Zhang P, Xiang H, Tao L, Dong H, Zhou Y, Hu TS, Chen X, Liu S, Wang S, Garaj S (2019) Chemically activated MoS2 for efficient hydrogen production. Nano Energy 57:535–541CrossRef
12.
Gao Q, Jin Y, Jin Y, Wang X, Ye Z, Hong Z, Zhi M (2018) Synthesis of amorphous MoSx and MoSx/carbon nanotubes composite aerogels as effective hydrogen evolution reaction catalysts. J Sol-Gel Sci Techn 88:227–235CrossRef
13.
Lloret V, Rivero-Crespo MÁ, Vidal-Moya JA, Wild S, Doménech-Carbó A, Heller BS, Shin S, Steinrück H-P, Maier F, Hauke F (2019) Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters. Nat Commun 10:1–11CrossRef
14.
Wang X, Bai L, Lu J, Zhang X, Liu D, Yang H, Wang J, Chu PK, Ramakrishna S, Yu XF (2019) Rapid activation of platinum with black phosphorus for efficient hydrogen evolution. Angew Chem Int Ed 58:19060–19066CrossRef
15.
Li L, Yu Y, Ye GJ, Ge Q, Ou X, Wu H, Feng D, Chen XH, Zhang Y (2014) Black phosphorus field-effect transistors. Nat Nanotechnol 9:372CrossRef
16.
Hu J, Chen D, Mo Z, Li N, Xu Q, Li H, He J, Xu H, Lu J (2019) Z‐Scheme 2D/2D heterojunction of black phosphorus/monolayer Bi2WO6 nanosheets with enhanced photocatalytic activities. Angew Chem Int Ed 58:2073–2077CrossRef
17.
Zhang L, Ding LX, Chen GF, Yang X, Wang H (2019) Ammonia synthesis under ambient conditions: selective electroreduction of dinitrogen to ammonia on black phosphorus nanosheets. Angew Chem 131:2638–2642CrossRef
18.
Bai L, Wang X, Tang S, Kang Y, Wang J, Yu Y, Zhou ZK, Ma C, Zhang X, Jiang J (2018) Black phosphorus/platinum heterostructure: a highly efficient photocatalyst for solar‐driven chemical reactions. Adv Mater 30:1803641CrossRef
19.
Tian B, Tian B, Smith B, Scott M, Hua R, Lei Q, Tian Y (2018) Supported black phosphorus nanosheets as hydrogen-evolving photocatalyst achieving 5.4% energy conversion efficiency at 353 K. Nat Commun 9:1–11CrossRef
20.
Abate Y, Akinwande D, Gamage S, Wang H, Snure M, Poudel N, Cronin SB (2018) Recent progress on stability and passivation of black phosphorus. Adv Mater 30:1704749CrossRef
21.
Kistanov AA, Khadiullin SK, Zhou K, Dmitriev SV, Korznikova EA (2019) Environmental stability of bismuthene: oxidation mechanism and structural stability of 2D pnictogens. J Mater Chem C 7:9195–9202CrossRef
22.
Mayorga‐Martinez CC, Gusmão R, Sofer Z, Pumera M (2019) Pnictogen‐based enzymatic phenol biosensors: phosphorene, arsenene, antimonene, and bismuthene. Angew Chem Int Ed 58:134–138CrossRef
23.
Nagao T, Sadowski J, Saito M, Yaginuma S, Fujikawa Y, Kogure T, Ohno T, Hasegawa Y, Hasegawa S, Sakurai T (2004) Nanofilm allotrope and phase transformation of ultrathin Bi film on Si (111)−7×7. Phys Rev Lett 93:105501CrossRef
24.
Medina-Ramos J, DiMeglio JL, Rosenthal J (2014) Efficient reduction of CO2 to CO with high current density using in situ or ex situ prepared Bi-based materials. J Am Chem Soc 136:8361–8367CrossRef
25.
Liu X, Zhang S, Guo S, Cai B, Yang SA, Shan F, Pumera M, Zeng H (2020) Advances of 2D bismuth in energy sciences. Chem Soc Rev 49:263–285CrossRef
26.
Zhang Y, Zuo L, Huang Y, Zhang L, Lai F, Fan W, Liu T (2015) In-situ growth of few-layered MoS2 nanosheets on highly porous carbon aerogel as advanced electrocatalysts for hydrogen evolution reaction. ACS Sustain Eng 3:3140–3148CrossRef
27.
Walker ES, Na SR, Jung D, March SD, Kim J-S, Trivedi T, Li W, Tao L, Lee ML, Liechti KM (2016) Large-area dry transfer of single-crystalline epitaxial bismuth thin films. Nano Lett 16:6931–6938CrossRef
28.
Lukowski MA, Daniel AS, Meng F, Forticaux A, Li L, Jin S (2013) Enhanced hydrogen evolution catalysis from chemically exfoliated metallic MoS2 nanosheets. J Am Chem Soc 135:10274–10277CrossRef
29.
Shao G, Xue XX, Wu B, Lin YC, Ouzounian M, Hu TS, Xu Y, Liu X, Li S, Suenaga K (2020) Template‐assisted synthesis of metallic 1T′‐Sn0.3W0.7S2 nanosheets for hydrogen evolution reaction. Adv Funct Mater 30:1906069CrossRef
30.
Aktürk E, Aktürk OÜ, Ciraci S (2016) Single and bilayer bismuthene: stability at high temperature and mechanical and electronic properties. Phys Rev B 94:014115CrossRef
31.
Su P, Xu W, Qiu Y, Zhang T, Li X, Zhang H (2018) Ultrathin bismuth nanosheets as highly efficient electrocatalyst for CO2 reduction. ChemSusChem 11:848–853CrossRef
32.
Yang B, Burch R, Hardacre C, Headdock G, Hu P (2014) Understanding the optimal adsorption energies for catalyst screening in heterogeneous catalysis. ACS Catal 4:182–186CrossRef
33.
Sabatier P (1911) Hydrogénations et déshydrogénations par catalyse. Ber Dtsch Chem Ges 44:1984–2001CrossRef
34.
Yu H, Huang H, Xu K, Hao W, Guo Y, Wang S, Shen X, Pan S, Zhang Y (2017) Liquid-phase exfoliation into monolayered BiOBr nanosheets for photocatalytic oxidation and reduction. ACS Sustain Chem Eng 5:10499–10508CrossRef
35.
Tang C, Sun A, Xu Y, Wu Z, Wang D (2015) High specific surface area Mo2C nanoparticles as an efficient electrocatalyst for hydrogen evolution. J Power Sources 296:18–22CrossRef
36.
Huang Y, Zhu C, Zhang S, Hu X, Zhang K, Zhou W, Guo S, Xu F, Zeng H (2019) Ultrathin bismuth nanosheets for stable Na-ion batteries: clarification of structure and phase transition by in situ observation. Nano Lett 19:1118–1123CrossRef
37.
Gusmão R, Sofer Z, Bouša D, Pumera M (2017) Pnictogen (As, Sb, Bi) nanosheets for electrochemical applications are produced by shear exfoliation using kitchen blenders. Angew Chem 129:14609–14614CrossRef
38.
Yin L, Hai X, Chang K, Ichihara F, Ye J (2018) Synergetic exfoliation and lateral size engineering of MoS2 for enhanced photocatalytic hydrogen generation. Small 14:1704153CrossRef
Metadaten
Titel
Two-dimensional Bi nanosheets as an enhanced electrocatalyst for hydrogen evolution reaction
verfasst von
Chenguang Duan
Huating Liu
Zongyu Huang
Hui Qiao
Yang Zhou
Gengcheng Liao
Yundan Liu
Xiang Qi
Publikationsdatum
07.06.2021
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2021
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-021-05562-6

Weitere Artikel der Ausgabe 1/2021

Journal of Sol-Gel Science and Technology 1/2021 Zur Ausgabe

Original Paper: Nano- and macroporous materials (aerogels, xerogels, cryogels, etc.)

Synthesis and characterization of low-cost hierarchical porous silica by nanoemulsion templating: influence of nanoemulsion volume and hydrodynamic diameter

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Co/ZnO/N-C composites obtained by ZIF derived from Co-Zn oxides as highly efficient catalyst for reduction of p-nitrophenol

Original Paper: Sol–gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications

Structural and electrical properties of sol–gel grown (1 − x) (ZnO) + (x) (SnO2) (x = 0, 0.25, 0.5) nanocomposites

Correction

Correction to: A phase-field study on polymerization-induced phase separation occasioned by diffusion and capillary flow—a mechanism for the formation of porous microstructures in membranes

Original Paper: Functional coatings, thin films and membranes (including deposition techniques)

Wrinkling surface of mono-layered thin film derived by using trifluoroacetate solution

Original Paper: Sol-gel and hybrid materials for biological and health (medical)

Synthesis and characterization of ultrafine γ-Al2O3:Cr nanoparticles and their performance in antibacterial activity

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise