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Tribology Letters

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01.06.2018 | Original Paper

Ultralow Friction Between Steel Surfaces Achieved by Lubricating with Liquid Crystal After a Running-in Process with Acetylacetone

verfasst von: Hui Chen, Chonghai Xu, Guangchun Xiao, Zhaoqiang Chen, Mingdong Yi

Erschienen in: Tribology Letters | Ausgabe 2/2018

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Abstract

A suitable running-in process is advantageous for reducing friction. The aim of the present work was to study the influence of the running-in with acetylacetone on tribological performance of 4-Cyano-4’-pentylbiphenyl (5CB) liquid crystal. Friction tests were performed between steel surfaces in a ball-on-disk sliding system. After a running-in period of 240 s, the COF of 5CB was measured to be 0.013, which is about a quarter of the value (0.055) without running-in. The reduced contact pressure, caused in running-in process, does not directly lead to a drop in COF. The generation of tris(acetylacetonato) iron(III) induced by the tribochemical reactions between acetylacetone and steel surfaces, and the unique physical properties of liquid crystal are assumed to be reasons for the ultralow COF. Surface analysis was performed to correlate COF with the topography of wear surfaces. An evenly distributed specific grooved structure observed on wear area of the ball may have a beneficial effect on COF as well. We believe our findings can provide an effective and simple solution to reduce COF of liquid crystal between steel surfaces. A better understanding of the tribological behavior is needed for the development of this tribological system and for the possible future applications.

Vorheriger Artikel Improving Dynamic and Tribological Behaviours by Means of a Mn–Cu Damping Alloy with Grooved Surface Features

Nächster Artikel Noncovalent Functionalized Graphene-Filled Polyimides with Improved Thermal, Mechanical, and Wear Resistance Properties

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Erdemir, A., Holmberg, K.: Energy Consumption due to Friction in Motored Vehicles and Low-Friction Coatings to Reduce it. Springer, New York (2015)CrossRef

Holmberg, K., Erdemir, A.: Influence of tribology on global energy consumption, costs and emissions. Friction. 5(3), 263–284 (2017). https://doi.org/10.1007/s40544-017-0183-5 CrossRef

Carrion, F.J., Martinez-Nicolas, G., Iglesias, P., Sanes, J., Bermudez, M.D.: Liquid crystals in tribology. Int. J. Mol. Sci. 10(9), 4102–4115 (2009). https://doi.org/10.3390/ijms10094102 CrossRef

Bermudez, M.D., Jimenez, A.E., Sanes, J., Carrion, F.J.: Ionic liquids as advanced lubricant fluids. Molecules. 14(8), 2888–2908 (2009). https://doi.org/10.3390/molecules14082888 CrossRef

Amann, T., Gatti, F., Oberle, N., Kailer, A., Rühe, J.: Galvanically induced potentials to enable minimal tribochemical wear of stainless steel lubricated with sodium chloride and ionic liquid aqueous solution. Friction. 6(2), 230–242 (2018). https://doi.org/10.1007/s40544-017-0198-y CrossRef

Prost, J.: The physics of liquid crystals. vol. 83. Oxford University Press, Oxford (1995)

Bahadur, B.: Liquid crystals: applications and uses, vol. 1. World scientific Publishing, Singapore (1990)CrossRef

Biresaw, G.: Tribology and the liquid-crystalline state. ACS Publications, Washington, DC (1990)CrossRef

Fischer, T.E., Bhattacharya, S., Salher, R., Lauer, J.L., Ahn, Y.J.: Lubrication by a smectic liquid crystal. Tribol. Trans. 31(4), 442–448 (1988). https://doi.org/10.1080/10402008808981846 CrossRef

10.

Mori, S., Iwata, H.: Relationship between tribological performance of liquid crystals and their molecular structure. Tribol. Int. 29(1), 35–39 (1996)CrossRef

11.

Sulek, M.W., Wasilewski, T.: Antiseizure properties of aqueous solutions of compounds forming liquid crystalline structures. Tribol. Lett. 18(2), 197–205 (2005). https://doi.org/10.1007/s11249-004-1776-5 CrossRef

12.

Tadokoro, C., Nihira, T., Nakano, K.: Minimization of friction at various speeds using autonomous viscosity control of nematic liquid crystal. Tribol. Lett. 56(2), 239–247 (2014). https://doi.org/10.1007/s11249-014-0404-2 CrossRef

13.

Ważyńska, B., Okowiak, J.A.: Tribological properties of nematic and smectic liquid crystalline mixtures used as lubricants. Tribol. Lett. 24(1), 1–5 (2006). https://doi.org/10.1007/s11249-006-9049-0 CrossRef

14.

Kupchinov, B.I.: Tribology and the liquid-crystalline state. J. Frict. Wear. 30(3), 169–171 (2009). https://doi.org/10.3103/s1068366609030039 CrossRef

15.

Ważyńska, B., Tykarska, M., Okowiak-Chinalska, J.: The estimation of abilities of liquid-crystalline compounds dissolved in paraffin oil for accumulation on solid surface. Mol. Cryst. Liq. Cryst. (2011). https://doi.org/10.1080/15421406.2011.571951

16.

Ghosh, P., Upadhyay, M., Das, M.K.: Studies on the additive performance of liquid crystal blended polyacrylate in lubricating oil. Liq. Cryst. 41(1), 30–35 (2013). https://doi.org/10.1080/02678292.2013.831132 CrossRef

17.

Eidenschink, R., Konrath, G., Kretzschmann, H., Rombach, M.: Unusual lift by shearing mesogenic fluids. Mol. Cryst. Liq. Cryst. Sci. Technol. 330(1), 327–334 (1999). https://doi.org/10.1080/10587259908025606 CrossRef

18.

Amann, T., Kailer, A.: Ultralow friction of mesogenic fluid mixtures in tribological reciprocating systems. Tribol. Lett. 37(2), 343–352 (2009). https://doi.org/10.1007/s11249-009-9527-2 CrossRef

19.

Amann, T., Kailer, A.: Relationship between ultralow friction of mesogenic-like fluids and their lateral chain length. Tribol. Lett. 41(1), 121–129 (2010). https://doi.org/10.1007/s11249-010-9692-3 CrossRef

20.

Amann, T., Kailer, A.: Analysis of the ultralow friction behavior of a mesogenic fluid in a reciprocating contact. Wear. 271(9–10), 1701–1706 (2011). https://doi.org/10.1016/j.wear.2010.12.012 CrossRef

21.

Li, K., Amann, T., Walter, M., Moseler, M., Kailer, A., Rühe, J.: Ultralow friction induced by tribochemical reactions: a novel mechanism of lubrication on steel surfaces. Langmuir. 29(17), 5207–5213 (2013). https://doi.org/10.1021/la400333d CrossRef

22.

Li, K., Amann, T., List, M., Walter, M., Moseler, M., Kailer, A., Rühe, J.: Ultralow friction of steel surfaces using a 1,3-diketone lubricant in the thin film lubrication regime. Langmuir. 31(40), 11033–11039 (2015). https://doi.org/10.1021/acs.langmuir.5b02315 CrossRef

23.

Amann, T., Kailer, A., Beyer-Faiß, S., Stehr, W., Metzger, B.: Development of sintered bearings with minimal friction losses and maximum life time using infiltrated liquid crystalline lubricants. Tribol. Int. 98, 282–291 (2016). https://doi.org/10.1016/j.triboint.2016.02.023 CrossRef

24.

Amann, T., Kailer, A., Oberle, N., Li, K., Walter, M., List, M., Rühe, J.: Macroscopic superlow friction of steel and diamond-like carbon lubricated with a formanisotropic 1,3-diketone. ACS Omega. 2(11), 8330–8342 (2017). https://doi.org/10.1021/acsomega.7b01561 CrossRef

25.

Liu, D., Li, K., Zhang, S., Amann, T., Zhang, C., Yan, X.: Anti-spreading behavior of 1,3-diketone lubricating oil on steel surfaces. Tribol. Int. 121, 108–113 (2018). https://doi.org/10.1016/j.triboint.2018.01.031 CrossRef

26.

Blau, P.J.: On the nature of running-in. Tribol. Int. 38(11–12), 1007–1012 (2005). https://doi.org/10.1016/j.triboint.2005.07.020 CrossRef

27.

Li, J., Zhang, C., Deng, M., Luo, J.: Superlubricity of silicone oil achieved between two surfaces by running-in with acid solution. RSC Adv. 5(39), 30861–30868 (2015). https://doi.org/10.1039/c5ra00323g CrossRef

28.

Charles, R.G., Barnartt, S.: Reaction of acetylacetone with metallic iron in the presence of oxygen. J. of Phys. Chem. 62(3), 315–318 (1958)CrossRef

29.

Sato, K., Kammori, O.: Studies of the direct dissolution of metal in a β-diketone reagent. Bull. Chem. Soc. Jpn. 42(10), 2778–2790 (1969)CrossRef

30.

Kalatain, E., Vilenkin, A.: Additives used in lubricating oils for foreign aviation gas turbine engines (review of patents). Chem. Technol. Fuels Oils 10(2), 162–166 (1974)CrossRef

31.

Nakano, K.: Scaling law on molecular orientation and effective viscosity of liquid-crystalline boundary films. Tribol. Lett. 14(1), 17–24 (2003)CrossRef

32.

Itoh, S., Imura, Y., Fukuzawa, K., Zhang, H.: Anisotropic shear viscosity of photoaligned liquid crystal confined in submicrometer-to-nanometer-scale gap widths revealed with simultaneously measured molecular orientation. Langmuir. 31(41), 11360–11369 (2015). https://doi.org/10.1021/acs.langmuir.5b02713 CrossRef

33.

Gao, M., Ma, L., Luo, J.: Effect of alkyl chain length on the orientational behavior of liquid crystals nano-film. Tribol. Lett. (2016). https://doi.org/10.1007/s11249-016-0663-1

34.

Gao, Y., Ma, L., Luo, J.: Friction anisotropy induced by oriented liquid crystal molecules. Tribol. Lett. (2016). https://doi.org/10.1007/s11249-016-0645-3

35.

Mansare, T., Decressain, R., Gors, C., Dolganov, V.K.: Phase transformations and dynamics of 4-cyano-4′-pentylbiphenyl (5CB) by nuclear magnetic resonance, analysis differential scanning calorimetry, and wideangle X-ray diffraction analysis. Mol. Cryst. 382(1), 97–111 (2002)CrossRef

36.

Tsai, T.R., Chen, C.Y., Pan, C.L., Pan, R.P., Zhang, X.C.: Terahertz time-domain spectroscopy studies of the optical constants of the nematic liquid crystal 5CB. Appl. Opt. 42(13), 2372–2376 (2003)CrossRef

37.

Burris, D.L., Sawyer, W.G.: Addressing practical challenges of low friction coefficient measurements. Tribol. Lett. 35(1), 17–23 (2009). https://doi.org/10.1007/s11249-009-9438-2 CrossRef

38.

Li, J., Zhang, C., Sun, L., Luo, J.: Analysis of measurement inaccuracy in superlubricity tests. Tribol. Trans. 56(1), 141–147 (2013). https://doi.org/10.1080/10402004.2012.732200 CrossRef

39.

Srivastava, S., Badrinarayanan, S., Mukhedkar, A.J.: X-ray photoelectron spectra of metal complexes of substituted 2,4-pentanediones. Polyhedron. 4(3), 409–414 (1985)CrossRef

40.

Berman, D., Erdemir, A., Sumant, A.V.: Few layer graphene to reduce wear and friction on sliding steel surfaces. Carbon. 54, 454–459 (2013). https://doi.org/10.1016/j.carbon.2012.11.061 CrossRef

41.

Gao, Y., Ma, L., Luo, J.: Pitted surfaces produced by lactic acid lubrication and their effect on ultra-low friction. Tribol. Lett. (2015). https://doi.org/10.1007/s11249-015-0463-z

42.

Jerome, B.: Surface effects and anchoring in liquid crystals. Rep. Prog. Phys. 54(3), 391 (1991)CrossRef

43.

Sengupta, A., Herminghaus, S., Bahr, C.: Liquid crystal microfluidics: surface, elastic and viscous interactions at microscales. Liq. Cryst. Rev. 2(2), 73–110 (2014)CrossRef

Titel: Ultralow Friction Between Steel Surfaces Achieved by Lubricating with Liquid Crystal After a Running-in Process with Acetylacetone
verfasst von: Hui Chen
Chonghai Xu
Guangchun Xiao
Zhaoqiang Chen
Mingdong Yi
Publikationsdatum: 01.06.2018
Verlag: Springer US
Erschienen in: Tribology Letters / Ausgabe 2/2018
Print ISSN: 1023-8883
Elektronische ISSN: 1573-2711
DOI: https://doi.org/10.1007/s11249-018-1020-3

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