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Erschienen in: Journal of Polymer Research 9/2020

01.09.2020 | ORIGINAL PAPER

Ultrasonic mediated synthesis of arsenic imprinted polymer and their analytical practicality as a selective sorbent for removal of toxic As3+ ion from real samples

verfasst von: Abdullah, Esra Alveroglu, Aamna Balouch, Farah Naz Talpur, Muhammad Tariq Shah, Ameet Kumar, Ali Muhammad Mahar, Muhammad Saqaf Jagirani, Amina

Erschienen in: Journal of Polymer Research | Ausgabe 9/2020

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Abstract

In this study, we report the synthesis of arsenic-imprinted polymer (As-IIP) through the combined effect of dual functional monomers, 4-vinyl pyridine, and methacrylic acid based ionic interaction by a simple and cost-effective ultrasonic-mediated precipitation polymerization. Ultrasonic energy application reduces the reaction time as compared to conventional protocol. Surface morphology and functionality were examined using SEM and FT-IR. Adsorption mechanism and kinetics was describes by Langmuir, followed by pseudo second order. The repeatability and selectivity of As-IIP were also evaluated. The As-IIP revealed excellent selectivity toward As3+ in the presence of Al3+, Cr3+, Hg2+, and Ni2+ high anti-interference ability in the presence of various coexisting ions. An excellent linear range of concentration (2–100) μg L−1 as well as LOD and LOQ were obtained 0.65 and 1.8 μgL−1 respectively. The synthesized As-IIP was applied for selective removal of toxic As3+ ions in real samples.

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Metadaten
Titel
Ultrasonic mediated synthesis of arsenic imprinted polymer and their analytical practicality as a selective sorbent for removal of toxic As3+ ion from real samples
verfasst von
Abdullah
Esra Alveroglu
Aamna Balouch
Farah Naz Talpur
Muhammad Tariq Shah
Ameet Kumar
Ali Muhammad Mahar
Muhammad Saqaf Jagirani
Amina
Publikationsdatum
01.09.2020
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 9/2020
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-02196-0

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