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Polymer Bulletin

Erschienen in:

01.10.2020 | Original Paper

Ultrasound-assisted polymerization of benzoquinone (BQ) with triphenylamine (TPA): comparison of computational and experimental studies

verfasst von: Neetika Singh, Elham S. Aazam, Ufana Riaz

Erschienen in: Polymer Bulletin | Ausgabe 5/2021

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Abstract

The present preliminary work reports chemical oxidative polymerization of benzoquinone with triphenylamine via ultrasound-assisted technique. The obtained polymer was characterized using Fourier transform infrared spectroscopy analysis, while the electronic transitions were analyzed via ultraviolet–visible studies. The experimental data were compared with the theoretically computed results using Gaussian 09 software. Theoretical IR and UV spectra were computed using DFT/B3LYP method with 6-311G basis set, and the results of spectral analysis were found to be in good agreement with the experimental ones. TEM analysis revealed flower-like particles, while the XRD results confirmed the formation of semi-crystalline polymers. Fluorescence studies exhibited emission around 800 nm, while the relative quantum yield was calculated to be 0.58. The synthesized polymer therefore holds immense potential to be used as near infrared bioimaging agent.

Vorheriger Artikel Ring-opening polymerization of L-lactide by using sodium complexes bearing amide as catalysts in high polar solvent

Nächster Artikel Determining long-lived photo-excited species in thin-film anthracene derivatives using quasi-continuous wavelength photo-induced absorption

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Titel: Ultrasound-assisted polymerization of benzoquinone (BQ) with triphenylamine (TPA): comparison of computational and experimental studies
verfasst von: Neetika Singh
Elham S. Aazam
Ufana Riaz
Publikationsdatum: 01.10.2020
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 5/2021
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-020-03384-0

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