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Rare Metals
Erschienen in: Rare Metals 12/2020

05.08.2020 | Original Article

Ultrathin porous graphitic carbon nanosheets activated by alkali metal salts for high power density lithium-ion capacitors

verfasst von: Yu-Qing Dai, Guang-Chao Li, Xin-Hai Li, Hua-Jun Guo, Zhi-Xing Wang, Guo-Chun Yan, Jie-Xi Wang

Erschienen in: Rare Metals | Ausgabe 12/2020

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Abstract

Graphitic carbons with reasonable pore volume and appropriate graphitization degree can provide efficient Li+/electrolyte-transfer channels and ameliorate the sluggish dynamic behavior of battery-type carbon negative electrode in lithium-ion capacitors (LICs). In this work, onion-like graphitic carbon materials are obtained by using carbon quantum dots as precursors after sintering, and the effects of alkali metal salts on the structure, morphology and performance of the samples are focused. The results show that alkali metal salts as activator can etch graphitic carbons, and the specific surface area and pore size distribution are intimately related to the description of the alkali metal salt. Moreover, it also affects the graphitization degree of the materials. The porous graphitic carbons (S-GCs) obtained by NaCl activation exhibit high specific surface area (77.14 m2·g−1) and appropriate graphitization degree. It is expectable that the electrochemical performance for lithium-ions storage can be largely promoted by the smart combination of catalytic graphitization and pores-creating strategy. High-performance LICs (S-GCs//AC LICs) are achieved with high energy density of 92 Wh·kg−1 and superior rate capability (66.3 Wh·kg−1 at 10 A·g−1) together with the power density as high as 10020.2 W·kg−1.

Graphic abstract

Vorheriger Artikel Layer-dependent and light-tunable surface potential of two-dimensional indium selenide (InSe) flakes
Nächster Artikel Optimizing thermoelectric properties of BiSe through Cu additive enhanced effective mass and phonon scattering

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Metadaten
Titel
Ultrathin porous graphitic carbon nanosheets activated by alkali metal salts for high power density lithium-ion capacitors
verfasst von
Yu-Qing Dai
Guang-Chao Li
Xin-Hai Li
Hua-Jun Guo
Zhi-Xing Wang
Guo-Chun Yan
Jie-Xi Wang
Publikationsdatum
05.08.2020
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 12/2020
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-020-01509-y

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