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Journal of Polymer Research

Erschienen in:

01.08.2021 | ORIGINAL PAPER

Uncarbonized crosslinked PVA-modified MMT/reduced graphene hybrid aerogel for efficient carbon dioxide adsorption at low pressure

verfasst von: Sona Stanly, Honey John

Erschienen in: Journal of Polymer Research | Ausgabe 8/2021

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Abstract

Graphene-based polymer aerogels are one of the important solutions for the adsorption of CO₂. In the present study, we have developed an economic, uncarbonized polyvinyl alcohol (PVA) based aerogel through the freeze-drying method using modified clay- reduced graphene oxide (rGO) hybrid as filler. The CO₂ capture efficiency of PVA-modified clay/rGO aerogel containing the hybrid filler in three different concentrations such as 0.1 w/v%, 0.5 w/v% and 1 w/v% at 25 °C and comparatively low pressure ranging from 0 to 900 mmHg was studied. The polyphosphoric acid (PPA) modified montmorillonite (PMMT)/rGO hybrid was synthesized by the hydrothermal method by varying the ratio of the individual components in 2:1 and 1:2 ratios and compared with a 1:1 ratio hybrid. The powdered hybrids were characterized and analyzed for CO₂ adsorption analysis. All the powdered hybrids were showing good CO₂ gas adsorption efficiency and the efficiency was increased with an increase in rGO content and hybrid with 1:2 ratio showed a CO₂ adsorption efficiency of 0.53 mmol g⁻¹. PVA aerogel was synthesized using 1:1 and 1:2 PMMT/rGO hybrids and CO₂ adsorption capacity were analyzed. PVA-PMMT/rGO aerogel of 1:2 ratio with 0.5 w/v% showed only 0.176 mmol g⁻¹ whereas PVA-PMMT/rGO aerogel of 1:1 ratio with 0.5 w/v% showed an excellent CO₂ adsorption capacity of 0.238 mmol g⁻¹ at 900 mmHg at 25 °C temperature and it is significantly high when compared with the literature results. The developed PVA-PMMT/rGO hybrid aerogel is an excellent material for CO₂ adsorption and it can be directly used for reducing the CO₂ level in the atmosphere.

Vorheriger Artikel Reversible thermo-electric energy harvesting with phase change material (PCM) composites

Nächster Artikel Enhanced UV protection and water adsorption properties of transparent poly(methyl methacrylate) films through incorporation of amorphous magnesium carbonate nanoparticles

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Titel: Uncarbonized crosslinked PVA-modified MMT/reduced graphene hybrid aerogel for efficient carbon dioxide adsorption at low pressure
verfasst von: Sona Stanly
Honey John
Publikationsdatum: 01.08.2021
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 8/2021
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-021-02614-x

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