Introduction
Experimental
Materials
Pretreatment of cotton fabric samples
Preparation of a betulin-terephthaloyl chloride copolymer
Film preparation
Mixture/film | CTA (mg) | Betulin (mg) | Copolymer (mg) | Ratioa |
---|---|---|---|---|
1 | 290 | 116 | – | 1:0.4 |
2 | 290 | 203 | – | 1:0.7 |
3 | 290 | 290 | – | 1:1 |
4 | 290 | 377 | – | 1:1.3 |
5 | 290 | 461 | – | 1:1.6 |
6 | 290 | 551 | – | 1:1.9 |
7 | 290 | – | 116 | 1:0.4 |
8 | 290 | – | 203 | 1:0.7 |
9 | 290 | – | 290 | 1:1 |
10 | 290 | – | 377 | 1:1.3 |
11 | 290 | – | 461 | 1:1.6 |
Impregnation of cotton fabric samples with solutions (methods A and B)
Surface coating of cotton fabric samples with films (methods C and D)
Characterization
Result and discussion
Preparation of a betulin-terephthaloyl chloride copolymer
Film preparation
Materials | Methods of preparation |
---|---|
A1 | Fabric impregnated with 3.75 g L−1 betulin solution in ethanol |
A2 | Fabric impregnated with 7.5 g L−1 betulin solution in ethanol |
A3 | Fabric impregnated with 7.5 g L−1 betulin solution in ethyl acetate |
B | Fabric impregnated with 3.75 g L−1 betulin-TPC copolymer solution in THF |
C | Fabric coated with betulin based film (film 4, CTA: betulin = 1:1.3) |
D | Fabric coated with betulin-TPC copolymer based film (film 9, CTA: betulin-TPC copolymer = 1:1) |
Materials preparation
SEM
Water contact angle
Water repellency
Rating | Evaluation |
---|---|
100 | No sticking or wetting of the specimen face |
90 | Slight random sticking or wetting of the specimen face |
80 | Wetting of specimen face at spray points |
70 | Partial wetting of the specimen face beyond the spray points |
50 | Complete wetting of the entire specimen face beyond the spray points |
0 | Complete wetting of the entire face of the specimen |