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Journal of Nanoparticle Research

Erschienen in:

01.06.2021 | Research paper

ZIF-8 derived porous ZnO with grain boundaries for efficient CO₂ electroreduction

verfasst von: Yuhan Hu, Haihua Wu, Yaoyue Yang, Xiaoman Lin, Hailian Cheng, Rui Zhang, Xiaole Jiang, Jing Wang

Erschienen in: Journal of Nanoparticle Research | Ausgabe 6/2021

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Abstract

Electrocatalytic CO₂ reduction reaction has been considered as a promising route to realize carbon cyclic utilization and renewable energy storage. Recently, Zn-based catalysts have attracted much attention due to their earth-abundant reserve and low cost, which can meet the demand for commercial applications at a large scale. Herein, ZnO catalyst (ZIF-8-D-ZnO) was synthesized by pyrolysis of ZIF-8 precursor for electrocatalytic reduction of CO₂. The ZIF-8-D-ZnO catalyst exhibits an excellent catalytic activity for CO production than rod-like ZnO and Zn foil catalysts, with faradaic efficiency of 86.7 % and geometric current density of 16.1 mA cm⁻² at −1.2 V (vs. RHE). Moreover, the overpotential over ZIF-8-D-ZnO is much lower than that of analogous catalysts. The results suggest that the grain boundaries within the porous structure facilitate CO₂ electroreduction over ZIF-8-D-ZnO due to the introduction of new catalytically active sites. This work provides experimental evidence for the design of efficient Zn-based materials for CO₂ electrocatalytic reduction.

Graphical abstract

ZIF-8-D-ZnO catalyst with porous structure and grain boundaries exhibits much higher CO faradaic efficiency and current density than ZnO-R and Zn foil catalysts.

Vorheriger Artikel Anomalous effect of Cu2O and CuO deposit on the porosity of a macroreticular anion exchanger

Nächster Artikel Upscaling nanoparticle synthesis by sputter deposition in ionic liquids

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Titel: ZIF-8 derived porous ZnO with grain boundaries for efficient CO2 electroreduction
verfasst von: Yuhan Hu
Haihua Wu
Yaoyue Yang
Xiaoman Lin
Hailian Cheng
Rui Zhang
Xiaole Jiang
Jing Wang
Publikationsdatum: 01.06.2021
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 6/2021
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-021-05271-9

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Abstract

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