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Journal of Materials Science
Erschienen in: Journal of Materials Science 6/2017

28.11.2016 | Original Paper

A novel MWCNT/nanotubular TiO2(B) loaded with SnO2 nanocrystals ternary composite as anode material for lithium-ion batteries

verfasst von: Jiao Zheng, Daqian Ma, Xiangfeng Wu, Peng Dou, Zhenzhen Cao, Chao Wang, Xinhua Xu

Erschienen in: Journal of Materials Science | Ausgabe 6/2017

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Abstract

A novel MWCNT/long nanotubular TiO2(B) loaded with SnO2 nanocrystals (SnO2NC/TiO2(B)NT/MWCNT) ternary composite has been prepared by two-step hydrothermal method and used as the anode material for the first time. In this work, the mechanical stirring improved the diffusion and surface reaction rates of reactants and promoted the appearance of longer intermediate TiO2(B) nanosheets, leading to the formation of TiO2(B) nanotubes with a length of ~9 μm. Among the SnO2NC/TiO2(B)NT/MWCNT composite, the wrapping and mechanical supporting functions of TiO2(B) nanotubes can effectively avoid the pulverization and aggregation of SnO2 nanocrystals (SnO2NC) in lithium-ion charging and discharging process. Moreover, the synergistic effects of nanotubular TiO2(B) coating layer and three-dimensional interconnected network structure composed of TiO2(B) nanotubes and MWCNT were taken to mitigate volume expansion of SnO2NC and improve the transport of lithium ion and electron in the network. Tested as anode materials, the SnO2NC/TiO2(B)NT/MWCNT composite maintained 211 mAh g−1 at 3000 mA g−1 after three testing processes with alternative current density of 200 and 3000 mA g−1 and could rebound to 338 mAh g−1 at a current density of 200 mA g−1, indicating an effective way to optimize electrochemical properties of SnO2 as anode material.
Vorheriger Artikel Investigation of the electronic and optical properties of ZnS monolayer nanosheet: first principles calculations
Nächster Artikel Parametric study of protein-encapsulated microcapsule formation and effect on self-healing efficiency of ‘green’ soy protein resin

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Metadaten
Titel
A novel MWCNT/nanotubular TiO2(B) loaded with SnO2 nanocrystals ternary composite as anode material for lithium-ion batteries
verfasst von
Jiao Zheng
Daqian Ma
Xiangfeng Wu
Peng Dou
Zhenzhen Cao
Chao Wang
Xinhua Xu
Publikationsdatum
28.11.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 6/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0578-0

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